Resilience of stormwater biofilters following the deposition of wildfire residues: Implication on downstream water quality management in wildfire-prone regions.

Stormwater treatment systems such as biofilters could intercept and remove pollutants from contaminated runoff in wildfire-affected areas, ensuring the protection of water quality downstream. However, the deposition of wildfire residues such as ash and black carbon onto biofilters could potentially impair their stormwater treatment functions. Yet, whether and how wildfire residue deposition could affect biofilter functions is unknown. This study examines the impact of wildfire residue deposition on biofilter infiltration and pollutant removal capacities. Exposure to wildfire residues decreased the infiltration capacity based on the amount of wildfire deposited. Wildfire residues accumulated at the top layer of the biofilter, forming a cake layer, but scraping this layer restored the infiltration capacity. While the deposition of wildfire residues slightly changed the pore water geochemistry, it did not significantly alter the removal of metals and E. coli. Although wildfire residues leached some metals into pore water within the simulated root zone, the leached metals were effectively removed by the compost present in the filter media. Collectively, these results indicate that biofilters downstream of wildfire-prone areas could remain resilient or functional and protect downstream water quality if deposited ash is periodically scraped to restore any loss of infiltration capacity following wildfire residue deposition.

PFAS release from the subsurface and capillary fringe during managed aquifer recharge.

Managed aquifer recharge (MAR) is a sustainable way of harvesting groundwater in water-stressed urbanized areas, where reclaimed wastewater or stormwater is applied on a large basin to infiltrate water into the groundwater aquifer naturally. This process could rapidly fluctuate the water table and move the capillary fringe boundary, and the change in flow dynamic and associated geochemical changes could trigger the release of sequestered pollutants, including per- and polyfluoroalkyl substances (PFAS), also known as 'forever chemicals', from the subsurface and capillary fringe. Yet, the potential of PFAS release from the subsurface and capillary zone during recharge events when the water table rapidly fluctuates has not been evaluated. This study uses laboratory column experiments to simulate PFAS release from pre-contaminated subsurface and capillary fringe during groundwater table fluctuation. The results reveal that the groundwater level fluctuations during MAR increased the release of perfluorobutanesulfonic acid (PFBS) and perfluorooctanesulfonic acid (PFOS) from the capillary fringe, but the fraction released depended on PFAS type and their association with soil colloids. A higher proportion of PFOS in column effluent was found to be associated with particles, while a greater portion of released PFBS was in a free or dissolved state. The direction of water table fluctuation did not affect the release of PFAS in this study. A lack of change in the concentration of bromide, a conservative tracer, during flow interruption, indicates that diffusion of PFAS through reconnected pores during water table rise had an insignificant effect on PFAS release. Overall, this study provides insights into how PFAS can be released from the subsurface and capillary fringe during managed aquifer recharge when the groundwater level is expected to fluctuate quickly.

Do drinking water treatment residuals underperform in the presence of compost in stormwater media filters?

Drinking water treatment residuals (WTR), a waste-derived product, are often recommended to use as an amendment in stormwater biofilters to enhance their capacity to remove phosphate and microbial pollutants. However, their efficacy has been assumed to remain high in the presence of compost, one of the most common amendments used in biofilters. This study tests the validity of that assumption by comparing the removal capacities of WTR-amended biofilters with and without the presence of compost. Our results show that amending sand with WTR increased E. coli removal by at least 1-log, but the addition of compost in the sand-WTR media lowered the removal capacity by 13 %. Similarly, the addition of WTR to sand improved phosphate removal to nearly 1177 %, but the removal decreased slightly by 8 % when adding compost to the media. The results confirmed that dissolved organic carbon (DOC) leached from the compost could compete for adsorption sites for bacteria and phosphate, thereby lowering WTR's adsorption capacity based on the amount of DOC adsorbed on WTR. Collectively, these results indicate that the stormwater treatment industry should avoid mixing compost with WTR to get the maximum benefits of WTR for bacterial removal and improve the performance lifetime of WTR-amended biofilters.

Wildfire impacts on surface water quality parameters: Cause of data variability and reporting needs.

Surface runoff mobilizes the burned residues and ashes produced during wildfires and deposits them in surface waters, thereby deteriorating water quality. A lack of a consistent reporting protocol precludes a quantitative understanding of how and to what extent wildfire may affect the water quality of surface waters. This study aims to analyze reported pre- and post-fire water quality data to inform the data reporting and highlight research opportunities. A comparison of the pre-and post-fire water quality data from 44 studies reveals that wildfire could increase the concentration of many pollutants by two orders of magnitude. However, the concentration increase is sensitive to when the sample was taken after the wildfire, the wildfire burned area, discharge rate in the surface water bodies where samples were collected, and pollutant type. Increases in burned areas disproportionally increased total suspended solids (TSS) concentration, indicating TSS concentration is dependent on the source area. Increases in surface water flow up to 10 m3 s-1 increased TSS concentration but any further increase in flow rate decreased TSS concentration, potentially due to dilution. Nutrients and suspended solids concentrations increase within a year after the wildfire, whereas peaks for heavy metals occur after 1-2 years of wildfire, indicating a delay in the leaching of heavy metals compared to nutrients from wildfire-affected areas. The concentration of polycyclic aromatic hydrocarbons (PAHs) was greatest within a year post-fire but did not exceed the surface water quality limits. The analysis also revealed inconsistency in the existing sampling protocols and provides a guideline for a modified protocol along with highlighting new research opportunities. Overall, this study underlines the need for consistent reporting of post-fire water quality data along with environmental factors that could affect the data so that the post-fire water quality can be assessed or compared between studies.