Haloacetonitriles adsorption using a low-cost adsorbent derived from canvas fabric.

The characteristics of canvas fabric-derived adsorbents and their removal efficiency on five haloacetronitriles (HANs) were investigated. In addition, the effect of chemical activation with ferric chloride (FeCl3) and ferric nitrate (Fe(NO3)3) solutions on HANs removal efficiency was determined. The results indicated that the surface area increased from 262.51 m2/g to 577.25 and 370.83 m2/g, respectively, after being activated with FeCl3 and Fe(NO3)3 solutions. Increases in surface area and pore volume had a direct impact on the effectiveness of HANs removal. As compared to the non-activated adsorbent, the activated adsorbent effectively removed five species of HANs. TCAN was highly removed by the Fe(NO3)3-activated adsorbent (94%) due to the presence of mesoporous pore volume after activation with Fe(NO3)3. On the other hand, MBAN had the lowest removal efficiency of all adsorbents in this study. The activation with FeCl3 and Fe(NO3)3 showed equal removal efficiency for DCAN, BCAN, and DBAN, with percent removal higher than 50%. The hydrophilicity of HANs species affected the removal efficiency. The hydrophilicity order of five HANs species was MBAN, DCAN, BCAN, DBAN, and TCAN, respectively, which well corresponded to the obtained removal efficiency. The canvas fabric-derived adsorbents synthesized in this study were proven to be utilized as low-cost adsorbents to efficiently remove HANs from the environment. Future research will focus on the adsorption mechanism and recycling method to realize the potential for large-scale utilization.

Adsorption of Fluoride onto Acid-Modified Low-Cost Pyrolusite Ore: Adsorption Characteristics and Efficiencies.

Fluoride concentrations in the groundwater continue to be a major cause for concern in Thailand, particularly in the country's north and west. The process of removing fluoride through adsorption has captured the attention of the abundance of ore in the mining industry. For the purpose of this investigation, the utilization of the adsorbent pyrolusite, which is a manganese mineral largely composed of MnO2, was a major component. Lab-scale experiments were conducted to investigate the efficacy of original pyrolusite ore (PA-1) and acid-modification PA (PA-2) created as low-cost adsorption materials for fluoride removal. The results of the adsorption rate in both PAs showed a fast rate of adsorption within 60 min of reaching equilibrium. According to the results of the adsorption capacity (qe) tests, PA that had been treated with an acid solution (PA-2) had the capacity to contain more fluoride (qe = 0.58 mg/g) than the PA that had been used initially (PA-1) (qe = 0.11 mg/g). According to the findings of an isotherm, primary adsorption behavior is determined by the effect that surface components and chemical composition have on porous materials. This is the first current study that provides a comparison between pyrolusite from Thailand's mining industry and basic modified pyrolusite regarding their ability to remove a fluoride contaminant in synthetic groundwater by an adsorption process. Such an approach will be able to be used in the future to protect the community from excessive fluoride concentrations in household and drinking water treatment technology.

Efficiencies of O-MBR and A/O-MBR for Organic Matter Removal from and Trihalomethane Formation Potential Reduction in Domestic Wastewater.

Lab-scale anoxic/oxic membrane bioreactor (A/O-MBR) and oxic membrane bioreactor (O-MBR) systems using a submerged polysulfone hollow-fiber membrane module with a pore size of 0.01 µm and a total surface area of 1.50 m2 were used to treat domestic wastewater. The sludge retention time (SRT) of each system was examined by setting the SRT to 10, 20, and infinity (no sludge withdrawal). The results showed that the total nitrogen removal efficiency of the A/O-MBR was more significant than that of the O-MBR at a SRT of infinity, with figures of 72.3% and 33.1% being found, respectively. The COD removal efficiencies of the A/O-MBR system with a SRT of 10 days, 20 days, and infinity were 82.4%, 84.3%, and 91.5%, respectively. The COD removal efficiencies of the O-MBR system with a SRT of 10 days, 20 days, and infinity were 79.3%, 81.5%, and 89.8%, respectively. An increase in the SRT resulted in an increase in the COD removal efficiency. The FEEM peak of the influent tended to decrease after an increase in the SRT for both systems (A/O-MBR and O-MBR). For the A/O-MBR system, the trihalomethane formation potential (THMFP) was significantly reduced by 88.91% (at a SRT of infinity). The THMFP declined significantly by 85.39% for the O-MBR system at a SRT of infinity. The A/O-MBR system showed a slightly higher efficiency than the O-MBR system in terms of the COD removal and the THMFP reduction. These results indicated that the MBR process, and the A/O-MBR system, in particular, could be used as an effective wastewater treatment process for many developing countries that are troubled by the emerging contamination of water and wastewater.

Trihalomethanes in Water Supply System and Water Distribution Networks.

The formation of trihalomethanes (THMs) in natural and treated water from water supply systems is an urgent research area due to the carcinogenic risk they pose. Seasonal effects and pH have captured interest as potential factors affecting THM formation in the water supply and distribution systems. We investigated THM occurrence in the water supply chain, including raw and treated water from water treatment plants (coagulation, sedimentation, sand filtration, ClO2-disinfection processes, and distribution pipelines) in the Chiang Mai municipality, particularly the educational institute area. The effects of two seasons, rainy (September-November 2019) and dry (December 2019-February 2020), acted as surrogates for the water quality profile and THM occurrence. The results showed that humic acid was the main aromatic and organic compound in all the water samples. In the raw water sample, we found a correlation between surrogate organic compounds, including SUVA and dissolved organic carbon (DOC) (R2 = 0.9878). Four species of THMs were detected, including chloroform, bromodichloromethane, dibromochloromethane, and bromoform. Chloroform was the dominant species among the THMs. The highest concentration of total THMs was 189.52 µg/L. The concentration of THMs tended to increase after chlorination when chlorine dioxide and organic compounds reacted in water. The effect of pH on the formation of TTHMs was also indicated during the study. TTHM concentrations trended lower with a pH ≤ 7 than with a pH ≥ 8 during the sampling periods. Finally, in terms of health concerns, the concentration of TTHMs was considered safe for consumption because it was below the standard (<1.0) of WHO's Guideline Values (GVs).

Evaluation of Fluoride Adsorption Mechanism and Capacity of Different Types of Bone Char.

The fluoride adsorption capacity of three types of bone char (BC), including cow BC (CBC), chicken BC (CKBC), and pig BC (PBC), was examined. At the optimum charring conditions (temperature and time), PBC had the highest hydroxyapatite (HAP) content (0.928 g-HAP/g-BC), while CBC had the highest specific surface area (103.11 m2/g-BC). CBC also had the maximum fluoride adsorption capacity (0.788 mg-F/g-HAP), suggesting that fluoride adsorption capacity depends more on the specific surface area of the BC than the HAP content. The adsorption data of CBC, CKBC, and PBC fit well with the pseudo-second-order model and the Langmuir isotherm. The maximum fluoride adsorption capacity of BC reached the maximum value when the solution had a pH of approximately 6.0. Lastly, the highest fluoride desorption occurred when the BCs were soaked in solutions with a pH higher than 11.0.

Molecular dissolved organic matter removal by cotton-based adsorbents and characterization using high-resolution mass spectrometry.

This research investigates the characteristics of dissolved organic matter (DOM) removal by synthesized cotton-fiber adsorbents using unknown screening analysis with high resolution and accurate mass spectrometry. Molecular characteristics of DOM removed by adsorbents were investigated semiquantitatively and unknown disinfection byproduct (DBP) formation potentials were also investigated. Adsorbents were modified using ferric nitrate to increase the magnetic property. The XRD pattern showed Fe-containing crystalline structures in the modified adsorbent (M-CF). The M-CF possessed higher mesopore volume, which enhanced the dissolved organic carbon (DOC) removal efficiency to 74.50% (compared to 32.12% in the unmodified CF adsorbent). The kinetics experiment showed that both adsorbents were better fitted to pseudo-second orders than pseudo-first orders. The initial rate constant was higher in M-CF (1.40 mg/g min) than in CF (0.02 mg/g min) treatments due to the higher mesopore volume in M-CF. M-CF removed almost 700 carbon­hydrogen­oxygen based DOMs (CHO features), 300 more CHO features than CF. CF selectively adsorbed only higher-molecular-weight (MW) CHO features (more CH2 groups), while the mesopores in M-CF removed DOM with lower MW (fewer CH2 groups) that were refractory to CF. The low MW DOM removed only by M-CF mesopore exhibited more oxidized (positive carbon oxidation state, Cos) and saturated characters (negative oxygen-subtracted double bond equivalent per carbon, (DBE-O)/C). After chlorination, over 50 unknown DBPs were detected, 33 of which were commonly found in all samples. M-CF decreased unknown formation potential more than CF. However, adsorption of M-CF and CF before chlorination resulted in different remaining precursors to water chlorination and formed unique DBPs from those precursors.

Synthesis of porous pig bone char as adsorbent for removal of DBP precursors from surface water.

This research study aims to investigate the efficiency of synthesized porous pig bone char (PBC) for reduction of disinfection by-product (DBP) precursors from surface water. Dissolved organic matter (DOM) is commonly present in natural water and acts as a disinfection by-product precursor. Adsorption is one of the promising technologies that is commonly applied for DOM removal. Interestingly, the properties of pig bone are such that it has a surface area and pore volumes that can adsorb DOM. Pig bone was synthesized as porous bone char (PBC). The results show that synthesized PBC at 900 °C (PBC-900 °C) provides a high volume of mesoporous structure. The adsorption process was best fitted with the pseudo-second-order and Freundlich isotherm model. Thus, the mechanisms occurred on the multilayer adsorption of the surface. PBC-900 °C can remove approximately 70-80% of DOM with varying concentrations, from 0.2 g/L to 0.8 g/L. Furthermore, the results of fluorescence excitation-emission (FEEM) showed that humic acids and humic-like substances in water can be removed by using PBC at concentrations higher than 0.4 g/L. From the obtained results, it can be concluded that PBC is an alternative low-cost adsorbent which can be utilized for reduction of DBP precursors from water.

Reduction of DOM fractions and their trihalomethane formation potential in surface river water by in-line coagulation with ceramic membrane filtration.

This research was aimed at investigating the reduction of DOM fractions and their trihalomethane formation potential (THMFP) by in-line coagulation with 0.1 µm ceramic membrane filtration. The combination of ceramic membrane filtration with a coagulation process is an alternative technology which can be applied to enhance conventional coagulation processes in the field of water treatment and drinking water production. The Ping River water (high turbidity water) was selected as the raw surface water because it is currently the main raw water source for water supply production in the urban and rural areas of Chiang Mai Province. From the investigation, the results showed that the highest percent reductions of DOC, UV-254, and THMFP (47.6%, 71.0%, and 67.4%, respectively) were achieved from in-line coagulation with ceramic membrane filtration at polyaluminum chloride dosage 40 mg/L. Resin adsorption techniques were employed to characterize the DOM in raw surface water and filtered water. The results showed that the use of a ceramic membrane with in-line coagulation was able to most efficiently reduce the hydrophobic fraction (HPOA) (68.5%), which was then followed by the hydrophilic fraction (HPIA) (49.3%). The greater mass DOC reduction of these two fractions provided the highest THMFP reductions (55.1% and 37.2%, respectively). Furthermore, the in-line coagulation with ceramic membrane filtration was able to reduce the hydrophobic (HPOB) fraction which is characterized by high reactivity toward THM formation. The percent reduction of mass DOC and THMFP of HPOB by in-line coagulation with ceramic membrane filtration was 45.9% and 48.0%, respectively.