Magnetic spin structure of pyroxene-type MnGeO(3).

Polycrystalline MnGeO(3) material was synthesized at 1473 K and ambient pressures using ceramic sintering techniques. Under these conditions the pyroxene-type compound crystallizes in the orthorhombic modification with space group Pbca, as determined from the refinement of the neutron diffraction data. The monoclinic modification, space group C 2/c, was also present at a level of 8.8(4) wt% and the magnetic structures for the two polymorphs at low temperatures have been found simultaneously. The monoclinic form orders magnetically below 34 K; the spin structure can be described using k = (0, 0, 0) in the magnetic space group C 2'/c, having an antiferromagnetic spin arrangement within and between the chains of M1 and M2 sites. The orthorhombic phase of MnGeO(3) transforms to a magnetically ordered state with k = (0, 0, 0) and magnetic space group Pb'c'a below 12 K. Spins on M1 sites are aligned along the crystallographic a-axis with a slight non-collinear antiferromagnetic spin arrangement with and between the M1 chains. Spins on M2 sites are also antiferromagnetically coupled; however, one of the three different M1-M2 superexchange pathways within the band of M1 and M2 sites displays a ferromagnetic interaction, while the other two allow antiferromagnetic interaction.

Raman spectroscopic and visible absorption investigation of LiCrSi2O6 pyroxene under pressure.

The first observation of the vibrational spectrum of the synthetic pyroxene Li-kosmochlor (LiCrSi2O6) is reported herein. The Raman and visible spectra are reported as a function of pressure. Though the pyroxene retains its P21/c symmetry, changes in the Raman spectra are observed between 6.8 and 7.7 GPa, possibly due to the formation of an additional bond between Li and O3 or some other transition that retains the mineral's P21/c space group. Splitting of the peak appearing at approximately 700 cm(-1), used to characterize the P21/c phase in other studies, is not observed. Comparison is made with the Raman spectra of LiAlSi2O6 and LiFeSi2O6 in the P21/c phase and the visible spectra of NaCrSi2O6 at high pressures.

LiInSiO4: a new monovalent-trivalent olivine.

The structure of the olivine LiInSiO(4) (lithium indium silicate) is isotypic with LiScSiO(4) and MgMgSiO(4) (forsterite). The main differences between the title compound and the divalent-divalent olivines are found for the bond lengths and angles opposite common edges between the tetrahedron and the Li(+) and In(3+) ion sites. The tetrahedron shares one common edge with the Li(+) site and two common edges with the In(3+) site. The tetrahedron is distinctly distorted, as are the Li(+) and In(3+) sites.