Introducing Materials Science: Experimenting with Magnetic Nanomaterials in the Undergraduate Chemistry Laboratory.

Materials science research has expanded significantly in recent years; a multidisciplinary field, home to an ever-growing number of chemists. However, our general chemistry degree courses have not changed to reflect the rise in interest in this topic. In this paper, we propose a laboratory experiment for the undergraduate chemistry practical course, which may serve as a hands-on introduction to this field. The experiment involves the synthesis and characterization of magnetic materials via commonly employed techniques in materials science. Students begin by producing three metal ferrite spinels using a sol-gel combustion synthesis. They must then characterize the differing magnetic properties across their three samples using a magnetic susceptibility balance. In the second part of the experiment, students must create a ferrofluid via coprecipitation, from which they may observe the phenomenon of "spiking" in response to an external magnet. Additional data such as X-ray diffraction (XRD) patterns and transmission electron microscopy (TEM) images corresponding to these materials are also provided, and students are tasked with the interpretation of these data in their writeup report. Upon completion, students should gain a new-found understanding of materials science and its fundamental overlap with chemistry.

What is Unique About Kindness? Exploring the Proximal Experience of Prosocial Acts Relative to Other Positive Behaviors.

Previous research has identified a robust connection between prosociality and happiness, suggesting that kindness has both hedonic and eudaimonic benefits-in the short term and in the long term. By contrast, our experiment aimed to examine people's momentary eudaimonic feelings while engaging in kind acts for others. To that end, we randomly assigned participants to one of four positively valenced conditions that varied in their inclusion of potential "active ingredients" of prosocial behavior. Namely, engaging in kind acts for others was compared to engaging in kind acts for oneself (social element removed), extraverted behavior (kindness element removed), and open-minded behavior (both social and kindness elements removed). Participants were assessed five times over 2 weeks, each time reporting on how they felt during their assigned activities. Multilevel models revealed that relative to all other conditions, participants assigned to do kind acts for others reported a greater sense of competence, self-confidence, and meaning while engaging in those acts across the intervention period. Engaging in acts of kindness for others also led to stronger feelings of connection relative to engaging in open-minded behavior or acts of kindness for oneself but did not differ from engaging in extraverted behavior. These results illuminate the experience of positive eudaimonic feelings while one commits kind acts for others and highlight the unique benefits of prosociality compared to other positive behaviors. Supplementary Information: The online version contains supplementary material available at 10.1007/s42761-022-00143-4.

Are Some Ways of Expressing Gratitude More Beneficial Than Others? Results From a Randomized Controlled Experiment.

Gratitude activities have been shown to increase well-being and other positive outcomes in numerous experiments to date. The current study tested whether self-directed gratitude interventions that vary by type (i.e., social vs. nonsocial) and format (i.e., long-form letters vs. shorter lists) produce differential benefits. To that end, 958 Australian adults were assigned to one of six activities to complete each day for 1 week, including five gratitude activities that varied by type and format and an active control condition (i.e., keeping track of daily activities). Regressed change analyses revealed that, overall, long-form writing exercises (i.e., essays and letters) resulted in greater subjective well-being and other positive outcomes than lists. Indeed, those who were instructed to write social and nonsocial gratitude lists did not differ from controls on any outcomes. However, participants who wrote unconstrained gratitude lists-that is, those who wrote about any topics they wanted-reported greater feelings of gratitude and positive affect than did controls. Finally, relative to the other gratitude conditions, participants who wrote gratitude letters to particular individuals in their lives not only showed stronger feelings of gratitude, elevation, and other positive emotions but also reported feeling more indebted. This study demonstrates that not only does gratitude "work" to boost well-being relative to an active neutral activity, but that some forms of gratitude may be more effective than others. We hope these findings help scholars and practitioners to develop, tailor, implement, and scale future gratitude-based interventions. Supplementary Information: The online version contains supplementary material available at 10.1007/s42761-022-00160-3.

What is the Optimal Way to Give Thanks? Comparing the Effects of Gratitude Expressed Privately, One-to-One via Text, or Publicly on Social Media.

Numerous investigations to date have established the benefits of expressing gratitude for improved psychological well-being and interpersonal relationships. Nevertheless, the social dynamics of gratitude remain understudied. Do the effects of gratitude differ when it is expressed privately, communicated directly to the benefactor one-to-one, or shared publicly? We tested this question in a preregistered intervention study. An ethnically and economically diverse sample of undergraduate students (N = 916) was randomly assigned to 1 of 4 conditions: (1) write gratitude letters and do not share them (private gratitude), (2) share gratitude one-to-one with benefactors via text (1-to-1 gratitude), (3) share gratitude publicly on social media (public gratitude), or (4) track daily activities (control). Participants were asked to complete their assigned activity four times with different people (as applicable) over the course of about a week. Overall, participants assigned to any digital gratitude intervention experienced improvements in state gratitude, positive emotions, negative emotions, elevation, connectedness, support, and loneliness, relative to controls. Relative to all other conditions, participants assigned to text their benefactors showed the biggest boosts in social connectedness and support. Our findings show that easily scalable digital gratitude interventions can advance the well-being of young college students. Supplementary Information: The online version contains supplementary material available at 10.1007/s42761-022-00150-5.

Experimental effects of social behavior on well-being.

Subjective well-being is characterized by relatively frequent positive emotions, relatively infrequent negative emotions, and high life satisfaction. Although myriad research topics related to subjective well-being have been explored - from how it should be measured to how it affects physical health - a key finding is that social connections are crucial. Researchers are therefore increasingly exploring whether subjective well-being can be improved through interventions that encourage specific types of social behaviors, including prosociality, gratitude, extraversion, and brief social interactions. We review this recent work, highlighting potential behavioral and psychological mechanisms underlying the effectiveness of such interventions, along with their boundary conditions.

The genomic impact of kindness to self vs. others: A randomized controlled trial.

OBJECTIVE: Prosocial behavior has been linked to improved physical health, but the biological mechanisms involved remain unclear. This study tested whether a 4-week kindness intervention could reduce expression of a stress-related immune response gene signature known as the Conserved Transcriptional Response to Adversity (CTRA). METHODS: In a diverse sample of community adults (N = 182), study participants were randomly assigned to perform 3 kind acts for other people, to perform 3 kind acts for themselves, or to list daily activities (control), on one day per week over 4 weeks. CTRA gene expression was measured by RNA sequencing of dried blood spots (DBS) collected at baseline and 5 weeks later (1 week after completing study assignments). Participants' descriptions of their kind acts were coded for protocol adherence and act content. RESULTS: Participants who were randomized to perform kind acts for others showed significant reductions in CTRA gene expression relative to controls. Participants who were randomized to perform kind acts for themselves also showed significant reductions in CTRA gene expression relative to controls, but this pattern emerged only for those who failed to perform the requested self-kind acts (protocol non-adherent). Those who fully adhered to the self-kindness protocol showed no change in CTRA gene expression and did not differ from controls. Act content analyses implicated self-stress-reducing behavior in the paradoxical effects of self-kindness and the physical presence of others in the effects of prosocial behavior. CONCLUSIONS: Prosocial engagement-doing something kind for others rather than oneself-reduces CTRA gene expression. The nature of kind acts and their intended recipient plays a key role in shaping the genomic impact of kindness.

Interpersonal Chemistry: What Is It, How Does It Emerge, and How Does It Operate?

Although chemistry is a well-known, sought-after interpersonal phenomenon, it has remained relatively unexplored in the psychological literature. The purpose of this article is to begin articulating a theoretically grounded and precise definition of interpersonal chemistry. To that end, we propose a conceptual model of interpersonal chemistry centered around the notion that when two or more individuals experience chemistry with one another, they experience their interaction as something more than the sum of their separate contributions. Our model stipulates that chemistry encompasses both behavior (i.e., what chemistry "looks like") and its perception (i.e., what it "feels like"). The behavior involves interaction sequences in which synchronicity is high and in which people's goals are expressed and responded to in supportive and encouraging ways. The perception of chemistry includes cognitive (i.e., perception of shared identity), affective (i.e., positive affect and attraction), and behavioral (i.e., perceived goal-relevant coordination) components. We review existing research on chemistry as well as supporting evidence from relevant topics (e.g., attraction, similarity, perceived partner responsiveness, synchrony) that inform and support this model. We hope that this conceptual model stimulates research to identify the circumstances in which chemistry arises and the processes by which it affects individuals, their interactions, and their relationships.

Does ±3,4-methylenedioxymethamphetamine (ecstasy) induce subjective feelings of social connection in humans? A multilevel meta-analysis.

3,4-Methylenedioxymethamphetamine (MDMA) is a psychostimulant known for producing positive subjective effects and for enhancing social functioning and social connection in both clinical and recreational settings. Over the past two decades, scientists have begun to study the psychological effects of MDMA through rigorous placebo-controlled experimental work. However, most existing studies have small Ns, and the average sizes of the reported effects are unknown, creating uncertainty about the impact of these findings. The goal of the present study was to quantify the strength of MDMA's effects on self-reported social connection by aggregating sociability-related outcomes across multiple placebo-controlled studies. To this end, we conducted a multilevel meta-analysis based on 27 studies, 54 effect sizes, and a total of 592 participants. The results revealed a moderate-to-large effect (d = 0.86; 95% CI [0.68, 1.04]; r = .39; 95% CI [.32, .46]) of MDMA on self-reported sociability-related outcomes (e.g., feeling loving, talkative, and friendly). Given the magnitude of its effect on felt sociability, we propose that MDMA may have powerful implications for a variety of social contexts and for clinical settings, in particular. Finally, we discuss potential mechanisms underlying the relationship between MDMA and sociability-related feelings, as well as future directions for experimental work in this area.

Two-Dimensional van der Waals Nanoplatelets with Robust Ferromagnetism.

We have synthesized unique colloidal nanoplatelets of the two-dimensional (2D) van der Waals ferromagnet CrI3 and have characterized these nanoplatelets structurally, magnetically, and by magnetic circular dichroism spectroscopy. The CrI3 nanoplatelets have lateral dimensions of ∼25 nm and thicknesses of only ∼4 nm, corresponding to just a few CrI3 monolayers. Magnetic and magneto-optical measurements demonstrate robust 2D ferromagnetic ordering with Curie temperatures similar to bulk CrI3, despite their small size. These data also show magnetization steps akin to those observed in micron-sized few-layer 2D sheets associated with concerted spin-reversal of individual CrI3 layers within few-layer van der Waals stacks. Similar data have also been obtained for CrBr3 and anion-alloyed Cr(I1-xBrx)3 nanoplatelets. These results represent the first example of lateral nanostructures of 2D van der Waals ferromagnets of any composition. The demonstration of robust ferromagnetism at nanometer lateral dimensions opens new doors for miniaturization in spintronics devices based on van der Waals ferromagnets.