Selective Fe(ii)-fluorescence sensor with validated two-consecutive working range using N,S,I-GQDs associated with garlic extract as an auxiliary green chelating agent.

The goal of this work was to use the pyrolysis process to synthesize graphene quantum dots doped with garlic extract (as N,S-GQDs) and simultaneously co-doped with iodine (as I-GQDs). XPS, HR-TEM, FE-SEM/EDX, FT-IR, fluorescence, and UV-visible absorption spectroscopy were used to characterize the N,S,I-GQDs and analyze their morphological images. The quantum yield of N,S,I-GQDs was found to be 45%, greater than that of undoped GQDs (31%). When stimulated at 363 nm, the N,S,I-GQDs display a strong fluorescence intensity at a maximum wavelength of 454 nm. Using N,S,I-GQDs as a fluorescence quenching sensor for screening tests with various metal ions, it was discovered that they are extremely selective towards Fe2+ over Fe3+ and other ions. Thus, solution pH, concentration of N,S,I-GQDs, quantity of garlic extract, EDTA and AgNO3 concentration as masking agents, reaction duration under ultrasonic aid, and tolerable limit of Fe3+ presence in the target analyte were all optimized for Fe2+ detection. A highly sensitive detection of Fe2+ was obtained using a linear curve with y = 141.34x + 5.5855, R 2 = 0.9961, LOD = 0.11 mg L-1, and LOQ = 0.35 mg L-1. The method precision, given as RSDs, was determined to be satisfactory at 1.04% for intra-day analysis and 3.22% for inter-day analysis, respectively. As a result, the selective determination of trace amounts of Fe2+ in real water samples using such labile multi-element doped GQDs in conjunction with garlic extract as a green chelating agent to maintain its enhanced sensitivity was successfully applied with good recoveries ranging from 89.16 to 121.45%.

Ultratrace Detection of Nickel(II) Ions in Water Samples Using Dimethylglyoxime-Doped GQDs as the Induced Metal Complex Nanoparticles by a Resonance Light Scattering Sensor.

This study aimed to synthesize dimethylglyoxime (DMG) (N-source)-doped graphene quantum dots (N-GQDs) via simultaneous pyrolysis of citric acid and 1.0% (w/v) DMG. The maximum excitation wavelength (λmax, ex = 380 nm) of the N-GQD solution (49% quantum yield (QY)) was a red shift with respect to that of bare GQDs (λmax, ex = 365 nm) (46% QY); at the same maximum emission wavelength (λmax, em = 460 nm), their resonance light scattering (RLS) intensity peak was observed at λmax, ex/em = 530/533 nm. FTIR, X-ray photoelectron spectroscopy, XRD, energy-dispersive X-ray spectroscopy, and transmission electron microscopy analyses were performed to examine the synthesized materials. The selective and sensitive detection of Ni2+ using the RLS intensity was performed at 533 nm under the optimum conditions consisting of both 25 mg L-1 N-GQDs and 2.5 mg L-1 DMG in the ammonium buffer solution of pH 9.0. The linearity of Ni2+ was 50.0-200.0 µg L-1 with a regression line, y = 5.031x - 190.4 (r 2 = 0.9948). The limit of detection (LOD) and the limit of quantitation (LOQ) were determined to be 20.0 and 60.0 µg L-1, respectively. The method precision expressed as % RSDs was 4.90 for intraday (n = 3 × 3) and 7.65 for interday (n = 5 × 3). This developed method afforded good recoveries of Ni2+ in a range of 85-108% when spiked with real water samples. Overall, this innovative method illustrated the identification and detection of Ni2+ as a DMG complex with N-GQDs, and the detection was highly sensitive and selective.

A Fluorescence Switching Sensor for Sensitive and Selective Detections of Cyanide and Ferricyanide Using Mercuric Cation-Graphene Quantum Dots.

This study aims to use graphene quantum dots (GQDs) as a fluorescence switching sensor (turn on-off) for the simultaneous detection of cyanide (CN-) and ferricyanide [Fe(CN)6]3- in wastewater samples. The GQDs were synthesized by pyrolyzing solid citric acid. The intrinsic blue color of the solution was observed under ultraviolet irradiation. The fluorescence spectrum was maximized at both excitation and emission wavelengths of 370 and 460 nm, respectively. The fluorescence intensity of GQDs decorated with Hg2+ (turn-off mode as the starting baseline) could be selectively turned on in the presence of CN- and once back to turn-off mode by [Fe(CN)6]3-. The fluorescence switching properties were used to develop a fluorescence turn-on-off sensor that could be used to detect trace amounts of CN- and [Fe(CN)6]3- in water samples. For highly sensitive detection under optimum conditions (Britton-Robinson buffer solution in the pH range of 8.0-9.0, linearity ranges of 5.0-15.0 µM (R 2 = 0.9976) and 10.0-50.0 µM (R 2 = 0.9994), respectively, and detection limits of 3.10 and 9.48 µM, respectively), good recoveries in the ranges of 85.89-112.66% and 84.88-113.92% for CN- and [Fe(CN)6]3-, respectively, were recorded. The developed methods were successfully used for the simultaneous and selective detection of CN- and [Fe(CN)6]3- in wastewater samples obtained from local municipal water reservoirs.