1.
ChemSusChem
; : e202400545, 2024 Jun 11.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38860859
RESUMO
Mechanochemistry turned out to be a powerful synthetic tool enabling the first efficient synthesis of nickel(II) complexes with diphosphines. It has been demonstrated that solventless ball-milling of nickel(II) halides with diphosphines leads to the [NiX2(diphosphine)] type compounds, which can be directly used in catalysis without any purification. Moreover, it was confirmed that despite the presence of impurities in the resulting complexes, their catalytic activity remains identical to those obtained via traditional solvent-based methods.