RESUMO
Solar-driven production of fuels such as hydrogen, hydrocarbons, and ammonia using semiconducting photocatalysts has the potential to be a sustainable alternative to current chemical processes. In recent years, silicon (Si) nanostructures have been recognized as a promising photocatalyst for hydrogen generation and organic oxidation reactions owing to its abundance, biocompatibility, and cost. While bulk Si has been studied extensively, on the nanoscale, plenty of opportunities exist to understand and engineer optimally performing Si photocatalysts. This perspective will highlight key results on the use of Si nanostructures for photocatalytic H2 production, CO2 reduction via light and heat-driven chemical looping, and current challenges in utilizing it for fuel-forming reactions. A brief guide on how these challenges can be addressed in the future and other unexplored questions that remain in the field are also discussed.
RESUMO
An advanced light-induced avenue to monodisperse sequence-defined linear macromolecules via a unique photochemical protocol is presented that does not require any protection-group chemistry. Starting from a symmetrical core unit, precision macromolecules with molecular weights up to 6257.10â g mol-1 are obtained via a two-monomer system: a monomer unit carrying a pyrene functionalized visible light responsive tetrazole and a photo-caged UV responsive diene, enabling an iterative approach for chain growth; and a monomer unit equipped with a carboxylic acid and a fumarate. Both light-induced chain growth reactions are carried out in a λ-orthogonal fashion, exciting the respective photosensitive group selectively and thus avoiding protecting chemistry. Characterization of each sequence-defined chain (size-exclusion chromatography (SEC), high-resolution electrospray ionization mass spectrometry (ESI-MS), and NMR spectroscopy), confirms the precision nature of the macromolecules.