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2.
Biomater Res ; 27(1): 115, 2023 Nov 10.
Artigo em Inglês | MEDLINE | ID: mdl-37950330

RESUMO

Coatings of metal-organic frameworks (MOFs) have potential applications in surface modification for medical implants, tissue engineering, and drug delivery systems. Therefore, developing an applicable method for surface-mounted MOF engineering to fabricate protective coating for implant tissue engineering is a crucial issue. Besides, the coating process was desgined for drug infusion and effect opposing chemical and mechanical resistance. In the present review, we discuss the techniques of MOF coatings for medical application in both in vitro and in vivo in various systems such as in situ growth of MOFs, dip coating of MOFs, spin coating of MOFs, Layer-by-layer methods, spray coating of MOFs, gas phase deposition of MOFs, electrochemical deposition of MOFs. The current study investigates the modification in the implant surface to change the properties of the alloy surface by MOF to improve properties such as reduction of the biofilm adhesion, prevention of infection, improvement of drugs and ions rate release, and corrosion resistance. MOF coatings on the surface of alloys can be considered as an opportunity or a restriction. The presence of MOF coatings in the outer layer of alloys would significantly demonstrate the biological, chemical and mechanical effects. Additionally, the impact of MOF properties and specific interactions with the surface of alloys on the anti-microbial resistance, anti-corrosion, and self-healing of MOF coatings are reported. Thus, the importance of multifunctional methods to improve the adhesion of alloy surfaces, microbial and corrosion resistance and prospects are summarized.

3.
J Environ Manage ; 345: 118656, 2023 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-37480664

RESUMO

In the present study, the magnetic Fe3O4/Ag2C2O4/Ag3PO4/Ag nanocomposite were prepared through a simple co-precipitation method by using calendula officinalis seed extract as a stabilizer. The fabricated quaternary photocatalyst was applied for to degrade food dye Brilliant Blue FCF (BB) and herbicide Paraquat (PQ) as contaminants at binary mixture in a batch and continuous flow-loop photoreactor under visible light irradiation and also the antibacterial properties was investigated. The fabricated nanocomposite was determined by XRD, FESEM, EDX, BET&BJH, UV-DRS, FT-IR and VSM methods to gain insight about structure, morphology, purity, surface area, optical, functional group and magnetic properties. The photoelectrochemical experiments, PL and DRS indicate the successful coupling of the active semiconductors. The degradation efficiency of BB and PQ was announced to be 88.9% and 92.72% under optimal conditions with a high reaction rate constant value (0.03 and 0.0326 min-1), respectively. The quaternary photocatalyst exhibited superior photocatalytic performance compared with Ag3PO4/Ag2C2O4 and Ag2C2O4. Various scavengers were used to explore the mechanism of photocatalytic performance and supports that [Formula: see text] and OH. is main active species in the degradation process of BB and PQ, respectively. Furthermore, the Fe3O4/Ag2C2O4/Ag3PO4/Ag also demonstrated bactericidal activity against Staphylococcus aureus (S. aureus) as gram-positive bacteria and Escherichia coli (E. coli) as gram-negative bacteria.


Assuntos
Poluentes Ambientais , Herbicidas , Água , Desinfecção , Escherichia coli , Espectroscopia de Infravermelho com Transformada de Fourier , Staphylococcus aureus , Luz
4.
Sci Total Environ ; 810: 151997, 2022 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-34848263

RESUMO

Residual antibiotics in food products originated from administration of the antibiotics to animals may be accumulated through food metabolism in the human body and endanger safety and health. Thus, developing a prompt and accurate way for detection of antibiotics is a crucial issue. The zero-dimensional fluorescent probes including metals based, carbon and graphene quantum dots (QDs), are highly sensitive materials to use for the detection of a wide range of antibiotics in natural products. These QDs demonstrate unique optical properties like tunable photoluminescence (PL) and excitation-wavelength dependent emission. This study investigates the trends related to carbon and metal based QDs preparation and modification, and their diverse detection application. We discuss the performance of QDs based sensors application in various detection systems such as photoluminescence, photoelectrochemical, chemiluminescence, electrochemiluminescence, colorimetric, as well as describing their working principles in several samples. The detecting mechanism of a QDs-based sensor is dependent on its properties and specific interactions with particular antibiotics. This review also tries to describe environmental application and future perspective of QDs for antibiotics detection.


Assuntos
Produtos Biológicos , Pontos Quânticos , Animais , Antibacterianos , Carbono , Corantes Fluorescentes , Humanos
5.
J Environ Manage ; 300: 113707, 2021 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-34534759

RESUMO

Selective removal of contaminants from water by membranes is of practical importance for water purification and environmental protection. In the present study, through an in-situ polymerization process, a novel composite of Fe3O4/molecularly imprinted resorcinol -formaldehyde-melamine resin (Fe3O4/MIRFMR) was synthesized. Then, the novel membrane was prepared from a tea filter bag (TFB) as a base substrate which was subsequently coated by a casting solution containing polyvinylidene fluoride (PVDF) matrix, Prunus scoparia gum as a hydrophilic agent and Fe3O4/MIRFMR as selective filler by phase inversion technique. Resorcinol as functional monomers with multiple hydrophilic groups such as -OH, -NH2 and -NH-, were used for selective removal of Rhodamine B (RhB) as target molecule. The Fe3O4/MIRFMR/PVDF/TFB membranes were characterized by FE-SEM, XRD, FTIR, BET, VSM, water contact angle (WCA) and mechanical analysis. The filtration and adsorption of RhB on the prepared membrane was investigated parameters in a cross-module filtration setup. Casting solution containing 0.01 g of Fe3O4/MIRFMR as optimum value showed good wettability, high water flux (42.5 L/m2 h), flux recovery ratio (88.9%), RhB removal efficiency (95.8%). The selectivity of 4.9, 3.3, 2.1 and 2.5 was found to be for RhB compared to AB, MG, EB, and TB dye. It seems that the fabricated membrane could be an effective and selective option for wastewater containing pollutants. The high removal efficiency, fouling resistance, good wettability and stability of the fabricated membrane are promising for use in practical water filtration, especially for selective removal of dyes.


Assuntos
Corantes , Membranas Artificiais , Fenômenos Magnéticos , Polivinil
7.
Heliyon ; 5(9): e02412, 2019 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-31687542

RESUMO

In the present research article we explore the synthesis method and adsorption capability of ZnFe oxides nanocomposites by using Pb as dopant. A conventional and simple batch adsorption method is selected and optimized. Pb@ZnFe2O4 NCs were fabricated by facile method i.e. co-precipitation method and characterized by FESEM, XRD, IR, EDX. The removal of dye has monitored by UV method. An outstanding result is obtained as adsorption efficiency of 1042 mg g-1 shows more significant performance than currently available bench-mark adsorbents. The optimized parameters pH 7.1, Adsorbent Mass: 50 mg, Initial Dye Concentration: 150 mg/l and Agitation Time: 90 min results in 96.49 % removal of CR (Congo red) dye. A CCD (central composite design) is applied to evaluate the role of adsorption variables. Based on its excellent performance, cost effectiveness, facile fabrication and large surface area, the Pb@ZnFe2O4 has considerable potential for the manufacture of cost effective and efficient adsorbents for environmental applications.

8.
Environ Sci Pollut Res Int ; 26(8): 8050-8068, 2019 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-30685863

RESUMO

CeO2/Ag2CrO4 composite photocatalyst was successfully fabricated using electrospinning and calcination and chemical precipitation method based on CeO2 ribbon-like fibers and characterized by field-emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS) and Fourier-transform infrared spectroscopy (FT-IR). The as-obtained CeO2/Ag2CrO4 composite used photocatalytic performance in the sonophotodegradation of rhodamine B in aqueous solution under visible-light (LED) irradiation. DRS analysis illustrates that CeO2/Ag2CrO4 composite exhibited enhanced absorption in the visible region-attributed CeO2 nanofibers. The effect of four effective parameters including initial concentration of rhodamine B (RhB), photocatalyst dosage, pH, and irradiation time was studied and optimized using central composite design. The kinetic studies confirmed ability of pseudo first-order reaction based on the Langmuir-Hinshelwood model for fitting empirical data, while its rate constant (kobs), L-H rate constants (kr), and L-H adsorption constants (KA) were 0.0449 min-1, 11.66 mg L-1 min-1 and 1.09E-3 mg L-1, respectively. The enhanced photocatalytic activity could be ascribed to the ultrasound field and formation of a heterojunction system among CeO2 and Ag2CrO4, which lead to a better mass transfer and higher efficiency of charge electron-hole separation, respectively.


Assuntos
Cério/química , Cromatos/química , Luz , Nanofibras/química , Rodaminas/análise , Compostos de Prata/química , Ondas Ultrassônicas , Poluentes Químicos da Água/análise , Purificação da Água/métodos , Adsorção , Catálise , Cério/efeitos da radiação , Cromatos/efeitos da radiação , Desenho de Equipamento , Cinética , Nanofibras/efeitos da radiação , Fotólise , Rodaminas/efeitos da radiação , Compostos de Prata/efeitos da radiação , Águas Residuárias/química , Poluentes Químicos da Água/efeitos da radiação , Purificação da Água/instrumentação
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