RESUMO
The new 2,3-diphenylquinoxalin-6-amine (dpqa) was designed and synthesized through an efficient and high yield condensation process. Data from FTIR and 1H-NMR spectroscopy have been adopted to ascertain the molecular structure of benzoxazine compounds. Furthermore, the quinoxaline amine based benzoxazine (BA-dpqa) was synthesized using bisphenol-A and paraformaldehyde followed by combining different weight percentages (1, 5 and 10 wt%) of (3-glycidyloxypropyl)trimethoxysilane functionalized CNT-PbS with benzoxazine to obtain nanocomposites. The thermal and morphological properties of the quinoxaline amine based neat polybenzoxazine matrix poly(BA-dpqa) and CNT-PbS/poly(BA-dpqa) composites were analysed by XRD, TGA and SEM analysis. The values of the degradation temperature (Td) obtained for neat poly(BA-dpqa) and 10 wt% CNT-PbS/poly(BA-dpqa) composites are 414 °C and 424 °C. Furthermore, the chair yield percentage was calculated as 33% and 35% respectively. The water contact angle of polybenzoxazine gradually increased from 89° to 127° proportional to the content of CNT-PbS. Among the composites, 10 wt% CNT-PbS reinforced poly(BA-dpqa) nanocomposites possess higher dielectric constant (k = 11.0) than other composites. The pseudocapacitor nature of the prepared electrodes is demonstrated by the good electrochemical performance according to the CV curve. Also, the prepared 10 wt% CNT-PbS/poly(BA-dpqa) (637 F g-1 at 5 A g-1 and 11.8 Ω) electrode shows better capacitance and lower charge transfer resistance values than 5 wt% CNT-PbS/poly(BA-dpqa) (613 F g-1 at 5 A g-1 and 13.2 Ω) and neat poly(BA-dpqa) (105 F g-1 at 5 A g-1 and 15.6 Ω) according to the charge/discharge curves and EIS spectra. 10 wt% CNT-PbS/poly(BA-dpqa) shows 99.2% cycling efficiency even at the 2000th cycle, which indicates the good electrochemical performance of the prepared electrode.
RESUMO
In this research, an electrochemical sensor was fabricated employing the metal-organic framework (MOF) deposited glassy carbon electrode (GCE) for the sensing copper ions in water with high sensitivity. The porous nanostructured MOF was characterized through Transmission electron microscope, scanning electron microscope and X-ray diffraction analysis. The Bi-MOF nanostructure deposited GCE (Bi-MOF/GCE) was fabricated by drop-casting a suspension of Bi-MOF in water on GCE surface. The performance of modified electrode in the presence and absence of heavy metal ions such as Cd2+, Hg2+ As3+, Pb2+ and Cu2+ was determined by the cyclic voltammetry in deionised water within the scan rate range of 25 and 300 mVs-1. The Bi-MOF/GCE displayed highest anodic and cathodic peak current for Cu2+ ions than other metal ions, which was enhanced linearly within the scan rate range of 10-100 mV s-1. Under the employed experimental conditions, the fabricated Bi-MOF/GCE based electrochemical sensor showed an outstanding routine in the determination of copper with a lowest sensing limit of 1 × 10-5 M, wide linear range variation, strong interaction between metal ions and Bi-MOF. It has long-term stability and good reproducibility. The Bi-MOF/GCE electrode was successfully tested to detect Cu2+ in tap water with acceptable results.
