Versatile ionic liquid gels formed by dynamic covalent bonding and microphase separated structures.

It is challenging for ionic liquid gels to achieve the combination of rapid self-healing with high toughness. Here, ionic liquid gels (DI-PR) were prepared from readily available materials. A dynamic covalently bonded oxime-carbamate was prepared from polycaprolactone diol, isophorone diisocyanate and dimethylethyleneglyoxime, followed by addition of the "rigid-flexible" cross-linking agent rutin to chemically cross-link the polymer chains and afford the ionic liquid gels, DI-PR. The tensile strength, elongation at break and toughness of the DI-PR gels were as high as 16.5 MPa, 1132.6%, and 52.6 MJ m-3, respectively. The toughness is similar to that of natural silkworm silk (70 MJ m-3) and wool (60 MJ m-3). After stretching, the DI-PR can rebound within 1 s, their room temperature self-healing rate is as high as 92%, they remain functional over the temperature range -50 °C to 140 °C and the interface with a steel plate has an adhesion toughness of >2000 J m-2. These properties mean that the DI-PR gels are particularly suitable for use as anticorrosion coatings for submarine and underground gas and oil pipelines. The use of rutin, which combines rigid quercetin-based structural units with flexible glycoside-based structural units, as a cross-linking agent, provides a new method for improving the toughness of soft materials through its synergistic interaction with hard and soft chain fragments of polyurethanes.

Synthesis, characterization and application of oligomeric proanthocyanidin-rich dual network hydrogels.

A structurally dense hydrogel, with strong hydrogen bonding networks, was formed from poly(vinyl alcohol), sodium alginate, and oligomeric proanthocyanidins, using a combination of freeze-thaw cycles and calcium ion cross-linking. The structure of the hydrogel was characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. Mechanical testing and thermogravimetric analysis showed that incorporation of proanthocyanidins enhanced both the mechanical properties and the thermal stability of the hydrogel. The hydrogel was also demonstrated to have excellent ultraviolet resistance and antioxidant properties. The hydrogel was further shown that this hydrogel is also capable of generating electrochemical reactions, which strongly suggests that this hydrogel has exciting potential in many fields.

Carboxymethyl Cellulose/Polyacrylamide/Fe3O4 Magnetic Ion Imprinting Biosorbent for Removal and Recovery of La3.

To use resources rationally, the recovery and recycling of rare earth (RE) from industrial sewage have attracted a lot of attention. Herein, a polymer adsorbent CMC/PAM/Fe3O4 (CPF) was synthesized from renewable carboxymethyl cellulose (CMC), polyacrylamide (PAM), and Fe3O4 by the template of La3+ using ion imprinting technology. The CPF was characterized with X-ray diffraction (XRD), IR, X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM), and results show that PAM and CMC can crosslink with each other and form copolymers with Fe3O4 particles dispersing in it. The adsorption properties for the template ions La3+ were fully studied. It is found that CPF exhibited good adsorption performance with an adsorption capacity of 34.6 mg·g-1. Cycling experiments show that CPF still has high efficiency even after 5 cycles. Meanwhile, the desorption rate can reach more than 98%. The low wastage and high adsorption/desorption efficiency would enable CPF to be a good candidate adsorbent for removal/recovery of La3+ from industrial sewage.

Simple lignin-based, light-driven shape memory polymers with excellent mechanical properties and wide range of glass transition temperatures.

Lignin is the most abundant biomass source of aromatic hydrocarbons but, at present, is not effectively utilized. The development of simple and efficient methods for producing lignin-based polymers to replace petroleum-based products is an important strategy for promoting environmentally friendly and sustainable materials and controlling carbon emissions. In this work, lignin-based, light-driven shape memory polymers (ELIDs) with improved mechanical properties have been prepared from enzymatic hydrolysis lignin, itaconic acid and 1,12-dodecanediol, without any chemical modification of the lignin. The polymers contain large proportions of lignin (20-40 wt%, designated ELID20 to ELID40) and their mechanical properties are dependent on the lignin content. Maximum tensile strength (46.9 MPa) was achieved with ELID30, maximum elongation at break (93.7 %) was achieved with ELID20 and highest fracture energy (10.75 J cm-3) was achieved with ELID25. These excellent mechanical properties are accompanied by good thermal stability and a wide range of glass transition temperatures (21.2-157.3 °C), supporting a broad range of applications. The shape fixation rate (Rf) and shape recovery rate (Rr) were highest for ELID30 (98.7 % and 97.4 %, respectively). Under 1 sun simulated solar irradiation, ELID20 reached a temperature exceeding the glass transition temperature in 15 s and, under 3 sun simulated solar irradiation, ELID30 reached a temperature of 130 °C and shape recovered in 60 s. The excellent mechanical properties and good light-driven shape memory of ELIDs provide inspiration for the development and utilization of lignin-based polymers.

High lignin, light-driven shape memory polymers with excellent mechanical performance.

With the gradual global standardization of carbon emission policies, the development of renewable resources to replace traditional fossil resources is assuming increasing importance. Lignin is the most abundant natural source of aromatic compounds and has the potential to replace petroleum-based aromatic hydrocarbons. In this work, the rigid benzene ring structure and excellent photothermal properties of lignin were exploited to produce light-driven lignin-based shape memory polymers (ELEPs) that contain high proportions of lignin and have good mechanical properties. Enzymatically hydrolyzed lignin (EL), epoxy soybean oil (ESO) and polyethylene glycol (PEG 400) were copolymerized and cured to form ELEPs, which have a disordered three-dimensional network. An increase in the proportion of EL from 40 to 60 wt% enhanced the mechanical properties, as reflected by an increase in tensile strength from 11.3 to 30.8 MPa and in the glass transition temperature (Tg) from 93 to 115.7 °C. Under simulated solar irradiation (2000 W m-2), ELEP50, which contains 50 wt% lignin and has a Tg of 105 °C, reached a surface temperature as high as 105 °C and achieved shape memory within 20 s. The shape fixation ratio (Rf) and shape recovery ratio (Rr) were stably >98 % and >97 %, respectively, over eight cycles in a bending-recovery experiment. The unique light-driven shape memory properties of ELEPs provide a method for high value utilization of EL, and the design strategy offers new ideas for producing novel intelligent materials.

Quantitative Study on Solubility Parameters and Related Thermodynamic Parameters of PVA with Different Alcoholysis Degrees.

In recent years, inverse gas chromatography (IGC) and molecular dynamics simulation methods have been used to characterize the solubility parameters and surface parameters of polymers, which can provide quantitative reference for the further study of the surface and interface compatibility of polymer components in the future. In this paper, the solubility parameters and surface parameters of two kinds of common alcoholysis, PVA88 and PVA99, are studied by using the IGC method. The accuracy of the solubility parameters obtained by the IGC experiment is verified by molecular dynamics simulation. On the basis of this, the influence of repeated units of polyvinyl alcohol (PVA) on solubility parameters is studied, so as to determine the appropriate chain length of the PVA for simulation verification calculation. The results show that the solubility parameters are not much different when the PVA chain length is 30 and above; the numerical trends of the solubility parameters of PVA88 and PVA99 at room temperature are the same as the results of molecular dynamics simulation; the dispersive surface energy γsd and the specific surface energy γssp are scattered with the temperature distribution and have a small dependence on temperature. On the whole, the surface energy of PVA99 with a higher alcoholysis degree is higher than that of PVA88 with a lower alcoholysis degree. The surface specific adsorption free energy (ΔGsp) indicates that both PVA88 and PVA99 are amphoteric meta-acid materials, and the acidity of PVA99 is stronger.

Catalytic hydrogenolysis of larix bark proanthocyanidins in ionic liquids produces UV blockers with potential for use in cosmetics.

The bark of larix, a major tree species in the coniferous forests of China's Greater Khingan Mountains, is typically treated as waste. The bark is, however, rich in flavonoids, known as proanthocyanidins, although their high degree of polymerization and high molecular weight reduce their biological activity and potential applications. Ionic liquids, a new type of "green solvent", characterized by low vapor pressure and good stability, have been developed and used as new solvents for naturally occurring macromolecules. Here, we used 1-butyl-3-methylimidazole chloride ([BMIM]Cl) as the ionic solvent to reduce the degree of polymerization of larix bark proanthocyanidins by Pd/C-catalyzed hydrogenolysis. The optimal reaction conditions, determined using an orthogonal experimental design, were: reaction temperature, 90 °C; reaction time, 1.5 h; catalyst loading, 4 g L-1 (Pd/C: [BMIM]Cl); and hydrogen pressure, 2.5 MPa. Characterization of the reaction products by UV-Vis and IR spectroscopy and gel permeation chromatographys showed that they retained the proanthocyanidin structure. We showed that whilst both the native and depolymerized proanthocyanidins were able to block UV light when added to commercially available skin creams and sunscreens, the depolymerized proanthocyanidins were more effective at a given concentration. This study expands the applications of a new "green" ionic liquid solvent, provides a technical foundation for the low-cost depolymerization of larix bark proanthocyanidins, and also explores a potential high-value use for waste larix bark as the source of a UV-blocking additive for cosmetics.

Simple, green, ultrasound-assisted preparation of novel core-shell microcapsules from octyl methoxycinnamate and oligomeric proanthocyanidins for UV-stable sunscreen.

Without sunscreens, UV rays in sunlight cause skin damage, ranging from dark spots and premature aging to skin cancer. Present sunscreens, however, are readily photodegraded, producing highly reactive radicals that can damage cells. To address this problem, we have now used ultrasound to prepare core-shell microcapsules, which offer improved protection against UV light and improved UV stability. The composite microcapsules have oligomeric proanthocyanidins (OPCs), which are amphiphilic plant-derived secondary metabolites, as the shell and octyl methoxycinnamate (OMC), which is a UVB absorber, as the core. The polyphenolic flavonoid structure of OPCs improves the UV stability of OMC and thus avoids the skin damage caused by OMC photodegradation products. In the microcapsules, π-π stacking interactions between OPCs and OMC molecules enhance the ability of OMC to absorb UV radiation and extend the absorption range from the UVB region (280-320 nm) to include the UVA and UVC regions (200-400 nm). The composite microcapsules were shown to be stable on storage and to be non-irritant to human skin. The ultrasound-assisted preparation of OMC/OPCs composite microcapsules is simple, efficient and green and provides a feasible strategy for the development of novel, more effective, sunscreens.

Facile fabrication of ion-imprinted Fe3O4/carboxymethyl cellulose magnetic biosorbent: removal and recovery properties for trivalent La ions.

An Fe3O4/carboxymethyl cellulose (Fe3O4/CMC) magnetic biosorbent was prepared using the ion-imprinting technology, where La(iii) was used as the template ion. The morphology and structure of Fe3O4/CMC were characterized by SEM, FTIR and XRD. It is found that nano Fe3O4 with inverse spinel structure can distribute in CMC and endow the composite with good magnetic properties. The adsorption performance such as adsorption capacity, influence of pH and initial concentration were fully explored. The prepared Fe3O4/CMC is revealed to have good adsorption properties with Q max of 61.5 mg g-1, in line with the pseudo-second-order kinetic model. When handling the multi-ion coexistence solution of Cu(ii), Ni(ii) and Cd(ii), Fe3O4/CMC shows high selective adsorption for La(iii). Meanwhile, cycling experiments find that the adsorption capacity is only slightly reduced (less than 5%) after 5-time reuse. Good adsorption properties, high selectivity and easy recovery give the newly-synthesized Fe3O4/CMC biosorbent broad application potential in the treatment of La(iii)-containing wastewater.

Quantitative Analysis of Solubility Parameters and Surface Properties of Larch Bark Proanthocyanidins.

Quantitative characterization of the solubility parameters and surface properties of larch bark proanthocyanidins will lay the foundation for quantitative studies of the interfacial interactions of proanthocyanidin/polymer composites and will improve the compatibility of components, with important practical and scientific significance. Here, the solubility parameters of highly polymerized larch polymeric proanthocyanidins (LPPCs) and less highly polymerized larch oligomeric proanthocyanidins (LOPCs) were determined experimentally by inverse gas chromatography (IGC). These values were then compared with the solubility parameters obtained using molecular dynamics simulations. The experimentally measured solubility parameters of LPPCs and LOPCs (20.5 and 22.09 (J/m-3)0.5, respectively) were in good agreement with the solubility parameters determined by molecular dynamics simulations (20.57 and 22.35 (J/m-3)0.5, respectively. IGC was also used to experimentally determine the total surface energy, which includes the dispersive component of surface energyand the specific component of surface energy , together with the surface acidity and basicity parameters of LPPCs and LOPCs at different temperatures. The surface properties of proanthocyanidins can be quickly and accurately evaluated by IGC, and both LPPCs and LOPCs were shown to be amphoteric materials. This study provides theoretical and technical support for the use of larch bark proanthocyanidins, which are non-toxic, renewable, and have good ultraviolet resistance, in the field of blending composites. The study also provides a reference for other studies on the interfacial interactions of wood fiber polymer composites.

Preparation of visible light-responsive photocatalytic paper containing BiVO4@diatomite/MCC/PVBCFs for degradation of organic pollutants.

Combining adsorption and photocatalysis is an effective strategy for degrading organic pollutants. Here, BiVO4@diatomite composite photocatalyst (BiVO4@diatomite CP) was prepared by hydrothermal synthesis from Bi(NO3)3·5H2O glycerin solution, NH4VO3 solution and diatomite. BiVO4@diatomite/microcrystalline cellulose/PVB composite fibers (BiVO4@diatomite/MCC/PVBCFs) were prepared from BiVO4@diatomite CPs, microcrystalline cellulose (MCC) and PVB ethanol solution using the electrospinning method. BiVO4@diatomite/MCC/PVBCFs were then mixed with pulp fibers to prepare the visible light-responsive photocatalytic paper. BiVO4@diatomite CP with a BiVO4/diatomite ratio of 6:4 had good interface states and displayed good photocatalytic activity with 64.32% degradation of methylene blue (MB) after 4 h. A PVB ethanol solution (6%) was formulated with BiVO4@diatomite CP and MCC to provide an ethanol spinning solution (12% solid) to prepare BiVO4@diatomite/MCC/PVBCFs (3:3:4). The resulting fibers had smooth surfaces, compact structures and exhibited good photocatalytic activity (66.80% and 56.80% degradation of MB and formaldehyde (HCHO), respectively, after 4 h). Photocatalytic paper containing 18% BiVO4@diatomite/MCC/PVBCFs had good photocatalytic activity with 50.20% degradation of HCHO after 4 h. This paper also had good physical properties and has the potential to be used for the photocatalytic degradation of indoor air pollutants, such as HCHO.

Simultaneous removal of Pb2+, Cu2+ and Cd2+ ions from wastewater using hierarchical porous polyacrylic acid grafted with lignin.

In PAA-g-lignin, phase separation, caused by the difference in expansion properties between lignin and polyacrylic acid, is used to build a porous hydrogel. In this study, PAA-g-APL was produced by grafting polyacrylic acid with acid-pretreated alkali lignin. Acid-pretreated alkali lignin acts as a hierarchical pore-forming agent that enhances the simultaneous adsorption capacities for Pb2+, Cu2+ and Cd2+ ions from wastewater. Notably, PAA-g-APL acted as a selective adsorbent for Pb2+ ions has an excellent selective removal coefficient α (20.22) in contaminated wastewater contained Cu2+ ions. Its molar partition coefficient for Pb2+ ions (68 %) is higher than that for either Cu2+ ions (28.6 %) or Cd2+ ions (3.4 %). At equilibrium, the total adsorption capacities of PAA-g-APL for Pb2+, Cu2+ and Cd2+ were 1.076 mmol g-1, 0.3233 mmol g-1 and 0.059 mmol g-1, respectively. The experimental kinetic data fitted well to a pseudo-second order model and to an intra-particle-diffusion model. The Freundlich isotherm model gave the best fit with the experimental equilibrium data. The ΔG° for PAA-g-APL is < 0, indicating that the adsorption of heavy metal ions is a spontaneous process. This study provides a highly promising candidate for the treatment of wastewater contaminated with a mixture of heavy metals.

A composite carbon-based solid acid-supported palladium catalyst (Pd/C-SO3H) for hydrogenolysis of plant-derived polymeric proanthocyanidins.

A composite catalyst, Pd/C-SO3H, has been prepared to depolymerize plant-derived polymeric proanthocyanidins (PPC). Different reaction conditions were explored and the catalyst was shown to have good performance and recyclability, as well as good thermal and acid-base stability. UV, FTIR and 1H NMR analyses showed that the depolymerization products (oligomeric proanthocyanidins, OPC) retained a condensed flavanol polyphenol structure and that the basic structural units of the polymers had not been destroyed. The antioxidant activity of the OPC was better than that of the PPC, and also better than that of 2,6-di-tert-butyl-4-methylphenol, which is widely used in industry, including as a food additive. OPC could, therefore, be developed as a commercially useful radical chain-breaking antioxidant. The preparation of Pd/C-SO3H provides an example of the design and development of a new composite catalyst that has high practical value. The study also provides a new technical route for the depolymerization of PPC and thus makes a useful contribution to the high-value utilization of renewable plant resources.

H3PW12O40/ZrO2 and 1-Butyl-3-methylimidazolium Chloride: A Double-Effect Catalyst for the Degradation of Alkali Lignin.

Alkali lignin is a component of the waste black liquor produced by the paper-making industry that is difficult to degrade. In recent years, the biological activities of lignin, such as free-radical scavenging and antioxidant capacity, have received increasing attention. Here, we prepared H3PW12O40/ZrO2 and used this catalyst together with the ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) as a double-effect catalyst for the degradation of alkali lignin. Single-factor and orthogonal tests showed that the best degradation conditions were as follows: reaction time, 2 h; reaction temperature, 100 °C; mass ratio of H3PW12O40/ZrO2 to lignin, 1:4; and substrate concentration, 2.5%. The phenolic hydroxyl group content of the lignin degradation product increased by 231.2% and the total hydroxyl group content increased by 337.1% when the double-effect catalyst was used rather than [BMIM]Cl alone. Analysis by gel permeation chromatography showed that both the weight-average molecular weight and the number-average molecular weight of the product were reduced and that the lignin was degraded into small-molecular-weight compounds by the macromolecule. The product after the catalytic degradation of lignin showed a markedly increased antioxidant capacity, which was similar to that of the commercial antioxidant, 2,6-ditert-butyl-4-methylphenol. The study opens up a new direction for the better utilization of lignin.

Low-Cost Ru/C-Catalyzed Depolymerization of the Polymeric Proanthocyanidin-Rich Fraction from Bark To Produce Oligomeric Proanthocyanidins with Antioxidant Activity.

A new method has been developed for the high-value utilization of larch bark, which is regarded as a low-value byproduct of the logging industry. Polymeric proanthocyanidins (PPCs) were extracted from the Larix gmelinii bark and depolymerized by catalytic hydrogenolysis, using ruthenium/carbon (Ru/C) as the catalyst. The method has been found that although the molecular weight of the depolymerized product was significantly lower, the basic structural units were not destroyed, and the product retained a condensed flavanol polyphenol structure; the depolymerized product contains very little Ru metal and thus complies with food safety standards; the antioxidant properties of both the depolymerized products and PPCs were better than those of the commonly used antioxidant 2,6-di-tert-butyl-4-methylphenol. The relative molecular weight and steric hindrance of the depolymerized products were lower than those of the PPCs, leading to better antioxidant performance. A new technical route for the depolymerization of PPCs from the L. gmelinii bark is provided. The route offers practical and commercial advantages, and the product could have many applications as an antioxidant.

Molecular Glue Strategy: Large-Scale Conversion of Clustering-Induced Emission Luminogen to Carbon Dots.

Carbon dots have wide applications in bioimaging, encryption, sensing, and light-emitting devices, but most preparations of carbon dots require complicated separation and purification steps. Here, a clustering-induced emission luminogen, sodium alginate, was covalently "glued" by ethylenediamine to prepare carbon dots on a 100 g scale, without any separation or purification. The conversion yield was as high as 94.7%. Theoretical calculations suggested that the fluorescence emission of as-prepared carbon dots (N-CDs) was mainly attributable to through-space conjugation between oxygen atoms and carbonyl moieties. The N-CDs were shown to have applications as a fluorescent ink for encryption and as a phosphor for white light-emitting diodes. This work provides a convenient method for the large-scale preparation of carbon dots and a new understanding of fluorescent emission of carbon dots.

Antioxidant and Fluorescence Properties of Hydrogenolyzised Polymeric Proanthocyanidins Prepared Using SO42-/ZrO2 Solid Superacids Catalyst.

Larix bark oligomeric proanthocyanidins (LOPC) were prepared from larix bark polymeric proanthocyanidins (LPPC) by catalytic hydrogenolysis using SO42-/ZrO2 solid superacid as the catalyst. The catalyst to polymeric proanthocyanidins ratio was 0.2:1 (m/m). The LOPC, obtained after hydrogenolysis at 100 °C for 4 h under 3 MPa hydrogen pressure, retained the structural characteristics of proanthocyanidins. The average degree of polymerization was reduced from 9.50% to 4.76% and the depolymerization yield was 53.85%. LOPC has good antioxidant properties and, at the same concentration, the reducing ability of LOPC was much higher than that of LPPC. The IC50 values of LOPC for scavenging DPPH• and ABTS•+ radicals were 0.046 mg/mL and 0.051 mg/mL, respectively. LOPC is biocompatible and has fluorescent properties that are affected by external factors, such as solvent polarity, pH and the presence of different metal ions. These features indicate that LOPC could be developed as a new biological fluorescent marker. The depolymerization of low-value polymeric proanthocyanidins to provide high-value oligomeric proanthocyanidins and the development of new applications for proanthocyanidins represent significant advances.

Correlation between Solubility Parameters and Properties of Alkali Lignin/PVA Composites.

Although lignin blending with thermoplastic polymers has been widely studied, the usefulness of the lignin⁻polymer composites is limited by the poor compatibility of the two components. In the present study, alkali lignin/PVA composite membranes were prepared by incorporating 10%, 15%, 20% and 25% alkali lignin into the composites. The thermodynamic parameters of the composites were measured using inverse gas chromatography (IGC). Composite membranes with 10%, 15%, 20%, and 25% alkali lignin had solubility parameters of 17.51, 18.70, 16.64 and 16.38 (J/cm³)0.5, respectively, indicating that the solubility parameter firstly increased, and then decreased, with increasing proportions of alkali lignin. When the alkali lignin content was 15%, the composites had the largest solubility parameters. The composite membrane with an alkali lignin content of 15% had a tensile strength of 18.86 MPa and a hydrophilic contact angle of 89°. We have shown that the solubility parameters of blends were related to mechanical and hydrophilic properties of the composites and the relationships have been verified experimentally and theoretically.

Quantitative Analysis of Relationship between Hansen Solubility Parameters and Properties of Alkali Lignin/Acrylonitrile-Butadiene-Styrene Blends.

Blends of alkali lignin and acrylonitrile-butadiene-styrene (ABS) resin are physically mixed and injected into the injection molding system. Although the components of the blend are bound together by intermolecular forces, noticeable phase separation still occurs. In the present study, inverse gas chromatography technology was used to characterize the Hansen solubility parameters of alkali lignin/ABS blends. The relationship between the Hansen solubility parameters and thermodynamic properties was then determined. Hansen solubility parameters, at room temperature, of alkali lignin/ABS blends containing 0, 10, 20, and 30 wt % alkali lignin were 17.40, 19.20, 18.98, and 17.37 (J/cm3)0.5, respectively. Hansen solubility parameters of the blends were shown, both experimentally and theoretically, to be related to their mechanical and thermal properties.

Hydrogenolysis and Activation of Soda Lignin Using [BMIM]Cl as a Catalyst and Solvent.

To improve the reactivity of the soda lignin, an acid ionic liquid 1-butyl-3-mthylimidazolium chloride ([BMIM]Cl) was used as the catalyst and solvent to degrade the soda lignin through hydrogenolysis. Structural elucidation of the lignin samples was conducted by using a combination of analytical methods including chemical analysis, ultraviolet spectrophotometry (UV spectrophotometry), Fourier transform infrared spectroscopy (FT-IR spectra), two-dimensional heteronuclear single quantum coherence nuclear magnetic resonance (2D-HSQC NMR) techniques, and gel permeation chromatography (GPC). The antioxidant activities of the lignin samples were evaluated using the diammonium 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS⁺) radical scavenging and 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging methods. The degradation mechanism was proposed based on the characterization results. The optimal reaction condition was as follows: the concentration of [BMIM]Cl in the solution was 10 wt %, the hydrogen initial pressure was 3 MPa, and the solution was heated for 4 h at 90 °C. After the reaction, the total hydroxyl content of the soda lignin increased by 81.3%, while the phenolic hydroxyl content increased by 23.1%. At the same time, the weight-average molar mass of the soda lignin sample decreased from 8220 to 6450 g/mol with an improved antioxidant activity. In addition, approximately 56.7% of the ß-O-4 linkages were degraded in the lreaction. The main effect of the acid ionic liquid [BMIM]C1 was related to the cleavage of ß-O-4 linkages. This study has shown the potential of using the catalyzed soda lignin as a natural polymer antioxidant.