1.
Chem Commun (Camb)
; 58(57): 7968-7971, 2022 Jul 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35758098
RESUMO
Concise and general synthesis protocols are reported to generate all-syn mono-, di- and tri-alkylated cyclohexanes where a single fluorine is located on the remaining carbons of the ring. The alkyl groups are positioned to lie equatorially and to have triaxial C-F bonds imparting polarity to these ring systems. Intermolecular electrostatic interactions in the solid-state structure of the trialkylated systems are explored and the resultant supramolecular order opens up prospects for design in soft materials.