Elastomer-Based Sealing O-Rings and Their Compatibility with Methanol, Ethanol, and Hydrotreated Vegetable Oil for Fueling Internal Combustion Engines.

Green methanol, ethanol, and diesel-based hydrotreated vegetable oils are some of the renewable liquid fuels that show satisfactory performance in diesel engines. A notable advantage of these fuels is that they are renewable and do not require significant modifications in the existing engines for successful operation. Suitable fuel systems, especially their material compatibility, remain unresolved, and therefore, it is a weak link in their large-scale adaptation. Elastomer-based sealing O-rings lose their mechanical properties after a short exposure time to these fuels, adversely impacting their functionality. This research study evaluated the long-term material compatibility of different elastomer-based sealing materials by immersing the O-rings in these test fuels (hydrotreated vegetable oil, methanol, ethanol, and diesel) for different time intervals (i.e., up to 15 months). The material compatibility was assessed mainly by investigating these changes in various mechanical properties of these O-rings, namely tensile strength (ΔTs), elongation at break (ΔEb), Shore A hardness (ΔH), and mass (ΔM). The degradation of mechanical properties was studied and analyzed during the immersion interval from 0.9 to 15.2 months and compared with O-rings kept in a normal atmosphere. It was noted that individual fuels affect various mechanical properties significantly. In a short interval of 0.9 months (28 days), significant changes in the mechanical properties of the sealing O-rings were observed.

Research on the Material Compatibility of Elastomer Sealing O-Rings.

Significant attention has been paid to combustion engines for the utilization of new liquid fuels and their testing at the present. Research activities in ensuring the optimum function of the engine by watching sealing and distribution rubber elements, which are part of fuel systems, should be an integral part of fuels research. When evaluating fuels utilization in combustion engines, the issue has to be judged in a complex. However, when using biofuels in combustion engines, it is not always simple owing to the different degradation properties of these products. Elastomer material is not entirely resistant to various types of fuels. More or less, it is possible to expect changes in its mechanical properties. For the evaluation of the functionality of elastomer sealing elements based on ACM, HNBR and FVMQ type O-rings with pure and blended fuels, the evaluation of changes in mass, hardness Shore A, permanent deformation CS, tensile strength TS and deformation Eb after immersion with the tested fuel is mainly used. Permanent changes were found by the tests. The degradation of elastomer O-rings was more pronounced for the tested fuels containing ethanol, iso-butanol, n-butanol, methanol and dodecanol. HVO 100 fuel containing hydrotreated vegetable oil did not show significant degradation of elastomer O-ring seals. Of the O-rings tested, the FVMQ type O-rings showed the best performance in terms of material compatibility for all fuels tested.

Material Utilization of Cotton Post-Harvest Line Residues in Polymeric Composites.

This paper deals with a research focused on utilization of microparticle and short-fiber filler based on cotton post-harvest line residues in an area of polymeric composites. Two different fractions of the biological filler (FCR-reinforced cotton filler) of 20 and 100 µm and the filler with short fibers of a length of 700 µm were used in the research. The aim of the research was to evaluate mechanical characteristics of composites and adhesive bonds for the purpose of gaining new pieces of knowledge which will be applicable in the area of material engineering and assessing application possibilities of residues coming into being from agricultural products processing. Mechanical properties of the composite material produced by a vacuum infusion and tested at temperatures 20, 40, and 60 °C and adhesive bonds which were exposed to a low-cyclic loading, i.e., 1000 cycles at 30% to 70% from reference value of the maximum strength, were evaluated. Composite systems with the FCR adjusted in 5% water solution of NaOH showed higher strength values on average compared to untreated FCR. Unsuitable size of the FCR led to a deterioration of the strength. The filler in the form of 700 FCR microfibers showed itself in a positive way to composite materials, and the particle in the form of 20 FCR did the same to adhesive bonds. Results of adhesive bond cyclic tests at higher stress values (70%) demonstrated viscoelastic behavior of the adhesive layer.