1.
ACS Macro Lett
; 7(3): 376-380, 2018 Mar 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35632915
RESUMO
Colloidal dispersions of epoxy-acid vitrimers have been synthesized by miniemulsion polymerization. This versatile strategy enables obtaining stable cross-linked particles, even from initially incompatible precursors, while minimizing hydrolysis of the ester bonds formed during the curing. After drying of the latexes, trans-esterification exchanges occurring at high temperatures through interparticle interfaces induces an efficient sintering into homogeneous cross-linked polymer films.