Characterization and Modeling of Nano Wear for Molybdenum-Based Lubrication Layer Systems.

As a result of global economic and environmental change, the demand for innovative, environmentally-friendly technologies is increasing. Employing solid lubricants in rolling contacts can reduce the use of environmentally harmful greases and oils. The aim of the current research was the development of a solid lubricant system with regenerative properties. The layer system consisted of a molybdenum (Mo) reservoir and a top layer of molybdenum trioxide (MoO3). After surface wear, Mo is supposed to react with atmospheric oxygen and form a new oxide. The determination of the wear volume of thin layers cannot be measured microscopically, which is why the wear behavior is initially determined on the nano level. In this work, single Mo and MoO3 coatings prepared by physical vapor deposition (PVD) are characterized by nano testing. The main objective was to determine the wear volume of the single coatings using a newly developed method considering the initial topology. For this purpose, nano-wear tests with different wear paths and normal forces were carried out and measured by in situ scanning probe microscopy (SPM). Based on the characteristic values determined, the coefficient of wear was determined for wear modeling according to Sarkar. The validation of the wear model developed was carried out by further wear tests on the respective mono layers.

How deep ocean-land coupling controls the generation of secondary microseism Love waves.

Wind driven ocean wave-wave interactions produce continuous Earth vibrations at the seafloor called secondary microseisms. While the origin of associated Rayleigh waves is well understood, there is currently no quantified explanation for the existence of Love waves in the most energetic region of the microseism spectrum (3-10 s). Here, using terrestrial seismic arrays and 3D synthetic acoustic-elastic simulations combined with ocean wave hindcast data, we demonstrate that, observed from land, our general understanding of Rayleigh and Love wave microseism sources is significantly impacted by 3D propagation path effects. We show that while Rayleigh to Love wave conversions occur along the microseism path, Love waves predominantly originate from steep subsurface geological interfaces and bathymetry, directly below the ocean source that couples to the solid Earth. We conclude that, in contrast to Rayleigh waves, microseism Love waves observed on land do not directly relate to the ocean wave climate but are significantly modulated by continental margin morphologies, with a first order effect from sedimentary basins. Hence, they yield rich spatio-temporal information about ocean-land coupling in deep water.

[Chloracne after exposure to dioxin]. / Chlorakne nach Dioxin-exposition.

In 2004, the assumed "dioxin intoxication" of the presidential candidate and today's President of the Ukraine, Victor Yushchenko, gained considerable attention in the media. The politician exhibited pronounced skin changes compatible with chloracne, a characteristic sequela of an exposure to high doses of dioxin. Although this dermatologic disorder has been known for a long time, it is only during recent years that detailed knowledge regarding possible pathomechanisms has been gained. The probable underlying mechanisms of dioxin toxicity, with special emphasis on the development of chloracne, will be discussed in this review.