Designing an Effective and Scalable UV-Protective Cooling Textile with Nanoporous Fibers.

Although radiative cooling concepts guarantee reduction of air conditioning energy consumption by maximizing the scattering of solar radiation and dissipation of thermal radiation of a human body or building, large-scale implementation is challenging due to the need of radical adaptation in manufacturing processes, materials, and design. Here, we introduce an extremely thin layer of nanoporous microfibers without any additional materials or post-treatments. The optical and thermal effectiveness of porous fibers are presented to report a nondisruptive method of preventing the transmission of energy-intensive radiation such as ultraviolet radiation (UV) through textiles. Results show ∼1.4 °C cooling by adding 1 g/m2 (GSM) of porous fibers on a 160 GSM cotton t-shirt, and 91% of UV was prevented with 7.5 GSM of a porous fiber mat. This minimalistic additive approach would widen the scope of optical and radiative cooling research and accelerate both functional and sustainable materials research to be more accessible.

Highly Sunlight Reflective and Infrared Semi-Transparent Nanomesh Textiles.

Radiative cooling in textiles is one of the important factors enabling cooling of the human body for thermal comfort. In particular, under an intense sunlight environment such as that experienced with outdoor exercise and sports activities, high near-infrared (NIR) reflectance to block sunlight energy influx along with high IR transmittance in textiles for substantial thermal emission from the human body would be highly desirable. This investigation demonstrates that a nanoscale geometric control of textile structure alone, instead of complicated introduction of specialty polymer materials and composites, can enable such desirable NIR and IR optical properties in textiles. A diameter-dependent Mie scattering event in fibers and associated optical and thermal behavior were simulated in relation to a nonwoven, nanomesh textile. As an example, a nanomesh structure made of PVDF (polyvinylidene fluoride) electrospun fibers with ∼600 nm average diameter was examined, which exhibited a significant radiative cooling performance with over 90% solar and NIR reflectance to profoundly block the sunlight energy influx as well as ∼50% IR transmittance for human body radiative heat dissipation. An extraordinary cooling effect, as much as 12 °C, was obtained on a simulated skin compared to the normal textile fabric materials. Such a powerful radiative cooling performance together with IR transmitting capability by the nanomesh textile offers a way to efficiently manage sunlight radiation energy to make persons, devices, and transport vehicles cooler and help to save energy in an outdoor sunlight environment as well as indoor conditions.

Cross-Linker-Controlled Ostwald Ripening in Emulsion Polymerization of Hollow Copolymer Nanoparticles.

We propose a synthesis method for hollow copolymer nanoparticles, in which the size is controllable by the wettability of the materials designed by relative energy difference (RED). We investigated the influence of cross-linkers in RED and the hollow polymer nanoparticle synthesis. The size of the nanoparticles was characterized by scanning electron microscopy and transmission electron microscopy images. The diameter size of the hollow copolymer (styrene-co-methyl methacrylate) changes from 400 to 141 nm and the average core-vacancy sizes changes from 330 to 71 nm as increasing the feed ratio of the cross-linker, divinyl benzene, from 0.07 to 0.43. Cross-linkers in polymerization precipitates a polymerization reaction to produce seed copolymer particles quickly. The seed copolymer is a more transferrable medium through the surfactants across emulsion droplets and inhibits emulsion growth by unstable concentration variations of seed copolymers in emulsions. Therefore, Ostwald ripening was reduced by a higher feeding ratio of the cross-linker in the copolymer, which tends to produce smaller sized hollow nanoparticles.

Size-Controllable, Single-Step, and Scalable Synthesis of Hollow Polymer Nanoparticles.

Hollow polymer nanoparticles are of great importance in various industrial fields such as drug delivery vehicles in pharmaceutics, high thermal insulation materials for heat flow blocking and energy savings, and materials with unique optical properties. While the fabrication methods for hollow polymer nanoparticles have been studied and developed by numerous researchers, most synthesis methods require a rather complicated process, including a thorough core-washing step to formulate pores inside the particles. Single-step synthesis methods were developed to overcome this practical issue by utilizing the sacrificial solvent filling the pores temporarily and having it naturally evaporate without further process; however, such processes could not produce sub-200 nm diameter particles, which limit the application for high surface area applications. Herein, we have developed an innovative synthesis method that can overcome the particle size limitation by utilizing a sacrificial solvent for pore formation and a recondensation inhibitor. Pseudo-state Ostwald ripening was realized by selecting the sacrificial solvent with less affinity to the copolymer of hollow polymer particles, thus inhibiting the particle growth during polymerization. We have successfully obtained 120 nm diameter hollow PS-PMMA copolymer particles in large quantity via the single-step preparation of emulsion polymerization.