Spectroscopic determination of the s-wave scattering lengths of 86Sr and 88Sr.

We report the use of photoassociative spectroscopy to determine the ground-state s-wave scattering lengths for the main bosonic isotopes of strontium, 86Sr and 88Sr. Photoassociative transitions are driven with a laser red detuned by up to 1400 GHz from the 1S0-1P1 atomic resonance at 461 nm. A minimum in the transition amplitude for 86Sr at -494 +/- 5 GHz allows us to determine the scattering lengths 610a0 < a86 < 2300a0 for 86Sr and a much smaller value of -1a0 < a88 < 13a0 for 88Sr.

Photoassociative spectroscopy at long range in ultracold strontium.

We report photoassociative spectroscopy of 88Sr(2) in a magneto-optical trap operating on the 1S0-->3P1 intercombination line at 689 nm. Photoassociative transitions are driven with a laser red detuned by 600-2400 MHz from the 1S0-->1P1 atomic resonance at 461 nm. Photoassociation takes place at extremely large internuclear separation, and the photoassociative spectrum is strongly affected by relativistic retardation. A fit of the transition frequencies determines the 1P1 atomic lifetime (tau=5.22+/-0.03 ns) and resolves a discrepancy between experiment and recent theoretical calculations.