1.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 1): m29, 2009 Dec 09.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21579928
RESUMO
The title compound, [PbCl(2)(C(17)H(9)NO(3))](n), was synthesized by the hydro-thermal reaction of PbCl(2) and liriodenine. The lead(II) atom has a distorted octa-hedral environment made up of the O and N atoms of the liriodenine ligand [Pb-O 2.666â (4)â Å, Pb-N 2.587â (5)â Å, O-Pb-N 61.78â (14)°] and four bridging chloro ligands, which link the complex mol-ecules into infinite chains along the a axis. Both crystallographically independent chloro-bridges are asymmetric, so that the Pb atom participates in two short [2.6872â (18) and 2.7952â (18)â Å] and two noticeably longer Pb-Cl bonds [2.9626â (18) and 3.031â (2)â Å].