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1.
Sci Total Environ ; 922: 171215, 2024 Apr 20.
Artigo em Inglês | MEDLINE | ID: mdl-38428611

RESUMO

Exposure to heat poses a pressing challenge in cities, with uneven health and environmental impacts across the urban fabric. To assess disparities in heat vulnerability and its environmental justice implications, we model supply-demand mismatches for the ecosystem service (ES) urban temperature regulation. We integrated remote sensing, health, and socio-demographic data with Artificial Intelligence for Environment and Sustainability (ARIES) and geographical information system tools. We computed composite indicators at the census tract level for urban cooling supply, and vulnerability to heat as a measure of demand. We do so in the context of the mid-size city of Vitoria-Gasteiz, Basque Country (Europe). We mapped relative mismatches after identifying and analysed their relationship with socio-demographic and health factors. Our findings show disparities in heat vulnerability, with increased exposure observed among socio-economically disadvantaged communities, the elderly, and people with health issues. Areas associated with higher income levels show lower ES mismatches, indicating higher temperature regulation supply and reduced heat vulnerability. The results point at the need for nature-based heat mitigation interventions that especially focus on the more socio-economically disadvantaged communities.


Assuntos
Ecossistema , Temperatura Alta , Humanos , Idoso , Inteligência Artificial , Cidades , Temperatura Baixa
2.
Bioscience ; 74(1): 25-43, 2024 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-38313563

RESUMO

In this article, we present results from a literature review of intrinsic, instrumental, and relational values of nature conducted for the Intergovernmental Science-Policy Platform on Biodiversity and Ecosystem Services, as part of the Methodological Assessment of the Diverse Values and Valuations of Nature. We identify the most frequently recurring meanings in the heterogeneous use of different value types and their association with worldviews and other key concepts. From frequent uses, we determine a core meaning for each value type, which is sufficiently inclusive to serve as an umbrella over different understandings in the literature and specific enough to help highlight its difference from the other types of values. Finally, we discuss convergences, overlapping areas, and fuzzy boundaries between different value types to facilitate dialogue, reduce misunderstandings, and improve the methods for valuation of nature's contributions to people, including ecosystem services, to inform policy and direct future research.

3.
Science ; 382(6666): 41-43, 2023 10 06.
Artigo em Inglês | MEDLINE | ID: mdl-37796998

RESUMO

Resilience-based and service-focused approaches could reduce contentions and injustices.

4.
Nature ; 620(7975): 813-823, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37558877

RESUMO

Twenty-five years since foundational publications on valuing ecosystem services for human well-being1,2, addressing the global biodiversity crisis3 still implies confronting barriers to incorporating nature's diverse values into decision-making. These barriers include powerful interests supported by current norms and legal rules such as property rights, which determine whose values and which values of nature are acted on. A better understanding of how and why nature is (under)valued is more urgent than ever4. Notwithstanding agreements to incorporate nature's values into actions, including the Kunming-Montreal Global Biodiversity Framework (GBF)5 and the UN Sustainable Development Goals6, predominant environmental and development policies still prioritize a subset of values, particularly those linked to markets, and ignore other ways people relate to and benefit from nature7. Arguably, a 'values crisis' underpins the intertwined crises of biodiversity loss and climate change8, pandemic emergence9 and socio-environmental injustices10. On the basis of more than 50,000 scientific publications, policy documents and Indigenous and local knowledge sources, the Intergovernmental Platform on Biodiversity and Ecosystem Services (IPBES) assessed knowledge on nature's diverse values and valuation methods to gain insights into their role in policymaking and fuller integration into decisions7,11. Applying this evidence, combinations of values-centred approaches are proposed to improve valuation and address barriers to uptake, ultimately leveraging transformative changes towards more just (that is, fair treatment of people and nature, including inter- and intragenerational equity) and sustainable futures.


Assuntos
Ecossistema , Justiça Ambiental , Política Ambiental , Objetivos , Desenvolvimento Sustentável , Humanos , Biodiversidade , Desenvolvimento Sustentável/economia , Política Ambiental/economia , Mudança Climática
5.
Dalton Trans ; 52(26): 9090-9096, 2023 Jul 04.
Artigo em Inglês | MEDLINE | ID: mdl-37338004

RESUMO

The tandem isomerization-hydrosilylation reaction is a highly valuable process able to transform mixtures of internal olefins into linear silanes. Unsaturated and cationic hydrido-silyl-Rh(III) complexes have proven to be effective catalysts for this reaction. Herein, three silicon-based bidentate ligands, 8-(dimethylsilyl)quinoline (L1), 8-(dimethylsilyl)-2-methylquinoline (L2) and 4-(dimethylsilyl)-9-phenylacridine (L3), have been used to synthesize three neutral [RhCl(H)(L)PPh3] (1-L1, 1-L2 and 1-L3) and three cationic [Rh(H)(L)(PPh3)2][BArF4] (2-L1, 2-L2 and 2-L3) Rh(III) complexes. Among the neutral compounds, 1-L2 could be characterized in the solid state by X-ray diffraction showing a distorted trigonal bipyramidal structure. Neutral complexes (1-L1, 1-L2 and 1-L3) failed to catalyze the hydrosilylation of olefins. On the other hand, the cationic compound 2-L2 was also characterized by X-ray diffraction showing a square pyramidal structure. The unsaturated and cationic Rh(III) complexes 2-L1, 2-L2 and 2-L3 showed significant catalytic activity in the hydrosilylation of remote alkenes, with the most sterically hindered (2-L2) being the most active one.

6.
Inorg Chem ; 62(7): 3095-3105, 2023 Feb 20.
Artigo em Inglês | MEDLINE | ID: mdl-36757389

RESUMO

Siloxanes and silanols containing Si-H units are important building blocks for the synthesis of functionalized siloxane materials, and their synthesis is a current challenge. Herein, we report the selective synthesis of hydrosilanols, hydrosiloxanes, and silanodiols depending on the nature of the catalysts and the silane used. Two neutral ({MCl[SiMe2(o-C6H4PPh2)]2}; M = Rh, Ir) and two cationic ({M[SiMe2(o-C6H4PPh2)]2(NCMe)}[BArF4]; M = Rh, Ir) have been synthesized and their catalytic behavior toward hydrolysis of secondary silanes has been described. Using the iridium complexes as precatalysts and diphenylsilane as a substrate, the product obtained is diphenylsilanediol. When rhodium complexes are used as precatalysts, it is possible to selectively obtain silanediol, hydrosilanol, and hydrosiloxane depending on the catalysts (neutral or cationic) and the silane substituents.

7.
Nat Ecol Evol ; 7(1): 51-61, 2023 01.
Artigo em Inglês | MEDLINE | ID: mdl-36443466

RESUMO

Sustaining the organisms, ecosystems and processes that underpin human wellbeing is necessary to achieve sustainable development. Here we define critical natural assets as the natural and semi-natural ecosystems that provide 90% of the total current magnitude of 14 types of nature's contributions to people (NCP), and we map the global locations of these critical natural assets at 2 km resolution. Critical natural assets for maintaining local-scale NCP (12 of the 14 NCP) account for 30% of total global land area and 24% of national territorial waters, while 44% of land area is required to also maintain two global-scale NCP (carbon storage and moisture recycling). These areas overlap substantially with cultural diversity (areas containing 96% of global languages) and biodiversity (covering area requirements for 73% of birds and 66% of mammals). At least 87% of the world's population live in the areas benefitting from critical natural assets for local-scale NCP, while only 16% live on the lands containing these assets. Many of the NCP mapped here are left out of international agreements focused on conserving species or mitigating climate change, yet this analysis shows that explicitly prioritizing critical natural assets and the NCP they provide could simultaneously advance development, climate and conservation goals.


Assuntos
Ecossistema , Planetas , Humanos , Animais , Conservação dos Recursos Naturais , Biodiversidade , Aves , Mamíferos
8.
Proc Natl Acad Sci U S A ; 119(7)2022 02 15.
Artigo em Inglês | MEDLINE | ID: mdl-35131937

RESUMO

Land use is central to addressing sustainability issues, including biodiversity conservation, climate change, food security, poverty alleviation, and sustainable energy. In this paper, we synthesize knowledge accumulated in land system science, the integrated study of terrestrial social-ecological systems, into 10 hard truths that have strong, general, empirical support. These facts help to explain the challenges of achieving sustainability in land use and thus also point toward solutions. The 10 facts are as follows: 1) Meanings and values of land are socially constructed and contested; 2) land systems exhibit complex behaviors with abrupt, hard-to-predict changes; 3) irreversible changes and path dependence are common features of land systems; 4) some land uses have a small footprint but very large impacts; 5) drivers and impacts of land-use change are globally interconnected and spill over to distant locations; 6) humanity lives on a used planet where all land provides benefits to societies; 7) land-use change usually entails trade-offs between different benefits-"win-wins" are thus rare; 8) land tenure and land-use claims are often unclear, overlapping, and contested; 9) the benefits and burdens from land are unequally distributed; and 10) land users have multiple, sometimes conflicting, ideas of what social and environmental justice entails. The facts have implications for governance, but do not provide fixed answers. Instead they constitute a set of core principles which can guide scientists, policy makers, and practitioners toward meeting sustainability challenges in land use.


Assuntos
Agricultura , Conservação dos Recursos Naturais/métodos , Ecossistema , Humanos , Energia Renovável , Mudança Social
9.
PLoS One ; 16(1): e0244619, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-33411756

RESUMO

The social-ecological effects of agricultural intensification are complex. We explore farmers' perceptions about the impacts of their land management and the impact of social information flows on their management through a case study in a farming community in Navarra, Spain, that is undergoing agricultural intensification due to adoption of large scale irrigation. We found that modern technology adopters are aware that their management practices often have negative social-ecological implications; by contrast, more traditional farmers tend to recognize their positive impacts on non-material benefits such as those linked with traditions and traditional knowledge, and climate regulation. We found that farmers' awareness about nature contributions to people co-production and their land management decisions determine, in part, the structure of the social networks among the farming community. Since modern farmers are at the core of the social network, they are better able to control the information flow within the community. This has important implications, such as the fact that the traditional farmers, who are more aware of their impacts on the environment, rely on information controlled by more intensive modern farmers, potentially jeopardizing sustainable practices in this region. We suggest that this might be counteracted by helping traditional farmers obtain information tailored to their practices from outside the social network.


Assuntos
Agricultura , Conservação dos Recursos Naturais , Fazendeiros , Rede Social , Tecnologia , Fazendas , Humanos , Espanha
10.
Science ; 366(6462): 255-258, 2019 10 11.
Artigo em Inglês | MEDLINE | ID: mdl-31601772

RESUMO

The magnitude and pace of global change demand rapid assessment of nature and its contributions to people. We present a fine-scale global modeling of current status and future scenarios for several contributions: water quality regulation, coastal risk reduction, and crop pollination. We find that where people's needs for nature are now greatest, nature's ability to meet those needs is declining. Up to 5 billion people face higher water pollution and insufficient pollination for nutrition under future scenarios of land use and climate change, particularly in Africa and South Asia. Hundreds of millions of people face heightened coastal risk across Africa, Eurasia, and the Americas. Continued loss of nature poses severe threats, yet these can be reduced 3- to 10-fold under a sustainable development scenario.


Assuntos
Produtos Agrícolas , Modelos Teóricos , Natureza , Polinização , Qualidade da Água , África , América , Ásia , Mudança Climática , Conservação dos Recursos Naturais , Países em Desenvolvimento , Ecossistema , Meio Ambiente , Europa (Continente) , Humanos , Poluição da Água
11.
Proc Natl Acad Sci U S A ; 116(45): 22645-22650, 2019 11 05.
Artigo em Inglês | MEDLINE | ID: mdl-31636201

RESUMO

The program on Reducing Emissions from Deforestation and Forest Degradation (REDD+) is one of the major attempts to tackle climate change mitigation in developing countries. REDD+ seeks to provide result-based incentives to promote emission reductions and increase carbon sinks in forest land while promoting other cobenefits, such as the conservation of biodiversity. We model different scenarios of international REDD+ funds distribution toward potential recipient countries using 2 carbon emission reduction targets (20% and 50% compared to the baseline scenario, i.e., deforestation and forest degradation without REDD+) by 2030. The model combines the prioritization of environmental outcomes in terms of carbon sequestration and biodiversity conservation and social equity, accounting for the equitable distribution of international REDD+ funds. Results highlight the synergy between carbon sequestration and biodiversity conservation under alternative fund allocation criteria, especially for scenarios of low carbon emission reduction. Trade-offs increase when distributional equity is considered as an additional criterion, especially under higher equity requirements. The analysis helps to better understand the inherent trade-offs between enhancing distributional equity and meeting environmental targets under alternative REDD+ fund allocation options.


Assuntos
Sequestro de Carbono , Conservação dos Recursos Naturais/economia , Biodiversidade , Mudança Climática , Administração Financeira/economia , Florestas , Modelos Econométricos , Árvores/crescimento & desenvolvimento
12.
Bioscience ; 69(3): 191-197, 2019 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-30914829

RESUMO

The Convention on Biological Diversity Aichi Target 11 requires its 193 signatory parties to incorporate social equity into protected area (PA) management by 2020. However, there is limited evidence of progress toward this commitment. We surveyed PA managers, staff, and community representatives involved in the management of 225 PAs worldwide to gather information against 10 equity criteria, including the distribution of benefits and burdens, recognition of rights, diversity of cultural and knowledge systems, and processes of participation in decision-making. Our results show that more than half of the respondents indicated that there are still significant challenges to be addressed in achieving equitably managed PAs, particularly in ensuring effective participation in decision-making, transparent procedures, access to justice in conflicting situations, and the recognition of the rights and diversity of local people. Our findings are a first and fundamental contribution toward a global assessment of equitable management in PAs to report on Aichi Target 11 in 2020 and help define the next set of PA targets from 2020-2030.

13.
Sustain Sci ; 13(6): 1519-1531, 2018.
Artigo em Inglês | MEDLINE | ID: mdl-30546485

RESUMO

Sustainability is a key challenge for humanity in the context of complex and unprecedented global changes. Future Earth, an international research initiative aiming to advance global sustainability science, has recently launched knowledge-action networks (KANs) as mechanisms for delivering its research strategy. The research initiative is currently developing a KAN on "natural assets" to facilitate and enable action-oriented research and synthesis towards natural assets sustainability. 'Natural assets' has been adopted by Future Earth as an umbrella term aiming to translate and bridge across different knowledge systems and different perspectives on peoples' relationships with nature. In this paper, we clarify the framing of Future Earth around natural assets emphasizing the recognition on pluralism and identifying the challenges of translating different visions about the role of natural assets, including via policy formulation, for local to global sustainability challenges. This understanding will be useful to develop inter-and transdisciplinary solutions for human-environmental problems by (i) embracing richer collaborative decision processes and building bridges across different perspectives; (ii) giving emphasis on the interactions between biophysical and socioeconomic drivers affecting the future trends of investments and disinvestments in natural assets; and (iii) focusing on social equity, power relationships for effective application of the natural assets approach. This understanding also intends to inform the scope of the natural asset KAN's research agenda to mobilize the translation of research into co-designed action for sustainability.

16.
Ambio ; 45(Suppl 3): 335-351, 2016 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-27878532

RESUMO

This paper examines climate change adaptation and gender issues through an application of a feminist intersectional approach. This approach permits the identification of diverse adaptation responses arising from the existence of multiple and fragmented dimensions of identity (including gender) that intersect with power relations to shape situation-specific interactions between farmers and ecosystems. Based on results from contrasting research cases in Bihar and Uttarakhand, India, this paper demonstrates, inter alia, that there are geographically determined gendered preferences and adoption strategies regarding adaptation options and that these are influenced by the socio-ecological context and institutional dynamics. Intersecting identities, such as caste, wealth, age and gender, influence decisions and reveal power dynamics and negotiation within the household and the community, as well as barriers to adaptation among groups. Overall, the findings suggest that a feminist intersectional approach does appear to be useful and worth further exploration in the context of climate change adaptation. In particular, future research could benefit from more emphasis on a nuanced analysis of the intra-gender differences that shape adaptive capacity to climate change.


Assuntos
Adaptação Psicológica , Mudança Climática , Identidade de Gênero , Meio Social , Agricultura , Meio Ambiente , Feminino , Humanos , Índia , Masculino
17.
Ambio ; 45(Suppl 3): 235-247, 2016 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-27878533

RESUMO

The main goal of this special issue is to offer a room for interdisciplinary and engaged research in global environmental change (GEC), where gender plays a key role in building resilience and adaptation pathways. In this editorial paper, we explain the background setting, key questions and core approaches of gender and feminist research in vulnerability, resilience and adaptation to GEC. Highlighting the interlinkages between gender and GEC, we introduce the main contributions of the collection of 11 papers in this special issue. Nine empirical papers from around the globe allow to understand how gendered diversity in knowledge, institutions and everyday practices matters in producing barriers and options for achieving resilience and adaptive capacity in societies. Additionally, two papers contribute to the theoretical debate through a systematic review and an insight on the relevance of intersectional framings within GEC research and development programming.


Assuntos
Mudança Climática , Meio Ambiente , Identidade de Gênero , Pesquisa , Adaptação Psicológica , Feminismo , Humanos
18.
Ambio ; 45(Suppl 3): 373-382, 2016 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-27878538

RESUMO

Most current approaches focused on vulnerability, resilience, and adaptation to climate change frame gender and its influence in a manner out-of-step with contemporary academic and international development research. The tendency to rely on analyses of the sex-disaggregated gender categories of 'men' and 'women' as sole or principal divisions explaining the abilities of different people within a group to adapt to climate change, illustrates this problem. This framing of gender persists in spite of established bodies of knowledge that show how roles and responsibilities that influence a person´s ability to deal with climate-induced and other stressors emerge at the intersection of diverse identity categories, including but not limited to gender, age, seniority, ethnicity, marital status, and livelihoods. Here, we provide a review of relevant literature on this topic and argue that approaching vulnerability to climate change through intersectional understandings of identity can help improve adaptation programming, project design, implementation, and outcomes.


Assuntos
Adaptação Psicológica , Agricultura/métodos , Mudança Climática , Países em Desenvolvimento , Identidade de Gênero , Feminino , Humanos , Masculino , Pesquisa
20.
PLoS One ; 11(2): e0148087, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-26845694

RESUMO

Q is a semi-qualitative methodology to identify typologies of perspectives. It is appropriate to address questions concerning diverse viewpoints, plurality of discourses, or participation processes across disciplines. Perspectives are interpreted based on rankings of a set of statements. These rankings are analysed using multivariate data reduction techniques in order to find similarities between respondents. Discussing the analytical process and looking for progress in Q methodology is becoming increasingly relevant. While its use is growing in social, health and environmental studies, the analytical process has received little attention in the last decades and it has not benefited from recent statistical and computational advances. Specifically, the standard procedure provides overall and arguably simplistic variability measures for perspectives and none of these measures are associated to individual statements, on which the interpretation is based. This paper presents an innovative approach of bootstrapping Q to obtain additional and more detailed measures of variability, which helps researchers understand better their data and the perspectives therein. This approach provides measures of variability that are specific to each statement and perspective, and additional measures that indicate the degree of certainty with which each respondent relates to each perspective. This supplementary information may add or subtract strength to particular arguments used to describe the perspectives. We illustrate and show the usefulness of this approach with an empirical example. The paper provides full details for other researchers to implement the bootstrap in Q studies with any data collection design.


Assuntos
Modelos Teóricos , Algoritmos , Humanos
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