Performance and stability enhancement of perovskite photodetectors by additive and interface engineering using a dual-functional PPS zwitterion.

Hybrid organic-inorganic metal halide perovskites (HOIPs) have gained significant research interest due to their tunable optoelectronic properties and ease of fabrication. Enhancing the stability and efficiency of perovskite materials can be achieved through the passivation of defective surfaces and the improvement of interfacial properties. In this study, we introduce a zwitterionic compound, PPS (3-(1-pyridinio)-1-propanesulfonate), as a bifunctional material that serves as an additive and an interlayer. Incorporating PPS into the perovskite film effectively reduces both positively and negatively charged defects, leading to improved surface morphology and a reduction in undesired charge carrier recombination. Additionally, the formation of a PPS interlayer on SnO2 improves the SnO2/perovskite interfacial characteristics, thereby enhancing charge carrier extraction. As a result, the photodetector exhibits a low dark current of 6.05 × 10-11 A, an excellent responsivity of 5.93 A W-1, a detectivity of 1.51 × 1013 J, and an on/off ratio of 1.2 × 104 under open-air conditions. Moreover, the device demonstrates outstanding stability, retaining 80% of its original responsivity in an ambient environment. This work highlights the great potential of dual-functional materials for defect passivation in future optoelectronic devices, emphasizing the importance of surface modification and interface engineering for improved performance and stability.

Electrical Transport Properties Driven by Unique Bonding Configuration in γ-GeSe.

Group IV monochalcogenides have recently shown great potential for their thermoelectric, ferroelectric, and other intriguing properties. The electrical properties of group IV monochalcogenides exhibit a strong dependence on the chalcogen type. For example, GeTe exhibits high doping concentration, whereas S/Se-based chalcogenides are semiconductors with sizable bandgaps. Here, we investigate the electrical and thermoelectric properties of γ-GeSe, a recently identified polymorph of GeSe. γ-GeSe exhibits high electrical conductivity (∼106 S/m) and a relatively low Seebeck coefficient (9.4 µV/K at room temperature) owing to its high p-doping level (5 × 1021 cm-3), which is in stark contrast to other known GeSe polymorphs. Elemental analysis and first-principles calculations confirm that the abundant formation of Ge vacancies leads to the high p-doping concentration. The magnetoresistance measurements also reveal weak antilocalization because of spin-orbit coupling in the crystal. Our results demonstrate that γ-GeSe is a unique polymorph in which the modified local bonding configuration leads to substantially different physical properties.

Efficient Propylene Carbonate Synthesis from Urea and Propylene Glycol over Calcium Oxide-Magnesium Oxide Catalysts.

A series of calcium oxide-magnesium oxide (CaO-MgO) catalysts were prepared under the effects of different precipitating agents and using varied Mg/Ca ratios. The physiochemical characteristics of the prepared catalysts were analyzed using XRD, FE-SEM, BET, FTIR, and TG/DTA techniques. Quantification of basic active sites present on the surface of the CaO-MgO catalysts was carried out using the Hammett indicator method. The as-prepared mixed oxide samples were tested for propylene carbonate (PC) synthesis through the alcoholysis of urea with propylene glycol (PG). The effects of the catalyst composition, catalyst dose, reaction temperature, and contact time on the PC yield and selectivity were investigated. The maximum PC yield of 96%, with high PC selectivity of 99% and a urea conversion rate of 96%, was attained at 160 °C using CaO-MgO catalysts prepared using a Mg/Ca ratio of 1 and Na2CO3 as a precipitating agent. The best-performing catalysts also exhibited good reusability without any significant loss in PC selectivity. It is expected that the present study will provide useful information on the suitability of different precipitating agents with respect to the catalytic properties of the oxides of Ca and Mg and their application in the synthesis of organic carbonates.

Zinc hydroxystannate/zinc-tin oxide heterojunctions for the UVC-assisted photocatalytic degradation of methyl orange and tetracycline.

Partial phase modification of zinc hydroxystannate (ZHS) is an effective technique for improving its light absorption capacity. In this study, a zinc hydroxystannate/zinc-tin oxide (ZHS/ZTO) heterostructure was synthesized via chemical co-precipitation followed by annealing. The as-prepared heterostructure revealed cubic crystal morphology along with high-intensity diffraction peaks in the XRD pattern. The XPS analysis of ZHS/ZTO heterostructures demonstrated the presence of key elements (Zn, Sn, and O) in their most stable ionic forms. The photocatalytic degradation efficiencies of the prepared samples were tested against methyl orange (MO) and tetracycline (TC) in an aqueous medium under UVC (254 nm) radiation. Under optimized conditions, maximum degradation efficiencies of 99% for MO and 97% for TC were observed in 120 and 180 min, respectively. Further, the predominant role of OH˙ radicals in the photocatalytic removal of MO and TC was evident through scavenging experiments. 2nd order kinetic model was outperformed in simulating the degradation mechanism of both targets over 1st and zero-order kinetic models. Finally, a photocatalytic degradation mechanism is proposed based on the energy values estimated for the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) using UPS analysis.

STEM Image Analysis Based on Deep Learning: Identification of Vacancy Defects and Polymorphs of MoS2.

Scanning transmission electron microscopy (STEM) is an indispensable tool for atomic-resolution structural analysis for a wide range of materials. The conventional analysis of STEM images is an extensive hands-on process, which limits efficient handling of high-throughput data. Here, we apply a fully convolutional network (FCN) for identification of important structural features of two-dimensional crystals. ResUNet, a type of FCN, is utilized in identifying sulfur vacancies and polymorph types of MoS2 from atomic resolution STEM images. Efficient models are achieved based on training with simulated images in the presence of different levels of noise, aberrations, and carbon contamination. The accuracy of the FCN models toward extensive experimental STEM images is comparable to that of careful hands-on analysis. Our work provides a guideline on best practices to train a deep learning model for STEM image analysis and demonstrates FCN's application for efficient processing of a large volume of STEM data.

Evaluation of photocatalytic performances of PEG and PVP capped zinc sulfide nanoparticles towards organic environmental pollutant in presence of sunlight.

Advanced oxidation processes triggered by nanoscale materials are promising owing to the in-situ generation of reactive radicals that can degrade toxic organic pollutants. In the present study, zinc sulfide (ZnS) nanoparticles with polyethylene glycol-4000 (PEG-4000) and polyvinylpyrrolidone (PVP) cappings were prepared using the chemical precipitation method and characterized thoroughly. Optical and structural characteristics of the capped ZnS nanoparticles were investigated and compared with those of uncapped ZnS nanoparticles. Results showed that PVP and PEG capped ZnS nanoparticles exhibited smaller crystallite size of 1.42 and 1.5 nm, respectively, as compared to uncapped ZnS (1.93 nm). Consequently, band gap energies of capped ZnS nanoparticles were higher which enable them to work as solar photocatalyst. The photocatalytic performance of the PEG, PVP-capped, and uncapped ZnS nanoparticles were evaluated against methyl orange (MO) dye and showed 85%, 87%, and 80% dye removal efficiencies, respectively. Degradation rate constant derived using Langmuir-Hinshelwood model revealed faster degradation kinetics bycapped ZnS photocatalysts owing to broader light absorption range. A possible dye degradation mechanism based on the energy levels positions was proposed to explain the route of photocatalytic degradation of MO by ZnS materials. It was inferred that the generation of reactive oxygen species by photogenerated electron-hole pairs facilitate degradation of MO dye molecules under sunlight illumination. It is expected that this work will provide insights into the development of strategies employed to achieve enhanced photocatalysis by nanoscale materials through organic capping.

Improved Photoresponse Characteristics of a ZnO-Based UV Photodetector by the Formation of an Amorphous SnO2 Shell Layer.

Although ZnO nanostructure-based photodetectors feature a well-established system, they still present difficulties when being used in practical situations due to their slow response time. In this study, we report on how forming an amorphous SnO2 (a-SnO2) shell layer on ZnO nanorods (NRs) enhances the photoresponse speed of a ZnO-based UV photodetector (UV PD). Our suggested UV PD, consisting of a ZnO/a-SnO2 NRs core-shell structure, shows a rise time that is 26 times faster than a UV PD with bare ZnO NRs under 365 nm UV irradiation. In addition, the light responsivity of the ZnO/SnO2 NRs PD simultaneously increases by 3.1 times, which can be attributed to the passivation effects of the coated a-SnO2 shell layer. With a wide bandgap (~4.5 eV), the a-SnO2 shell layer can successfully suppress the oxygen-mediated process on the ZnO NRs surface, improving the photoresponse properties. Therefore, with a fast photoresponse speed and a low fabrication temperature, our as-synthesized, a-SnO2-coated ZnO core-shell structure qualifies as a candidate for ZnO-based PDs.

Characterization of an Antibacterial Agent Targeting Ferrous Iron Transport Protein FeoB against Staphylococcus aureus and Gram-Positive Bacteria.

The emergence of multidrug-resistant Staphylococcus aureus strains has become a serious clinical problem. Iron is absolutely required for the bacterial growth, virulence associated with colonization, and survival from the host immune system. The FeoB protein is a major iron permease in bacterial ferrous iron transport systems (Feo) that has been shown to play a crucial role in virulence of some pathogenic bacteria. However, FeoB is still uncharacterized in Gram-positive pathogens, and its effects on S. aureus pathogenesis are unknown. In this study, we identified a novel inhibitor, GW3965·HCl, that targets FeoB in S. aureus. The molecule effectively inhibited FeoB in vitro enzyme activity, bacterial growth, and virulence factor expression. Genome-editing and metabolomic analyses revealed that GW3965·HCl inhibited FeoB function and affected the associated mechanisms with reduced iron availability in S. aureus. Gentamicin resistance and Caenorhabditis elegans infection assays further demonstrated the power of GW3965·HCl as a safe and efficient antibacterial agent. In addition to S. aureus, GW3965·HCl also presented its effectiveness on inhibition of the FeoB activity and growth of Gram-positive bacteria. This novel inhibitor will provide new insight for developing a next-generation antibacterial therapy.

Biochemical characterization of bacterial FeoBs: A perspective on nucleotide specificity.

Iron is an essential requirement for the survival and virulence of most bacteria. The bacterial ferrous iron transporter protein FeoB functions as a major reduced iron transporter in prokaryotes, but its biochemical mechanism has not been fully elucidated. In the present study, we compared enzymatic properties of the cytosolic portions of pathogenic bacterial FeoBs to elucidate each bacterial strain-specific characteristic of the Feo system. We show that bacterial FeoBs are classified into two distinct groups that possess either a sole GTPase or an NTPase with a substrate promiscuity. This difference in nucleotide preference alters cellular requirements for monovalent and divalent cations. While the hydrolytic activity of the GTP-dependent FeoBs was stimulated by potassium, the action of the NTP-dependent FeoBs was not significantly affected by the presence of monovalent cations. Mutation of Asn11, having a role in potassium-dependent GTP hydrolysis, changed nucleotide specificity of the NTP-dependent FeoB, resulting in loss of ATPase activity. Sequence analysis suggested a possible association of alanine in the G5 motif for the NTP-dependent activity in FeoBs. This demonstration of the distinct enzymatic properties of bacterial FeoBs provides important insights into mechanistic details of Feo iron transport processes, as well as offers a promising species-specific anti-virulence target.

Ultraviolet photodetector using pn junction formed by transferrable hollow n-TiO2 nano-spheres monolayer.

We report an ultraviolet (UV) photodetector with a universally transferable monolayer film with ordered hollow TiO2 spheres on p-GaN. After forming a TiO2 monolayer film by unidirectional rubbing of hollow TiO2 spheres on a polydimethylsiloxane (PDMS) supporting plate, we used a 5% polyvinyl alcohol (PVA) aqueous solution to transfer the film onto the target substrate. The PVA/TiO2 monolayer film was detached from the PDMS film and transferred to the p-GaN/Al2O3 substrate. To investigate the effects of crystallized phases of the TiO2 hollow spheres, anatase and rutile TiO2 sphere monolayers prepared by combining template synthesis and thermal treatment. The responsiveness of the UV photodetectors using anatase and rutile hollow n-TiO2 monolayer/p-GaN was 0.203 A/W at 312 nm and 0.093 A/W at 327 nm, respectively.

Enhancement of Device Performances in GaN-Based Light-Emitting Diodes Using Nano-Sized Surface Pit.

We report the improvement in optical and electrical properties of GaN-based green light-emitting diodes (LEDs) with nano-sized etch pits formed by the surface chemical etching. In order to control the density and sizes of etch pits formed on top surface of green LEDs, H3PO4 solution is used as a etchant with different etching time. When the etching time was increased from 0 min to 20 min, both the etch pit size and density were gradually increased. The improvement of extraction efficiency of LEDs using surface etching method can be attributed to the enlarged escape angle of generated photon by roughened p-GaN surface. The finite-difference time-domain (FDTD) simulation results well agreed with experimentally observed results. Moreover, the LED with etched p-GaN surface for 5 min shows the lowest leakage current value and the further increase of etching time resulting in increase of densities of the large-sized etch pit makes the degradation of electrical properties of LEDs.

Enhanced light extraction from GaN based light-emitting diodes using a hemispherical NiCoO lens.

We report on the improvement of light extraction efficiency from GaN-based light-emitting diodes (LEDs) using Ni(1-x)Co(x)O nanoparticles (NPs) formed on the p-GaN layer. After formation of Ni(1-x)Co(x)O hemispherical lens arrays on the blue LEDs by drop-casting colloidal NPs, electroluminescence (EL) and photoluminescence (PL) measurements are conducted to investigate the electrical and optical properties. The PL and EL intensities from the blue LEDs with the Ni(1-x)Co(x)O NPs are 1.74 and 1.61 times greater, respectively, than a conventional LED. Finally, a hybrid approach using ZnO nanorod arrays grown on the NiCoO hemispherical lens shows further increase of light extraction by 3.8 and 6.2 times compared to LEDs with bare NiCoO NPs and without any NPs, respectively. Finite-difference time-domain (FDTD) simulation results also agree well with the experimental results. The enhancement of light extraction from LEDs with ZnO nanorods and NiCoO NPs can be attributed to an enlarged escape angle cone and increased probability of light scattering.

Structural and optical property studies on indium doped ZnO nanostructures for solution based organic-inorganic hybrid p-n junctions.

In doped ZnO nanocrystallites have established through a facile, low cost and high yield wet-chemical route. The X-ray diffraction measurements revealed the samples to be well crystallized, with a considerable shift in the prominent peak positions, indicating the successful substitution of In ions into the ZnO matrix. The particulate characteristic of the nanostructures was evaluated through the aid of electron microscopes, which revealed both the pristine and In doped ZnO nanocrystals to possess similar morphologies. The UV-vis absorption spectroscopic measurements revealed the doping of In(3+) ions to lead with a red shift in the absorption edge of ZnO nanostructures. The Raman measurements provided conclusive evidence for the substitution of In ions at the Zn sites and their influence on the hexagonal lattice. The hybrid heterostructures made up of polypyrrole/ZnO and polypyrrole/Zn(1-x)In(x)O were established via drop casting a colloidal dispersion containing the prepared nanocrystallites and subsequently chemically in situ polymerizing the pyrrole monomers on the drop casted electrodes. The hybrid p-n junctions were then evaluated using the current-voltage characteristics.

Less strained and more efficient GaN light-emitting diodes with embedded silica hollow nanospheres.

Light-emitting diodes (LEDs) become an attractive alternative to conventional light sources due to high efficiency and long lifetime. However, different material properties between GaN and sapphire cause several problems such as high defect density in GaN, serious wafer bowing, particularly in large-area wafers, and poor light extraction of GaN-based LEDs. Here, we suggest a new growth strategy for high efficiency LEDs by incorporating silica hollow nanospheres (S-HNS). In this strategy, S-HNSs were introduced as a monolayer on a sapphire substrate and the subsequent growth of GaN by metalorganic chemical vapor deposition results in improved crystal quality due to nano-scale lateral epitaxial overgrowth. Moreover, well-defined voids embedded at the GaN/sapphire interface help scatter lights effectively for improved light extraction, and reduce wafer bowing due to partial alleviation of compressive stress in GaN. The incorporation of S-HNS into LEDs is thus quite advantageous in achieving high efficiency LEDs for solid-state lighting.

Enhancement of photoluminescence intensity of GaN-based light-emitting diodes with coated polystyrene/silica core-shell nanostructures.

We report the enhancement of the photoluminescence (PL) intensity of GaN-based light-emitting diode (LED) structures by using of a surface coating of polystyrene (PS)/silica (SiO2) core-shell nanospheres. PS/SiO2 core-shell nanosphere-coated LEDs show the highest PL intensity among various type LEDs. The relative PL intensity of PS/SiO2 core-shell nanosphere-coated LEDs increased by 10% and 14% compared with that of LEDs coated with only SiO2 nanospheres and conventional LEDs without any nanostructures, respectively. Moreover, the theoretically investigated results using finite-difference time-domain (FDTD) simulations show the 1.33 times improvement of total intensity integrated over the measured sample coated by PS/SiO2 core-shell nanospheres than that of a conventional LED without the coating of nanospheres, which corresponds to the experimentally observed results. The enhancement in PL intensity using PS/SiO2 core-shell nanostructures can be attributed to the improvement in light extraction efficiency by both increasing the probability of light escape by reducing Fresnel reflection and by multiple scattering within the core-shell nanospheres.

Vertical array of ZnO submicrorods on periodically polarity-inverted templates using solution method.

Vertically aligned ZnO nano/submicrorods are grown on periodically polarity-inverted (PPI) ZnO templates by a solution-based growth method without any catalyst. For the selective growth of ZnO submicrorods, PPI ZnO structures are used for templates made by using a polarity control technique of ZnO with CrN and Cr2O3 intermediate layers. After syntheses of ZnO nanostructures on PPI ZnO, the vertically aligned ZnO rods were grown only onto the Zn-polar regions.

Catalyst-free metal-organic chemical vapor deposition growth of InN nanorods.

We demonstrated the successful growth of catalyst-free InN nanorods on (0001) Al2O3 substrates using metal-organic chemical vapor deposition. Morphological evolution was significantly affected by growth temperature. At 710 degrees C, complete InN nanorods with typical diameters of 150 nm and length of approximately 3.5 microm were grown with hexagonal facets. theta-2theta X-ray diffraction measurement shows that (0002) InN nanorods grown on (0001) Al2O3 substrates were vertically aligned along c-axis. In addition, high resolution transmission electron microscopy indicates the spacing of the (0001) lattice planes is 0.28 nm, which is very close to that of bulk InN. The electron diffraction patterns also revealed that the InN nanorods are single crystalline with a growth direction along (0001) with (10-10) facets.

Second harmonic generation in periodically polarity-inverted zinc oxide.

We report on the second harmonic generation (SHG) in 2D periodically polarity-inverted (PPI) ZnO heterostructures. The grating structures with nanometer-scale periodicity are fabricated on (0001) Al(2)O(3) substrates by using the in situ polarity inversion method. The achievements of SHG with grating in fabricated PPI ZnO structures are demonstrated under consideration of quasi phase matching conditions. In general, grating formation using the this periodical array of differnet polar surface can be extended to the other heteroepitaxial systems with polarity characteristics.

Lateral arrays of vertical ZnO nanowalls on a periodically polarity-inverted ZnO template.

Well aligned ZnO nanowall arrays with submicron pitch were grown on a periodically polarity-inverted ZnO template using a carbothermal reduction process. Under the conditions of a highly dense Au catalyst for increasing nucleation sites, ZnO nanowalls with a thickness of 126 +/- 10 nm, an average height of 3.4 microm, and a length of about 10 mm were formed on the template. The nanowalls were only grown on a Zn-polar surface due to a different growth mode with an O-polar surface. The results of x-ray diffraction and photoluminescence (PL) measurements revealed a single crystalline, vertical alignment on the template, and a large surface to volume ratio of the ZnO nanowalls.