RESUMO
The ionic diode structure has become one of the attractive structures in the field of moisture-based power generation. However, existing devices still suffer from poor moisture trapping, low surface charge, and inefficient ion separation, resulting in low output power. Moreover, water freezes at low temperatures (<0 °C), limiting the ionic diode structure to generate electricity in cold environments. In this paper, a moisture-enabled power generator has been designed and fabricated, which assembles a negatively charged ionic hydrogel film and a positively charged anodized aluminum oxide (AAO) film to construct a heterojunction. The hydrogel polymer network is modified with a large number of sulfonate groups that dissociate to provide nanoscale pores with high surface charge to improve the rectification ratio. And the lithium chloride (LiCl) salt with high hydration ability is added to the hydrogel as a moisture-trapping and anti-freezing component. Usually salt ions reduce the Debye length, so that the ion transport is finally not controlled by the electric double layer (EDL) and the rectification fails. Interestingly, due to the natural affinity of the hydrogel polymer network for LiCl, LiCl is locked on the hydrogel side and does not easily enter the AAO pores to change the distribution of EDL within the nanochannel. As a result, the device rectification ratio is almost independent of the amount of LiCl addition, demonstrating an excellent balance of high output power and high freeze resistance. Ultimately, the device exhibits excellent power generation performance in the -20 °C to 60 °C temperature range and 15% to 93% RH humidity range. Typically, under high humidity (93% RH) at room temperature (25 °C), it provides an open-circuit voltage of 1.25 V and a short-circuit current of 300 µA cm-2, with an on-load output power of up to 71.35 µW cm-2. Under medium humidity (50% RH) at low temperature (-20 °C), it provides an open-circuit voltage of 1.11 V and a short-circuit current of 15 µA cm-2.
RESUMO
Field investigations on the vertical and horizontal distribution patterns of Bemisia tabaci (Gennadius) population on Bt cotton Guokang No. 22 and non-Bt cotton Simian No. 3 showed that in July, no obvious difference was found in the vertical distribution of B. tabaci population on cotton plant, but in August, the population density was significantly higher on the upper part of cotton plant than on its middle and lower parts. The horizontal distribution patterns of B. tabaci adult and nymph were similar. B. tabaci distributed evenly on cotton leaves when its population density was low, but aggregated when its population density was high. The greater the population density, the higher the aggregation rate was observed. Throughout the incidence stage, B. tabaci adult and nymph aggregated and diffused alternatively. No significant difference was observed in the spatial distribution pattern of B. tabaci on Bt and non-Bt cotton plants.
