Optimization of NO oxidation by H2O2 thermal decomposition at moderate temperatures.

H2O2 was adopted to oxidize NO in simulated flue gas at 100-500°C. The effects of the H2O2 evaporation conditions, gas temperature, initial NO concentration, H2O2 concentration, and H2O2:NO molar ratio on the oxidation efficiency of NO were investigated. The reason for the narrow NO oxidation temperature range near 500°C was determined. The NO oxidation products were analyzed. The removal of NOx using NaOH solution at a moderate oxidation ratio was studied. It was proven that rapid evaporation of the H2O2 solution was critical to increase the NO oxidation efficiency and broaden the oxidation temperature range. the NO oxidation efficiency was above 50% at 300-500°C by contacting the outlet of the syringe needle and the stainless-steel gas pipe together to spread H2O2 solution into a thin film on the surface of the stainless-steel gas pipe, which greatly accelerated the evaporation of H2O2. The NO oxidation efficiency and the NO oxidation rate increased with increasing initial NO concentration. This method was more effective for the oxidation of NO at high concentrations. H2O2 solution with a concentration higher than 15% was more efficient in oxidizing NO. High temperatures decreased the influence of the H2O2 concentration on the NO oxidation efficiency. The oxidation efficiency of NO increased with an increase in the H2O2:NO molar ratio, but the ratio of H2O2 to oxidized NO decreased. Over 80% of the NO oxidation product was NO2, which indicated that the oxidation ratio of NO did not need to be very high. An 86.7% NO removal efficiency was obtained at an oxidation ratio of only 53.8% when combined with alkali absorption.

[Optical Constants Determination of Zinc Selenide by Inversing Transmittance Spectrogram Transmittance Spectra Measurement and Thermal Radiative Physical Parameters Inversion of Diesel Fuel].

A novel inversion method of optical constants of diesel fuel that is one of semitransparent liquid was developed based on spectral transmittance radio inversion calculation of optical cell with glass-liquid fuel-glass configuration, which was validated by measured the optical constants of water. The measurements of transmittance spectrogram of optical cell filled with diesel fuel in the infrared wavelength 2 - 15 µm at normal incidence were investigated by Bruke V70 FTIR spectrometer. The optical constants and thermal radiative physcial parameters of diesel fuel were achieved. The results show that, (1) The optical constants of water determined by the new method (IDTM) have good agreement with previously data sets. (2) The optical constants calculation precision of the IDTM is similar with MCDTM, which is higher than SODTM and SDTM. (3) The transmittance capability of diesel fuel in the infrared wavelength 2 - 15 µm are weak, and there exist five absorption peaks, which are respectively 2.4, 3.4, 6.2, 7.3 and 13.8 µm. (4) The spectral selectivity of optical constants and thermal radiative physcial parameters of diesel fuel are stronger, whose values are urgently varied with different wavelenths.