Optimization of the Form Factors of Advanced Li-S Pouch Cells.

Lithium-sulfur (Li-S) batteries hold immense promise as next-generation energy storage due to their high theoretical energy density (2600 Wh kg⁻¹), low cost, and non-toxic nature. However, practical implementation faces challenges, primarily from Li polysulfide (LiPS) shuttling within the cathode and Li dendrite growth at the anode. Optimized electrodes/electrolytes design effectively confines LiPS to the cathode, boosting cycling performance in coin cells to up to hundreds of cycles. Scaling up to larger pouch cells presents new obstacles, requiring further research for long-term stability. A 1.45 Ah pouch cell, with optimized sulfur loading and electrolyte/sulfur ratio is developed, which delivers an energy density of 151 Wh kg-1 with 70% capacity retention up to 100 cycles. Targeting higher energy density (180 Wh kg-1 ), the developed 1Ah pouch cell exhibits 68% capacity retention after 50 cycles. Morphological analysis reveals that pouch cell failure is primarily from Li metal powdering and resulting polarization, rather than LiPS shuttling. This occurs for continuous Li ion stripping/plating during cycling, leading to dendrite growth and formation of non-reactive Li powder, especially under high currents. These issues increase ion diffusion resistance and reduce coulombic efficiency over time. Therefore, the study highlights the importance of a protected Li metal anode for achieving high-energy-dense batteries.

Enabling Extreme Low-Temperature (≤ -100 °C) Battery Cycling with Niobium Tungsten Oxides Electrode and Tailored Electrolytes.

The degradation of current Li-ion batteries (LIBs) hinders their use in electronic devices, electric vehicles, and other applications at low temperatures, particularly in extreme environments like the polar regions and outer space. This study presents a pseudocapacitive-type niobium tungsten oxides (NbWO) electrode material combined with tailored electrolytes, enabling extreme low-temperature battery cycling for the first time. The synthesized NbWO material exhibits analogous structural properties to previous studies. Its homogenous atom distribution can further facilitate Li+ diffusion, while its pseudocapacitive Li+ storage mechanism enables faster Li+ reactions. Notably, the NbWO electrode material exhibits remarkable battery performance even at -60 and -100 °C, showcasing capacities of ≈90 and ≈75 mAh g-1 , respectively. The electrolytes, which have demonstrated favorable Li+ transport attributes at low temperatures in the earlier investigations, now enable extreme low-temperature battery operations, a feat not achievable with either NbWO or the electrolytes independently. Moreover, the outcomes extend to -120 °C and encompass a pouch-type cell configuration at -100 °C, albeit with reduced performance. This study highlights the potential of NbWO for developing batteries for their use in extremely frigid environments.

Sustainable Enhanced Sodium-Ion Storage at Subzero Temperature with LiF Integration.

Though layered sodium oxide materials are identified as promising cathodes in sodium-ion batteries, biphasic P3/O3 depicts improved electrochemical performance and structural stability. Herein, a coexistent P3/O3 biphasic cathode material was synthesized with "LiF" integration, verified with X-ray diffraction and Rietveld refinement analysis. Furthermore, the presence of Li and F was deduced by inductively coupled plasma-optical emission spectrometry (ICP-OES) and energy dispersive X-ray spectroscopy (EDS). The biphasic P3/O3 cathode displayed an excellent capacity retention of 85% after 100 cycles (0.2C/30 mA g-1) at room temperature and 94% at -20 °C after 100 cycles (0.1C/15 mA g-1) with superior rate capability as compared to the pristine cathode. Furthermore, a full cell comprising a hard carbon anode and a biphasic cathode with 1 M NaPF6 electrolyte displayed excellent cyclic stabilities at a wider temperature range of -20 to 50 °C (with the energy density of 151.48 Wh kg-1) due to the enhanced structural stability, alleviated Jahn-Teller distortions, and rapid Na+ kinetics facilitating Na+ motion at various temperatures in sodium-ion batteries. The detailed post-characterization studies revealed that the incorporation of LiF accounts for facile Na+ kinetics, boosting the overall Na storage.

Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries.

The electrochemical instability of ether-based electrolyte solutions hinders their practical applications in high-voltage Li metal batteries. To circumvent this issue, here, we propose a dilution strategy to lose the Li+/solvent interaction and use the dilute non-aqueous electrolyte solution in high-voltage lithium metal batteries. We demonstrate that in a non-polar dipropyl ether (DPE)-based electrolyte solution with lithium bis(fluorosulfonyl) imide salt, the decomposition order of solvated species can be adjusted to promote the Li+/salt-derived anion clusters decomposition over free ether solvent molecules. This selective mechanism favors the formation of a robust cathode electrolyte interphase (CEI) and a solvent-deficient electric double-layer structure at the positive electrode interface. When the DPE-based electrolyte is tested in combination with a Li metal negative electrode (50 µm thick) and a LiNi0.8Co0.1Mn0.1O2-based positive electrode (3.3 mAh/cm2) in pouch cell configuration at 25 °C, a specific discharge capacity retention of about 74% after 150 cycles (0.33 and 1 mA/cm2 charge and discharge, respectively) is obtained.

Tailored Solvation and Interface Structures by Tetrahydrofuran-Derived Electrolyte Facilitates Ultralow Temperature Lithium Metal Battery Operations.

Ineffectiveness of Li-ion batteries (LIBs) in cold climates hinders electronics to work in various conditions including frigid environments, despite high demands. Given that intrinsic properties of LIB materials cause this problem, optimized cell chemistries ultimately are required for low-temperature usage. In this study, Li-metal batteries (LMBs) composed of a Li-metal anode (LMA) stabilized by a localized high-concentration electrolyte (LHCE) are found to significantly enhance low-temperature performance. The LHCE allows the LMA to have compact and regular deposition and excellent plating/stripping efficiency at sub-zero temperatures. The LHCE produces an inorganic-rich solid-electrolyte interphase with larger amounts of Li2 O/LiF interfaces, dominance of ion aggregates in Li+ solvation, and enhanced Li+ transport, which can greatly improve the LMA stability. LMB full cells based on LiNi0.8 Co0.1 Mn0.1 O2 cathodes with the tailored electrolyte show high retentions of 75 and 64 % at -20 and -40 °C, respectively. Furthermore, the LMB configuration retains its charge-discharge capability even at -60 °C.

Ion-Solvent Interplay in Concentrated Electrolytes Enables Subzero Temperature Li-Ion Battery Operations.

Despite the essential role of ethylene carbonate (EC) in solid electrolyte interphase (SEI) formation, the high Li+ desolvation barrier and melting point (36 °C) of EC impede lithium-ion battery operation at low temperatures and induce sluggish Li+ reaction kinetics. Here, we demonstrate an EC-free high salt concentration electrolyte (HSCE) composed of lithium bis(fluorosulfonyl)imide salt and tetrahydrofuran solvent with enhanced subzero temperature operation originating from unusually rapid low-temperature Li+ transport. Experimental and theoretical characterizations reveal the dominance of intra-aggregate ion transport in the HSCE that enables efficient low-temperature transport by increasing the exchange rate of solvating counterions relative to that of solvent molecules. This electrolyte also produces a <5 nm thick anion-derived LiF-rich SEI layer with excellent graphite electrode compatibility and electrochemical performance at subzero temperature in half-cells. Full cells based on LiNi0.6Co0.2Mn0.2O2||graphite with tailored HSCE electrolytes outperform state-of-the-art cells comprising conventional EC electrolytes during charge-discharge operation at an extreme temperature of -40 °C. These results demonstrate the opportunities for creating intrinsically robust low-temperature Li+ technology.

Influence of the fluoroethylene carbonate on the electrochemical behavior of Bi3Ge4O12 as Lithium-ion anode.

Systematic ex-situ X-ray diffraction (XRD) characterization and electrochemical study revealed the key roles that the cut-off voltage and fluoroethylene carbonate (FEC) additive play on improving electrochemical performance of the Bi3Ge4O12-based (BGO) electrode. The ex-situ XRD analysis revealed that BGO particles suffer multiphase transitions during the (dis)charge reactions, being observed some phases as Bi2O2.33, BiLi3, Li2O, Ge4Li15, Ge2Li7, Ge3Li7, Ge5Li22, Ge4Li9, Bi2O3 and GeO2. The electrochemical evaluation exhibited that the addition of 5 v/v% of FEC in 1.0 M lithium hexafluorophosphate (LiPF6) in ethylene carbonate and diethyl carbonate (EC: DEC) at an applied cut-off voltage (1.5 V vs Li/Li+) improves the specific capacity (29%, delivering 479 mAh g-1), capacity retention (12%) and rate capability (369 mAh g-1 at 1000 mA g-1) of the BGO-based electrode. Also, FEC promotes the formation of a stable solid-electrolyte interface (SEI) layer on the anode at a cut-off voltage of 1.5 V vs Li/Li+. It displays the lowest values of SEI and charge transfer (CT) resistances, and electrode polarization, improving the reversibility of the alloying reactions related to Ge-Li and Bi-Li and maintaining their redox activity after 100 cycles, according to dQ dV-1 data.

Critical-Point-Dried, Porous, and Safer Aramid Nanofiber Separator for High-Performance Durable Lithium-Ion Batteries.

Ionically conducting, porous separator membranes with submicrometer size pores play an important role in governing the outcome of lithium-ion batteries (LIBs) in terms of life, safety, and effective transport of ions. Though the polyolefin membranes have dominated the commercial segment for the past few decades, to develop next-generation batteries with high-energy density, high capacity, and enhanced safety, there is a need to develop advanced separators with superior thermal stability, electrolyte interfacial capabilities, high melting temperature, and mechanical stability at elevated temperatures. Here, aramid nanofiber separators with enhanced mechanical and thermal stability dried at the critical point are processed and tested for mechanical strength, wettability, electrochemical performance, and thermal safety aspects in LIBs. These separators outperform Celgard polypropylene in all aspects such as delivering a high Young's modulus of 6.9 ± 1.1 GPa, and ultimate tensile strength of 170 ± 25 MPa. At 40 and 25 °C, stable 200 and 300 cycles with 10% and 11% capacity fade were obtained at 1 C rate, respectively. Multimode calorimetry, specially designed to study thermal safety aspects of LIB coin cells, demonstrates low exothermicity for critical-point-dried aramid nanofiber separators, and post-diagnosis illustrates preservation of structural integrity up to 300 °C, depicting possibilities of developing advanced safer, high-performance LIBs.

In Situ Thermal Safety Aspect of the Electrospun Polyimide-Al2O3 Separator Reveals Less Exothermic Heat Energies Than Polypropylene at the Thermal Runaway Event of Lithium-Ion Batteries.

Polyimide-Al2O3 membranes are developed as a direct alternative to current polyolefin separators by the electrospinning technique and their chemical structures confirm the carbonyl group with the presence of asymmetric and symmetric stretching and bending vibrations at 1778, 1720, and 720 cm-1 and stretching vibration at 1373 cm-1 for the imide group. Porous nanofiber architecture morphology is realized with a nanofiber thickness of ∼200 nm and shows an ultrasmooth surface and >1 µm pore size in the architecture, built with the chemical constituents of carbon, nitrogen, aluminum, and oxygen elements. The galvanostatic cycling study of the Li/PI-Al2O3/LiFePO4 lithium cell delivers stable charge-discharge capacities of 144/143 mAh g-1 at 0.2 C and 110/100 mAh g-1 at 1 C for 1-100 cycles. The fabricated MCMB/PI-Al2O3/LiFePO4 lithium-ion full-cell reveals less charge transfer resistance of Rct ∼ 25 Ω and yields stable charge-discharge capacities of 125/119 mAh g-1. The thermogravimetric curve for the PI-Al2O3 separator discloses thermal stability up to 525 °C, and the differential scanning calorimetric curve shows a straight line until 300 °C and depicts high thermal stability than the PP separator. In situ multimode calorimetry analysis of the MCMB/PP/LiFePO4 full-cell showed a pronounced exothermic peak at 225 °C with a higher released heat energy of 211 J g-1 at the thermal runaway event, while the MCMB/PI-Al2O3/LiFePO4 full-cell revealed an almost 8-fold less exothermic released heat energy of 25 J g-1 than the Celgard polypropylene separator, which was because the MCMB anode and LiFePO4 cathode can be mechanically isolated without any additional separator's melting and burning reactions, as a fire-suppressant separator for lithium-ion batteries.

A novel cyclopentyl methyl ether electrolyte solvent with a unique solvation structure for subzero (-40 °C) lithium-ion batteries.

1 M LiFSI in cyclopentyl methyl ether is shown as a novel electrolyte with a unique solvation structure to form a thin robust multilayer solid electrolyte interface with an inorganic LiF-rich inner layer. Aggregates and contact ion pairs are actively formed in the solvation shell and reduced on the graphite anode during lithiation. This EC-free electrolyte provides 86.9% initial efficiency, and 355 mA h g-1 over 350 cycles with an excellent capacity retention of 84% at a 1C rate. An excellent low-temperature performance of 370, 337, and 330 mA h g-1 at 0, -10, and -20 °C, respectively, at a 0.1C rate is recorded. Furthermore, at -40 °C, the graphite half-cell has a capacity of 274 mA h g-1 without electrolyte freezing.

Impedimetric Chemosensing of Volatile Organic Compounds Released from Li-Ion Batteries.

Detection of toxic and flammable gases and volatile organic compounds (VOCs) released from Li-ion batteries during thermal runaway can generate an early warning. A submicron (∼0.15 µm)-thick poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) sensor film is coated on a platinum electrode through a facile aqueous dispersion. The resulting sensor reliably detected different volatile organic compounds (VOCs) released during the early stages of thermal runaway of lithium-ion batteries (LIBs) even at low concentrations. The single-electrode sensor utilizes impedance spectroscopy to measure ethyl methyl carbonate and methyl formate concentrations at 5, 15, and 30 ppm independently and in various combinations using ethanol as a reference. In contrast to DC resistance measurement, which provides a single parameter, impedance spectroscopy provides a wealth of information, including impedance and phase angle at multiple frequencies as well as fitted charge transfer resistance and constant-phase elements. Different analytes influence the measurement of different parameters to varying degrees, enabling distinction using a single sensing material. The response time for ethyl methyl carbonate was measured to be 6 s. Three principal components (PCs) preserve more than 95% of information and efficiently enable discrimination of different classes of analytes. Application of low-power PEDOT:PSS-based gas sensors will facilitate cost-effective early detection of VOCs and provide early warning to battery management systems (BMS), potentially mitigating catastrophic thermal runaway events.

Is the Plastic Pandemic a Greater Threat to Humankind than COVID-19?

The advent of the COVID-19 pandemic has initiated a radical attention shift of society toward the severe consequences it has had over human health, shadowing a symmetrically, if not more, important issue of the rapid intensification in the amount of plastic waste that has been generated over the due course of time. Such a growth in the plastic footprint across the globe has led to a carbon positive environment with an increased amount of greenhouse gases (GHGs) released due to the processing of the waste plastic. We aim to address and provide our perception to this pressing challenge that can be decoded via the advancement of upcycling technologies, utilized and augmented worldwide. With the establishment of such sustainable policies and strategies, the global plastic footprint can be systematically mitigated, accelerating the world into economic circularity and environmental sustainability.

Mesoporous Weaved Turbostratic Nanodomains Enable Stable Na+ Ion Storage and Micropore Filling is Revealed to be More Unsafe than Adsorption and Deintercalation.

Advanced wave-shape non-graphitizable carbon sheets are derived, comprising mesoporous weaved turbostratic micropore enabled stable Na+ ion storage. The non-graphitizable amorphous characteristics are determined from the obtained two broad diffraction peaks at 22.7° and 43.8°. The observed D-band at 1325 cm-1 and G-band at 1586 cm-1 confirm the disordered graphitic structure, attributed to the measured specific surface area of 54 m2 g-1. Mesoporous weaved wave-shape carbon sheet architecture is confirmed by surface morphological studies, showing lattice fringes of disordered graphitic structures and dispersed ring patterns for the non-crystalline characteristics. The predominant stable redox peak at 0.014 V/0.185 V and the broader rectangular shape between 0.9 and 0.15 V depict the adsorption-micropore filling mechanism. The mesoporous hard carbon sheet delivers discharge-charge capacities of 450/311 mAh g-1 (1st cycle) and 263/267 mAh g-1 (250th cycle) at 25 mA g-1, exhibiting a superior anode for sodium-ion batteries. Besides, in situ multimode calorimetry results disclose that the micropore filling Na+ ion storage shows a higher released total heat energy of 721 J g-1 than the adsorption (471 J g-1). Ultimately, differential scanning calorimetry analysis of micropore filling Na+ ion storage (discharged state at 0.01 V) has revealed a predominant exothermic peak at 156 °C with the highest released total heat energy of 2183 J g-1 compared to adsorption (553 J g-1) and deintercalation (85 J g-1), indicating that micropore filling status is more unsafe than the adsorption and deintercalation for SIBs.

Discharge State of Layered P2-Type Cathode Reveals Unsafe than Charge Condition in Thermal Runaway Event for Sodium-Ion Batteries.

A sol-gel process followed by heat treatment derived a layered P2-type NaCoO2 cathode, which depicted unit cell parameters values of a = 2.8389 Å, c = 10.9899 Å, and V = 76.71 Å3 in powder X-ray diffraction pattern. The synthesized cathode exhibited hexagonal, 2D platelets with an ∼300 nm thickness. During the anodic and cathodic sweeps, the cyclic voltammograms revealed multiple redox peaks with the same current densities, shapes, and peak positions, associated with the highly reversible phase transition mechanism of the layered P2-type NaCoO2 cathode. The sodium cells yielded the capacities of 93/92 mAh g-1 at 0.5 C and 87/87 mAh g-1 at 1 C for the 50th charge-discharge cycles. The in situ multimode calorimetry (MMC) studies of sodium cells demonstrated a thermal explosion event, which occurred by sodium melting, short-circuit, electrode decomposition reaction, gas generation, exothermic reaction, released heat energy ,and cell gasket melting. Ultimately, the calculated released total heat energies of ∼550/740 J g-1 for in situ MMC studies and ∼312/594 J g-1 for ex situ DSC analyses (charge state at 4 V and discharge state at 2 V) show that the discharged state of sodiated layered P2-type NaCoO2 cathode material is more unsafe than the charge state. Furthermore, the ex situ differential scanning calorimetry (DSC) spectrum of a discharge state at 2 V of layered P2-type NaCoO2 revealed a decreased onset temperature (DOT) at 141 °C with two pronounced exothermic peaks at 197 and 266 °C with a released higher total heat energy of 594 J g-1 than the charge state heat energy at 312 J g-1, attributed to the higher charge onset temperature (COT) at 191 °C. Thus, the observed higher heat energy and decreased onset temperature for the discharge state at 2 V is associated with the higher Na+ ion in the discharge state of the layered P2-type NaxCoO2 cathode than that of the pristine cathode, showcasing that the layered P2-type NaCoO2 cathode is unsafe at the discharged condition for sodium-ion batteries.

Single-Source Alkoxide Precursor Approach to Titanium Molybdate, TiMoO5, and Its Structure, Electrochemical Properties, and Potential as an Anode Material for Alkali Metal Ion Batteries.

Transition-metal oxide nanostructured materials are potentially attractive alternatives as anodes for Li ion batteries and as photocatalysts. Combining the structural and thermal stability of titanium oxides with the relatively high oxidation potential and charge capacity of molybdenum(VI) oxides was the motivation for a search for approaches to mixed oxides of these two metals. Challenges in traditional synthetic methods for such materials made development of a soft chemistry single-source precursor pathway our priority. A series of bimetallic Ti-Mo alkoxides were produced by reactions of homometallic species in a 1:1 ratio. Thermal solution reduction with subsequent reoxidation by dry air offered in minor yields Ti2Mo2O4(OMe)6(OiPr)6 (1) by the interaction of Ti(OiPr)4 with MoO(OMe)4 and Ti6Mo6O22(OiPr)16(iPrOH)2 (2) by the reaction of Ti(OiPr)4 with MoO(OiPr)4. An attempt to improve the yield of 2 by microhydrolysis, using the addition of stoichiometric amounts of water, resulted in the formation with high yield of a different complex, Mo7Ti7+xO31+x(OiPr)8+2x (3). Controlled thermal decomposition of 1-3 in air resulted in their transformation into the phase TiMoO5 (4) with an orthorhombic structure in space group Pnma, as determined by a Rietveld refinement. The electrochemical characteristics of 4 and its chemical transformation on Li insertion were investigated, showing its potential as a promising anode material for Li ion batteries for the first time. A lower charge capacity and lower stability were observed for its application as an anode for a Na ion battery.

Double transition metal MXene (TixTa4-xC3) 2D materials as anodes for Li-ion batteries.

A bi-metallic titanium-tantalum carbide MXene, TixTa(4-x)C3 is successfully prepared via etching of Al atoms from parent TixTa(4-x)AlC3 MAX phase for the first time. X-ray diffractometer and Raman spectroscopic analysis proved the crystalline phase evolution from the MAX phase to the lamellar MXene arrangements. Also, the X-ray photoelectron spectroscopy (XPS) study confirmed that the synthesized MXene is free from Al after hydro fluoric acid (HF) etching process as well as partial oxidation of Ti and Ta. Moreover, the FE-SEM and TEM characterizations demonstrate the exfoliation process tailored by the TixTa(4-x)C3 MXene after the Al atoms from its corresponding MAX TixTa(4-x)AlC3 phase, promoting its structural delamination with an expanded interlayer d-spacing, which can allow an effective reversible Li-ion storage. The lamellar TixTa(4-x)C3 MXene demonstrated a reversible specific discharge capacity of 459 mAhg-1 at an applied C-rate of 0.5 °C with a capacity retention of 97% over 200 cycles. An excellent electrochemical redox performance is attributed to the formation of a stable, promising bi-metallic MXene material, which stores Li-ions on the surface of its layers. Furthermore, the TixTa(4-x)C3 MXene anode demonstrate a high rate capability as a result of its good electron and Li-ion transport, suggesting that it is a promising candidate as Li-ion anode material.

Engineered heat dissipation and current distribution boron nitride-graphene layer coated on polypropylene separator for high performance lithium metal battery.

Li metal as a battery anode has been intensively studied because of its high gravimetric capacity (3860 mAh g-1), a low standard electrode potential (-3.04 vs. SHE), a reasonable electronic conductivity and low density. However, lithium metal suffers from a continuous Li dendrite growth upon charge-discharge cycling, delivering a poor coulombic efficiency and consequently its early failure. Here, engineered bilayer separators demonstrate that a boron nitride-graphene (BNxGry) layer coated on one side of polypropylene (PP) membrane remarkably reduces the polarization and impedance, and significantly improve the performance and stability of Li/Cu half-cells. Moreover, Li/LiFePO4 full cell with the modified BN50Gr50/PP separator presents a remarkably stable 1000 charge-discharge cycles with a specific capacity of 114 mAh g-1 at 1C-rate. The superiority of the modified separator is orginated from an effective synergistic effect between physico-chemical properties of Gr (reducing local current density) and BN (dissipating local heat) and its enhanced structural and mechanical stability.

First-principles view of the interaction between Li and Bi4Ge3O12 anodes.

As a novel anodic electrode for Li-ion storage, the cubic Bi4Ge3O12 phase can experimentally deliver a remarkably high reversible specific capacity of 586 mA h g-1 at 200 mA h g-1 with a coulombic efficiency of 99.8% after 500 cycles, and has recently attracted attention for its stable electrochemical performance. Here we calculated its lithiation/delithiation reactions by using density functional theory studies, through the structural changes as the conversion and alloying reaction takes place during the Li-ion insertion and extraction process. The obtained theoretical capacity of Li is 48.75 mol (∼1043 mA h g-1) for 1 mol Bi4Ge3O12. The decomposed Bi2O3 (P3[combining macron]m1) and GeO2 (P3121) in the lithiation process of Bi4Ge3O12 are the active materials to react with the Li atoms via a conversion reaction. Besides Li2O with both Fm3[combining macron]m and Pnma phases, the final lithiation products of Bi4Ge3O12 should include Li3Bi (Fm3[combining macron]m) and Li4.25Ge (F4[combining macron]3m), through the alloying reactions of multi-valence elements of Bi and Ge with Li. Bi and Ge metals are also helpful in the decomposition of Li2O into Li during the delithiation process, increasing the reversibility of the conversion reactions. Our research provides theoretical support to understand the working mechanism of Bi4Ge3O12 and related mixed-metal anode materials.

Waste Biomass-Derived Carbon Anode for Enhanced Lithium Storage.

Due to increased populations, there is an increased demand for food; thus, battery electrode materials created from waste biomass provide an attractive opportunity. Unfortunately, such batteries rarely sustain capacities comparable to current state-of-the-art technologies. However, an anode synthesized from waste avocado seeds provides high cycling stability over 100 cycles and provides comparable capacity to graphite, around 315 mAh g-1 at 100 mA g-1 current density, and readily outperforms graphene in terms of both stability and capacity. This novel electrode provides such capacities as an amorphous carbon without the use of any additives or doped heteroatoms by utilizing capacitance-driven mechanisms to contribute to 54% of its lithium-ion storage. This allows the waste biomass-derived anode to overcome its low apparent diffusion coefficient of 4.38 × 10-11 cm2 s-1. By creating battery anodes from avocado seeds, waste streams can be redirected into creating valuable, renewable energy storage resources.