RESUMO
According to Environmental Protection Agency estimates, 20% of hazardous waste drums currently managed in the 6500 known, uncontrolled Superfund removal or remediation sites contain some degree of elevated internal pressurization. This estimate increases to 90% during the summer months, and, overall, up to 5% of the drums stored in active treatment, storage, and disposal facilities may be pressurized. The ability to identify pressurized drums in real-time would enhance worker health and safety, reduce the potential for environmental contamination, and minimize property damage. A prototype hand-held drum pressure detection device was field tested at an active Resource Conservation and Recovery Act mixed waste operation using acoustic resonance spectroscopy technology to identify pressurized drums. The waste operation used a drum venting system that measured the actual drum pressure of retrieved drums. Drum venting system data were analyzed to quantify the ability of the drum pressure detection device to correctly identify drums with elevated internal pressure. After 456 drums were measured, the dichotomous pressure data (pressurized vs. nonpressurized) were analyzed. The relationship between the drum venting system and drum pressure detection device pressure data was found to be statistically significant. With alpha and beta values of 0.05, the negative predictive value was 0.94, the positive predictive value was 0.47, the sensitivity was 0.82, and the specificity was 0.77. Although capable of identifying nonpressurized drums, this instrument may not be appropriate for general use. Study results and critical improvements necessary to improve the instrument's predictive value, specificity, and sensitivity are presented.