Electrospun polyacrylonitrile-Moringa Olifera based nanofibrous bio-sorbent for remediation of Congo red dye.

The integration of polymers with biomaterials offers promising and effective nanomaterials with intrinsic and extrinsic properties that are utilized in several applications. The present work reported the development of Polyacrylonitrile (PAN) supported biosorbent (Moringa oleifera, (MO)) which was utilized for the removal of Congo red (CR) dye from aqueous solution. MO loaded polyacrylonitrile (PAN/MO) nanofibrous biosorbent was prepared by solvent homogenization method followed by electrospinning for the deposition of nanofibers. The developed nanofibrous biosorbent was investigated by several analytical techniques such as FESEM, TEM, XRD, FTIR, and XPS to study the material properties along with their control counterparts. The adsorption experiments such as the effect of contact time, effect of concentration, effect of pH, and reusability studies were performed. The adsorption capacity of the nanofibrous biosorbent is ∼52 mg g-1, which is significant as bulk sorbent when compared with other activated carbon in powder form. The adsorption capacities vary with an increase in the dye concentration and obtained ∼88% of dye removal. The adsorption data are validated using the empirical pseudo-first-order, pseudo-second-order kinetic models, and the mechanism involved in the adsorption phenomena was investigated by Langmuir and Freundlich isotherm models, respectively. The biosorbent follows the pseudo-second-order kinetics and Freundlich isotherm, which involves in multilayer adsorption phenomena. In a nutshell, the present work corroborated the importance of bio-based natural sorbent available in nature which can be effectively engineered with polymeric materials for obtaining novel hybrid materials to explore their inherent properties for various applications.

In-situ growth of manganese oxide on self-assembled 3D- magnesium hydroxide coated on polyurethane: Catalytic oxidation mechanism and application for Mn(II) removal.

Novel integration of adsorption followed by catalytic oxidation is expected to be more beneficial for higher Mn(II) removal performance. We prepared self-assembled 3D flower-like Mg(OH)2 coated on granular-sized polyurethane (namely FMHP) via hydrothermal method at 120 °C under a facile synthesis route. The optimized material, FMHP prepared with 7 g MgO and 20 g polyurethane (FMH0.35P), achieved up to 351.2 mg g-1 Mn(II) removal capacity by Langmuir isotherm model. Besides, FMHP exhibited high Mn(II) removal in a wide range of NaCl concentration (0~0.1 M) and pH 2-9. Notably, through consecutive kinetics, BET, XPS, XRD, FESEM, and TEM analyses, it was found that the MnOx layer grows in-situ via ion exchange with Mg(II) on FMHP and further boosts the Mn(II) removal via catalytic oxidation during the Mn(II) removal process. Further, column experiments revealed that the FMH0.35P exhibited superior Mn(II) removal capacities up to 135.9 mg g-1 and highly compatible treatment costs ($0.062 m-3) compared to conventional chemical processes. The granular-sized FMH0.35P prepared by economic precursors and simple synthesis route revealed a high potential for Mn(II) containing water treatment due to its high removal capacities and easy operation.

Biocatalyst physiology and interplay: a protagonist of MFC operation.

Microbial fuel cells (MFC) have been foreseen as a sustainable renewable energy resource to meet future energy demand. In the past, several studies have been executed in both benchtop and pilot scale to produce electrical energy from wastewater. The key role players in this technology that leads to the operation are microbes, mainly bacteria. The dominant among them is termed as "exoelectrogens" that have the capability to produce and transport electron by utilizing waste source. The current review focuses on such electrogenic bacteria's involvement for enhanced power generation of MFC. The pathway of electron transfer in their cell along and its conduction to the extracellular environment of the MFC system are critically discussed. The interaction of the microbes in various MFC operational conditions, including the role of substrate and solid electron acceptors, i.e., anode, external resistance, temperature, and pH, was also discussed in depth along with biotechnological advancement and future research perspective.

Sonophotocatalytic degradation of bisphenol A and its intermediates with graphitic carbon nitride.

Since bisphenol A (BPA) exhibits endocrine disrupting action and high toxicity in aqueous system, there are high demands to remove it completely. In this study, the BPA removal by sonophotocatalysis coupled with nano-structured graphitic carbon nitride (g-C3N4, GCN) was conducted with various batch tests using energy-based advanced oxidation process (AOP) based on ultrasound (US) and visible light (Vis-L). Results of batch tests indicated that GCN-based sonophotocatalysis (Vis-L/US) had higher rate constants than other AOPs and especially two times higher degradation rate than TiO2-based Vis-L/US. This result infers that GCN is effective in the catalytic activity in Vis-L/US since its surface can be activated by Vis-L to transport electrons from valence band (VB) for utilizing holes (h+VB) in the removal of BPA. In addition, US irradiation exfoliated the GCN effectively. The formation of BPA intermediates was investigated in detail by using high-performance liquid chromatography-mass spectrometry (HPLC/MS). The possible degradation pathway of BPA was proposed.

Titanium dioxide-based sonophotocatalytic mineralization of bisphenol A and its intermediates.

In this study, bisphenol A (BPA) removal by sonophotocatalysis coupled with commercially available titanium dioxide (TiO2, P25) was assessed in batch tests using energy-based advanced oxidation combining ultrasound (US) and ultraviolet (UV). The kinetics of BPA removal were systematically evaluated by changing operational parameters, such as US frequency and power, mechanical stirring speed, and temperature, but also comparison of single and coupled systems under the optimum US conditions (35 kHz, 50 W, 300 rpm stirring speed, and 20 °C). The combination of US/UV/P25 exhibited the highest BPA removal rate (28.0 × 10-3 min-1). In terms of the synergy index, the synergistic effect of sonophotocatalysis was found to be 2.2. This indicated that sonophotocatalysis has a considerably higher removal efficiency than sonocatalysis or photocatalysis. The removal of BPA was further investigated to identify BPA byproducts and intermediates using high-performance liquid chromatography-mass spectrometry. Five main intermediates were formed during sonophotocatalytic degradation, and complete removal of BPA and its intermediates was obtained after 3 h of operation. The degradation pathway of BPA by sonophotocatalysis was also elucidated.

Nano-Structured Magnesium Oxide Coated Iron Ore: Its Application to the Remediation of Wastewater Containing Lead.

Magnetically separable nano-structured magnesium oxide coated iron ore (IO(MgO)) was prepared using environmentally benign chemicals, such as iron ore (IO), magnesium(II) nitrate hexahydrate [Mg(NO3)2 x 6H2O] and urea; via an easy and fast preparation method. The lO(MgO) was characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS) and alternating gradient magnetometer (AGM) analyses. The isotherm and kinetic studies indicated that lO(MgO) has a comparably higher Langmuir constant (K(L), 1.69 L mg(-1)) and maximum sorption capacity (33.9 mg g(-1)) for lead (Pb) than other inorganic media. Based on MgO amount, the removal capacity of Pb by IO(MgO) was 2,724 mg Pb (g MgO)(-1), which was higher than that (1,980 mg g(-1)) for flowerlike magnesium oxide nanostructures reported by Cao et al. The kinetics, FE-SEM, elemental mapping and XRD results revealed that the substitution followed by precipitation was identified as the mechanism of Pb removal and plumbophyllite (Pb2Si4O10 x H2O) was the precipitated phase of Pb. A leaching test revealed that IOMgO) had negligible concentrations of leached Fe at pH 4-9. Since the base material, IO, is cheap and easily available, lO(MgO) could be produced in massive amounts and used for remediation of wastewater containing heavy metals, applying simple and fast magnetic separation.

Synergetic effect of conductive polymer poly(3,4-ethylenedioxythiophene) with different structural configuration of anode for microbial fuel cell application.

PEDOT was synthesized by chemical polymerisation and characterised for its electrochemical insights. Three different anode configuration, namely graphite plate (GP), carbon cloth (CC) and graphite felt (GF) were then loaded with a fixed amount of PEDOT (2.5 mg/m(2)) denoted as GP-P, CC-P and GF-P respectively. The PEDOT coating improved the electrochemical characteristics and electron transfer capabilities of the anodes. They also contributed for enhanced MFC performances with maximum energy generation along with coulombic efficiency than the unmodified anodes. The morphological characteristics like higher surface area and open structure of felt material promoted both microbial formation and electrochemical active area. A maximum current density of 3.5A/m(2) was achieved for GF-P with CE and COD of 51% and 86% respectively. Thus, the GF-P anode excelled among the studied anodes with synergetic effect of PEDOT coating and structural configuration, making it as a potential optimum anode for MFC application.

Enhanced magnetic separation and photocatalytic activity of nitrogen doped titania photocatalyst supported on strontium ferrite.

An enhanced ferromagnetic property, visible light active TiO(2) photocatalyst was successfully synthesized by supporting strontium ferrite (SrFe(12)O(19)) onto TiO(2) doped with nitrogen (N) and compared with N-doped TiO(2). The synthesized catalysts were further characterized with X-ray diffraction (XRD), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy (EDS), BET surface area analysis, vibrating sample magnetometer (VSM), X-ray photon spectroscopy (XPS) and visible light spectroscopy analysis for their respective properties. The XRD and EDS revealed the structural and inorganic composition of N-TiO(2) supported on SrFe(12)O(19). The supported N-TiO(2) exhibited a strong ferromagnetic property with tremendous stability against magnetic property losses. It also resulted in reduced band gap (2.8 eV) and better visible light absorption between 400 and 800 nm compared to N-doped TiO(2). The photocatalytic activity was investigated with a recalcitrant phenolic compound namely 2,4-dichlorophenol (2,4-DCP) as a model pollutant under direct bright and diffuse sunlight exposure. A complete degradation of 2,4-DCP was achieved with an initial concentration of 50mg/L for both photocatalysts in 180 min and 270 min respectively under bright sunlight. Similarly the diffuse sunlight study resulted in complete degradation for supported N-TiO(2) and >85% degradation N-TiO(2), respectively. Finally the supported photocatalyst was separated under permanent magnetic field with a mass recovery ≈ 98% for further reuse.