1.
Angew Chem Int Ed Engl
; 59(32): 13335-13340, 2020 Aug 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32367589
RESUMO
We report the first f-block-ruthenocenophane complexes 1 (Dy) and 2 (Tb) and provide a comparative discussion of their magnetic structure with respect to earlier reported ferrocenophane analogues. While axial elongation of the rare trigonal-prismatic geometry stabilizes the magnetic ground state in the case of Dy3+ and results in a larger barrier to magnetization reversal (U), a decrease in U is observed for the case of Tb3+ .