Co2+-adsorbed chitosan-grafted-poly(acrylic acid) hydrogel as peroxymonosulfate activator for effective dye degradation.

In this work, chitosan-grafted-poly(acrylic acid) (CS-g-PAA) was synthesized for use as a Co2+ adsorbent and circularly utilized as a peroxymonosulfate (PMS) activator in the degradation of rhodamine B (RhB) dye. CS-g-PAA demonstrated 3.7 times higher adsorption capacity toward Co2+ than pristine chitosan. The impact of the adsorption conditions was evaluated. The pseudo-second-order kinetic model and the Langmuir isotherm model best described the adsorption process. Under optimum conditions, the adsorption capacity of CS-g-PAA for Co2+ was 212 mg/g. The Co2+-adsorbed CS-g-PAA hydrogel was further utilized in the RhB degradation process. The effects of catalyst dosage, initial RhB concentration, pH, and the coexistence of anions on the degradation of RhB were studied. The hydrogel catalyst could remove 98 % of RhB within 5 min, at a degradation rate of 0.624 per min. Electron paramagnetic resonance (EPR) analysis and the radical scavenger experiment suggested that SO4•-, HO•, 1O2, and O2•- were involved in the degradation. Furthermore, when tested in various water systems, high degradation efficiencies of 98 % were attained after 20 min. The hydrogel catalyst performed excellent degradation over ten cycles without any chemical recovery processes. Moreover, high degradation efficiencies were observed between 95 % and 98 % when tested with other dyes.

Chitosan-grafted hydrogels for heavy metal ion adsorption and catalytic reduction of nitroaromatic pollutants and dyes.

Chitosan-grafted-poly(acrylic acid) (CS-g-PAA) and chitosan-grafted- poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (CS-g-P(AA-co-AMPS)) hydrogels were synthesized and then employed as adsorbents for the effective removal of Cu2+ and other heavy metal ions. The effect of hydrogel's composition on the Cu2+ adsorption was explored. The CS-g-PAA hydrogel demonstrated a superior adsorption capacity compared to pristine CS, PAA hydrogel, and CS-g-P(AA-co-AMPS) hydrogels. The adsorption followed the Langmuir isotherm model, and the pseudo-second order kinetic model. Additionally, the CS-g-PAA hydrogel exhibited relatively high adsorption performances toward Cr3+, Co2+, Ni2+, Pb2+, and Zn2+. Metal ions adsorbed within CS-g-PAA hydrogels underwent reduction to their corresponding metallic states and were reutilized as catalysts for the reduction of 4-nitrophenol. The comparative catalytic performances of the metal species in the hydrogel were in the order of Cu > Ni > Co > Zn. The reduction efficiency of Cu-CS-g-PAA increased with increased catalyst dosage, NaBH4 concentration, and temperature. A very low activation energy of 3.7 kJ/mol was observed. The catalyst maintained high catalytic performance even when subjected to real water samples and proved its reusability for up to three cycles. Moreover, the catalyst could effectively reduce 2-nitrophenol and methyl orange.

Poly(acrylic acid-co-2-acrylamido-2-methyl-1-propanesulfonic acid)-grafted chitosan hydrogels for effective adsorption and photocatalytic degradation of dyes.

As a result of the growth of industrialization and urbanization, the water ecosystem is contaminated by various pollutants, including heavy metal ions and dyes. The use of low-cost and environmentally friendly dye adsorbents has been investigated. A hydrogel was fabricated via graft polymerization of acrylic acid (AA) and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) onto chitosan. The hydrogel was used as a dye adsorbent and support for a zinc oxide (ZnO) powder photocatalyst. The adsorption capacity of the bare hydrogel was greater towards cationic dyes than anionic dyes. Grafting P(AA-co-AMPS) exhibited a 23-time increase in adsorption capacity towards crystal violet (CV) compared to pristine chitosan. The effect of the AA-AMPS molar ratio on CV adsorption was studied. A hydrogel with an AA-AMPS ratio of 10 : 1 had the highest adsorption capacity towards CV in water, removing 91% of the dye in 12 h. The maximum adsorption capacity was 2023 mg g-1. The adsorption kinetics and isotherm were described by the pseudo-second-order model and the Langmuir model, respectively. ZnO particles were in situ synthesized within the 10 : 1 hydrogel to facilitate the recovery of the photocatalyst. The ZnO hydrogel composite could remove 95% and 92% of CV from solutions on the 1st and 2nd cycle, respectively. In addition, the hydrogel composite containing only 8.7 wt% of ZnO particles effectively degraded adsorbed CV under sunlight and could be reused without requiring a chemical regeneration or photocatalyst recovery procedure. This hydrogel composite is an effective dual-functional material for the adsorption and photodegradation of dye pollutants in wastewater.

Composite beads from chitosan and zeolitic imidazolate framework-8 for the adsorption and photocatalytic degradation of reactive red 141.

This study describes the fabrication of composite beads comprising chitosan and zeolitic imidazolate framework-8 (ZIF-8) as a natural biodegradable dye adsorbent and support for ZnO photocatalyst. Chitosan beads were cross-linked with trisodium citrate dihydrate to enhance the adsorption capacity for the reactive red 141 dye (RR141). The ability was further improved by adding ZIF-8. The optimum loading was 2.5%, and the adsorption equilibrium was reached within 2 h. The maximum adsorption capacity of the composite beads was 6.51 mg g-1 at pH 4 when an initial concentration of 1000 mg L-1 was used. The pseudo-second-order kinetics model and the Langmuir isotherm model best described the adsorption process. The composite beads could also adsorb dyes like reactive black, Congo red, direct yellow, reactive orange, rhodamine B, crystal violet, and methylene blue (MB). Thermal stability was significantly improved after coating the surface of the 2.5% ZIF beads with a ZnO photocatalyst. After UV irradiation for 5 h, the photocatalytic beads containing 2.59 weight percent of ZnO could decolorize 99% of MB and 90% of RR141 dyes with a degradation rate of 0.6032 h-1 and 0.3198 h-1, respectively. Furthermore, the photocatalytic beads remained effective for at least ten consecutive cycles.