RESUMO
The interplay between phase separation and wetting of multicomponent mixtures is ubiquitous in nature and technology and recently gained significant attention across scientific disciplines, due to the discovery of biomolecular condensates. It is well understood that sessile droplets, undergoing phase separation in a static wetting configuration, exhibit microdroplet nucleation at their contact lines, forming an oil ring during later stages. However, very little is known about the dynamic counterpart, when phase separation occurs in a nonequilibrium wetting configuration, i.e., spreading droplets. Here we show that liquid-liquid phase separation strongly couples to the spreading motion of three-phase contact lines. Thus, the classical Cox-Voinov law is not applicable anymore, because phase separation adds an active spreading force beyond the capillary driving. Intriguingly, we observe that spreading starts well before any visible nucleation of microdroplets in the main droplet. Using high-speed ellipsometry, we further demonstrate that the evaporation-induced enrichment, together with surface forces, causes an even earlier nucleation in the wetting precursor film around the droplet, initiating the observed wetting transition. We expect our findings to improve the fundamental understanding of phase separation processes that involve dynamical contact lines and/or surface forces, with implications in a wide range of applications, from oil recovery or inkjet printing to material synthesis and biomolecular condensates.
RESUMO
The wetting properties of multicomponent liquids are crucial to numerous industrial applications. The mechanisms that determine the contact angles for such liquids remain poorly understood, with many intricacies arising due to complex physical phenomena, for example, due to the presence of surfactants. Here, we consider two-component drops that consist of mixtures of vicinal alkanediols and water. These diols behave surfactant-like in water. However, the contact angles of such mixtures on solid substrates are surprisingly large. We experimentally reveal that the contact angle is determined by two separate mechanisms of completely different nature, namely, Marangoni contraction (hydrodynamic) and autophobing (molecular). The competition between these effects can even inhibit Marangoni contraction, highlighting the importance of molecular structures in physico-chemical hydrodynamics.
RESUMO
By sufficiently heating a solid, a sessile drop can be prevented from contacting the surface by floating on its own vapour. While certain aspects of the dynamics of this so-called Leidenfrost effect are understood, it is still unclear why a minimum temperature (the Leidenfrost temperature TL) is required before the effect manifests itself, what properties affect this temperature, and what physical principles govern it. Here we investigate the dependence of the Leidenfrost temperature on the ambient conditions: first, by increasing (decreasing) the ambient pressure, we find an increase (decrease) in TL. We propose a rescaling of the temperature which allows us to collapse the curves for various organic liquids and water onto a single master curve, which yields a powerful tool to predict TL. Secondly, increasing the ambient temperature stabilizes meta-stable, levitating drops at increasingly lower temperatures below TL. This observation reveals the importance of thermal Marangoni flow in describing the Leidenfrost effect accurately. Our results shed new light on the mechanisms playing a role in the Leidenfrost effect and may help to eventually predict the Leidenfrost temperature and achieve complete understanding of the phenomenon, however, many questions still remain open.
RESUMO
Colliding drops are encountered in everyday technologies and natural processes, from combustion engines and commodity sprays to raindrops and cloud formation. The outcome of a collision depends on many factors, including the impact velocity and the degree of alignment, and intrinsic properties like surface tension. Yet, little is known on binary impact dynamics of low-surface-tension drops on a low-wetting surface. We investigate the dynamics of an oil drop impacting an identical sessile drop sitting on a superamphiphobic surface. We observe five rebound scenarios, four of which do not involve coalescence. We describe two previously unexplored cases for sessile drop liftoff, resulting from drop-on-drop impact. Numerical simulations quantitatively reproduce the rebound scenarios and enable quantification of velocity profiles, energy transfer, and viscous dissipation. Our results illustrate how varying the offset from head-on alignment and the impact velocity results in controllable rebound dynamics for oil drop collisions on superamphiphobic surfaces.
