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1.
Int J Biometeorol ; 2024 May 14.
Artigo em Inglês | MEDLINE | ID: mdl-38744707

RESUMO

The risk of cardiovascular and respiratory diseases attributed to satellite-based PM2.5 has been less investigated. In this study, the attributable risk was estimated in an area of Iran. The predicted air PM2.5 using satellite data and a two-stage regression model was used as the predictor of the diseases. The dose-response linkage between the bias-corrected predictor employing a strong statistical approach and the outcomes was evaluated using the distributed lag nonlinear model. We considered two distinct scenarios of PM2.5 for the risk estimation. Alongside the risk, the attributable risk and number were estimated for different levels of PM2.5 by age and gender categories. The cumulative influence of PM2.5 particles on respiratory illnesses was statistically significant at 13-16 µg/m3 relative to the reference value (median), mostly apparent in the middle delays. The cumulative relative risk of 90th and 95th percentiles were 2.03 (CI 95%: 1.28, 3.19) and 2.25 (CI 95%: 1.28, 3.96), respectively. Nearly 600 cases of the diseases were attributable to the non-optimum values of the pollutant during 2017-2022, of which more than 400 cases were attributed to high values range. The predictor's influence on cardiovascular illnesses was along with uncertainty, indicating that additional research into their relationship is needed. The bias-corrected PM2.5 played an essential role in the prediction of respiratory illnesses, and it may likely be employed as a trigger for a preventative strategy.

2.
Int J Environ Health Res ; : 1-13, 2024 Mar 09.
Artigo em Inglês | MEDLINE | ID: mdl-38461371

RESUMO

Satellite-based exposure of fine particulate matters has been seldom used as a predictor of mortality. PM2.5 was predicted using Aerosol Optical Depths (AOD) through a two-stage regression model. The predicted PM2.5 was corrected for the bias using two approaches. We estimated the impact by two different scenarios of PM2.5 in the model. We statistically found different distributions of the predicted PM2.5 over the region. Compared to the reference value (5 µg/m3), 90th and 95th percentiles had significant adverse effect on total mortality (RR 90th percentile:1.45; CI 95%: 1.08-1.95 and RR 95th percentile:1.53; CI 95%: 1.11-2.1). Nearly 1050 deaths were attributed to any range of the air pollution (unhealthy range), of which more than half were attributed to high concentration range. Given the adverse effect of extreme values compared to the both scenarios, more efforts are suggested to define local-specific reference values and preventive strategies.

3.
Int J Biometeorol ; 67(12): 2081-2091, 2023 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-37845501

RESUMO

Compared to previous decade, impact of heat waves (HWs) on mortality in recent years needs to be discussed in Iran. We investigated temporal change in added impact of summer HWs on mortality in eight cities of Iran. The pooled length of HWs was compared between 2015-2022 and 2008-2014 using random and fixed-effects of meta-analysis regression model. The temporal change in impact of HWs was evaluated through interaction effect between crossbasis function of HW and year in a two-stage time varying model. In order to pool the reduced coefficients of each period, multivariate meta-regression model, including city-specific temperature and temperature range as heterogenicity factors, was used. In addition to relative risk (RR), attributable fraction (AF) of HW in the two periods was also estimated in each city. In the last years, the frequency of all HWs was higher and the weak HWs were significantly longer. The only significant RR was related to the lowest and low severe HWs which was observed in the second period. In terms of AF, compared to the strong HWs, all weak HWs caused a considerable excess mortality in all cities and second period. The subgroup analysis revealed that the significant impact in the second period was mainly related to females and elderlies. The increased risk and AF due to more frequent and longer HWs (weak HWs) in the last years highlights the need for mitigation strategies in the region. Because of uncertainty in the results of severe HWs, further elaborately investigation of the HWs is need.


Assuntos
Temperatura Alta , Mortalidade , Feminino , Humanos , Cidades/epidemiologia , Irã (Geográfico)/epidemiologia , Risco , Estações do Ano , Masculino , Idoso
4.
Sci Rep ; 12(1): 11473, 2022 07 06.
Artigo em Inglês | MEDLINE | ID: mdl-35794461

RESUMO

The adsorption of cadmium ions by magnetite (Fe3O4)@biosilica/alginate (MBA nano-hybrid) was the main aim of the present investigation. Herein, MBA nano-hybrid was synthesized via chemical precipitation technique. As-synthesized MBA nano-hybrid was characterized using FT-IR, FESEM and XRD analyzes. Based on the results, the maximum adsorption capacity of the adsorbent for the removal of Cd(II) was obtained at the initial pH of 7.0. At the initial Cd(II) concentration of 40 mg/L, increasing the reaction time to 180 min led to the Cd adsorption of 35.36 mg/g. Since the removal of Cd(II) after the reaction time of 60 min was insignificant, the reaction time of 60 min was considered as optimum reaction time for performing the experimental runs. According to the results, Langmuir isotherm and pseudo-second order kinetic models were the best fitted models with high correlation coefficients (R2 > 0.99). The results of thermodynamic study indicated exothermic (positive ΔH°) and spontaneous nature (negative ΔG°) of the adsorption of Cd(II) on the surface of MBA nano-hybrid. Negligible reduction in the adsorption capacity of the nano-hybrid was observed (16.57%) after fifth experimental runs, indicating high reusability potential of the as-synthesized nano-hybrid adsorbent.


Assuntos
Nanopartículas de Magnetita , Adsorção , Alginatos , Cádmio/química , Espectroscopia de Infravermelho com Transformada de Fourier
5.
Chemosphere ; 297: 134129, 2022 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-35231477

RESUMO

An aero-electrochemical advanced oxidation process (aero-EAOP) equipped with graphite cathode and dimensionally stable anodes was utilized for the treatment of aquatic media containing common and emerging contaminants. Among various anode materials, the application of Ti/RuO2/IrO2/SnO2 anode resulted in the highest effectiveness. Central composite experimental design (CCED) was used to attain the optimum operational parameters in terms of chlorine generation. Simultaneous decolorization and ammonium removal by the aero-EAOP process were investigated. Accordingly, the decolorization efficiency of 94%, along with the ammonium removal of 65.2%, was obtained within 30 min. Implementation of ultrasound and UV irradiation resulted in the complete decolorization within 25 and 20 min, respectively. In comparison, the influence of ultrasound and UV irradiation on the ammonium removal by the aero-EAOP reactor was not remarkable. Mineralization efficiency of 75.1% was obtained during the short reaction time of 30 min. With increasing hydraulic retention time (HRT) from 2 to 20 min, decolorization efficiency increased from 12.0 to 55.7% and ammonium removal efficiency increased from 16.6 to 37.8%, respectively. The complete degradation of amoxicillin (AMX) and tetracycline (TC) antibiotics were achieved within 25 and 30 min, respectively. The degradation efficiencies of ibuprofen (IBP), acetaminophen (APAP) and endocrine disrupting compound of bisphenol A (BPA) were obtained to be 58, 66 and 78% within 30 min, respectively. Photo-assisted aero-EAOP was more efficient than the aero-EAOP in degrading target emerging pollutants.


Assuntos
Compostos de Amônio , Grafite , Poluentes Químicos da Água , Ligas , Eletrodos , Oxirredução , Óxidos/química , Titânio/química , Poluentes Químicos da Água/análise
6.
Nano Lett ; 21(21): 9124-9130, 2021 Nov 10.
Artigo em Inglês | MEDLINE | ID: mdl-34723552

RESUMO

Metamaterials are a new class of artificial materials that can achieve electromagnetic properties that do not occur naturally, and as such they can also be a new class of photocatalytic structures. We show that metal-based catalysts can achieve electromagnetic field amplification and broadband absorption by decoupling optical properties from the material composition as exemplified with a ZnO/Cu metamaterial surface comprising periodically arranged nanocubes. Through refractive index engineering close to the index of air, the metamaterial exhibits near-perfect 98% absorption. The combination of plasmonics and broadband absorption elevates the weak electric field intensities across the nonplasmonic absorption range. This feedback between optical excitation and plasmonic excitation dramatically enhances light-to-dark catalytic rates by up to a factor of 181 times, compared to a 3 times photoenhancement of ZnO/Cu nanoparticles or films, and with angular invariance. These results show that metamaterial catalysts can act as a singular light harvesting device that substantially enhances photocatalysis of important reactions.

7.
Obstet Gynecol Sci ; 62(5): 352-356, 2019 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-31538079

RESUMO

OBJECTIVE: Primary dysmenorrhea typically occurs with no associated pelvic pathology and is common in adolescents and young women. This study evaluated the effect of bee propolis on relief of primary dysmenorrhea. METHODS: The study was performed in 2018 in Hamadan, in western Iran, among female students with primary dysmenorrhea. Participants were randomly divided into two groups, using balanced block randomization, and were administered a placebo or bee propolis capsules for 5 days during two menstruation cycles. The number of participants required was estimated to be 86 in total, with 43 students in each group according to the inclusion criteria. We used the visual analog scale to assess pain severity. The independent t-test was conducted for comparing between two groups, using SPSS 16.0. RESULTS: A significant change was found in the mean pain scores during the first (P<0.001) and second (P<0.001) months after using bee propolis in comparison with placebo. The means of the pain scores in the bee propolis group were 5.32±2.28 and 4.74±2.40 in first and second months after the intervention, respectively, whereas the means of the pain scores in the placebo group were 7.40±1.21 and 7.17±1.24 in first and second months after the intervention, respectively. CONCLUSION: Our study showed that the use of bee propolis for two months compared with placebo reduced primary dysmenorrhea during the first and second months after use, with no adverse effects. Therefore, it could be used as an alternative to nonsteroidal anti-inflammatory drugs for relief of primary dysmenorrhea.

8.
J Environ Health Sci Eng ; 17(1): 479-492, 2019 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-31297221

RESUMO

BACKGROUND: Azo dyes represent the most commonly used group of dyes in the textile industry. These organic dyes are mainly resistant to biodegradation and may exhibit toxic and carcinogenic properties. The purpose of this study was to investigate the effects of doping zinc oxide (ZnO) nanoparticles (NPs) with transition metals (silver, manganese, and copper) on the photocatalytic efficiency of ZnO NPs in the removal of Direct Blue 15 dye from aqueous environments under ultraviolet (UV) radiation and visible light irradiation. METHODS: One or two metals were used for doping the NPs. In total, seven types of undoped and transition metal-doped NPs were synthesized using the thermal solvent method with ZnO precursors and transition metal salts. The characteristics of the synthesized NPs were determined based on the scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, dynamic light scattering (DLS), atomic force microscopy (AFM), and zeta potential measurements. RESULTS: The produced ZnO NPs did not exhibit any particular photocatalytic activities under UV radiation and visible light irradiation. The highest removal efficiency under UV radiation was about 74% in the presence of silver-doped ZnO NPs, while the maximum efficiency under visible light was 70% in the presence of copper-doped ZnO NPs. The lowest removal efficiency was related to pure ZnO, which was 18.4% and 14.6% under UV and visible light irradiation, respectively. Although the efficiency of dye removal under visible light was not high compared to UV radiation, this efficiency was noteworthy in terms of both practical and economic aspects since it was achieved without the presence of ultraviolet radiation. CONCLUSIONS: The synthesis of transition metal-doped ZnO nanophotocatalysts (with one or two metals) under UV radiation or visible light irradiation could be used as an efficient and promising technology for the photocatalytic removal of Direct Blue 15 dye from aqueous environments.

9.
Ultrason Sonochem ; 55: 117-124, 2019 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-31084785

RESUMO

The aim of the present investigation was the combination of ZnO nanostructures with nano-cellulose (NC) for the efficient degradation of tetracycline (TC) antibiotic under ultrasonic irradiation. The removal efficiency of 12.8% was obtained by the sole use of ultrasound (US), while the removal efficiency increased up to 70% by the US/ZnO treatment process. Due to the integration of ZnO nanostructures with NC, the removal efficiency of 87.6% was obtained within 45 min. The removal efficiency substantially decreased in the presence of tert-butyl alcohol (more than 25% reduction), indicating that radOH-mediation oxidation is responsible for the degradation of TC molecules. Peroxymonosulfate (PMS) led to the most enhancing effect on the removal of TC among percarbonate, persulfate and periodate ions. The addition of PMS caused the degradation efficiency of 96.4% within the short contact time of 15 min. The bio-toxicity examination on the basis of inhibition test conducted on activated sludge revealed diminishing the oxygen consumption inhibition percent [IOUR (%)] from 33.6 to 22.1% during the US/ZnO/NC process. Consequently, the utilization of the US/ZnO/NC process can convert TC molecules to less toxic compounds. However, longer reaction time is required for complete conversion into non-toxic substances.


Assuntos
Celulose/química , Nanocompostos/química , Tetraciclina/química , Tetraciclina/isolamento & purificação , Ondas Ultrassônicas , Óxido de Zinco/química , Antibacterianos/química , Antibacterianos/isolamento & purificação , Catálise , Oxidantes/química , Peróxidos/química , Água/química , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação
10.
Int J Biol Macromol ; 133: 712-721, 2019 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-31022483

RESUMO

Recovery of antibiotics from water and wastewaters has recently gained a great deal of attention due to their serious health and environmental problems. In this work, a magnetite imprinted chitosan polymer nanocomposites (Fe-CS NCs) were synthesized and applied for the adsorptive removal of ciprofloxacin (CIFO) as a model fluoroquinolone antibiotics. The composition and surface morphology of Fe-CS NCs were studied by SEM, BET, XRD, TEM, FTIR and zeta potential meter. Modelling and optimization of adsorption process were studied using response surface methodology (RSM). The reliability of the RSM models was tested by fitting the data. A comparative analysis of the results derived from the models demonstrated that the second-order model was the best. From the contour plotting results, at pH < pHiep low adsorption rate was observed due to protonation of the chitosan NH2 groups, whereas the adsorption rate was significantly enhanced and achieved to a maximum level at pH 6 due to the electrostatic interactions and hydrophobic interactions. Under optimum conditions, maximum removal efficiency and maximum adsorption capacity were obtained 68% and 142 mg/g, respectively. Well regenerability of Fe-CS together with its high capacity of fluoroquinolone antibiotics removal provide a promisable strategy to remediation of wastewaters.


Assuntos
Quitosana/química , Ciprofloxacina/química , Óxido Ferroso-Férrico/química , Nanocompostos/química , Adsorção , Cinética , Modelos Químicos , Termodinâmica
11.
J Environ Manage ; 224: 315-326, 2018 Oct 15.
Artigo em Inglês | MEDLINE | ID: mdl-30056351

RESUMO

In the present investigation, the treatment of amoxicillin (AMX)-polluted water by the activated persulfate (PS) was considered. As a novel research, continuously electro-generated magnetite (Fe3O4) nanoparticles (CEMNPs) were utilized as the activator of PS in an electrochemical medium. The PS/CEMNPs displayed a remarkable enhancement in the decomposition of AMX molecules up to 72.6% compared with lonely PS (24.8%) and CEMNPs (13.4%). On the basis of pseudo-first order reaction rate constants, the synergy percent of about 70% was achieved due to the combination of PS with CEMNPs. The adverse influence of free radical-scavenging compounds on the efficiency of the PS/CEMNPs process was in the following order: carbonate < chloride < tert-butyl alcohol < ethanol. Overall, these results proved the main role of free radical species in degrading AMX. The implementation of ultrasound (US) enhanced the performance of the PS/CEMNPs process. Nevertheless, the highest degradation efficiency of about 94% was achieved when UV254 lamp was joined the PS/CEMNPs system. Under UV254 and US irradiation, the results showed significant potential of the PS/CEMNPs process for degrading AMX antibiotic and generating low toxic effluent based on the activated sludge inhibition test. However, more time is needed to achieve the acceptable mineralization.


Assuntos
Amoxicilina/isolamento & purificação , Nanopartículas , Purificação da Água , Antibacterianos , Óxido Ferroso-Férrico , Oxirredução , Poluentes Químicos da Água
12.
J Colloid Interface Sci ; 522: 228-241, 2018 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-29604441

RESUMO

In the present work, ultrasonically facilitated adsorption (UFA) of a cationic dye [Basic Red 46 (BR46)] was examined using cellulosic nanostructures obtained from broom and cooler straw. Although the exclusive application of the nanostructured broom resulted in the 43.51% adsorption of BR46, the UFA process gave rise to the substantial removal efficiency of about 93%. In the case of the nanostructured straw, the efficiency was increased from 36.9% to 55.7%. The UFA process for both adsorbents reached the equilibrium within 60 min which was shorter than the time for the only adsorption. According to the values of the mean free energy (E), the decolorization via the UFA process applying broom (15.81 kJ/mol) and straw (11.18 kJ/mol) nanostructures was occurred chemically. An insignificant loss in the adsorption capacity of both adsorbents was observed after three regeneration tests by means of 0.05 M hydrochloric acid, indicating the good reusability potential of the as-synthesized cellulosic nanostructures.

13.
Bioelectromagnetics ; 38(7): 550-558, 2017 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-28799651

RESUMO

Since the development of communication devices and expansion of their applications, there have been concerns about their harmful health effects. The main aim of this study was to investigate laptop thermal effects caused by exposure to electromagnetic fields and thermal sources simultaneously; propose a nondestructive, replicable process that is less expensive than clinical measurements; and to study the effects of positioning any new device near the human body in steady state conditions to ensure safety by U.S. and European standard thresholds. A computer simulation was designed to obtain laptop heat flux from SolidWorks flow simulation. Increase in body temperature due to heat flux was calculated, and antenna radiation was calculated using Computer Simulation Technology (CST) Microwave Studio software. Steady state temperature and specific absorption rate (SAR) distribution in user's body, and heat flux beneath the laptop, were obtained from simulations. The laptop in its high performance mode caused 420 (W/m2 ) peak two-dimensional heat flux beneath it. The cumulative effect of laptop in high performance mode and 1 W antenna radiation resulted in temperatures of 42.9, 38.1, and 37.2 °C in lap skin, scrotum, and testis, that is, 5.6, 2.1, and 1.4 °C increase in temperature, respectively. Also, 1 W antenna radiation caused 0.37 × 10-3 and 0.13 × 10-1 (W/kg) peak three-dimensional SAR at 2.4 and 5 GHz, respectively, which could be ignored in reference to standards and temperature rise due to laptop use. Bioelectromagnetics. 38:550-558, 2017. © 2017 Wiley Periodicals, Inc.


Assuntos
Simulação por Computador , Computadores , Campos Eletromagnéticos/efeitos adversos , Genitália Masculina/efeitos da radiação , Pele/efeitos da radiação , Temperatura , Absorção de Radiação , Adulto , Temperatura Corporal/efeitos da radiação , Humanos , Masculino , Especificidade de Órgãos
14.
Environ Sci Pollut Res Int ; 24(17): 15157-15166, 2017 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-28500548

RESUMO

The application of a novel nanocomposite synthesized through the combination of Fe3O4 nanoparticles and bone char particles for the adsorption of As(V) ions in the aquatic medium was investigated. As-prepared nanocomposite was immobilized by using chitosan biopolymer. The characterization of the nanocomposite was performed via SEM, XRD, FT-IR, and BET together with the determination of zero-point charge of the adsorbent surface. As results, the obtained experimental data were fitted well with pseudo-first-order kinetic model (R2 = 0.997) and Langmuir isotherm model (R2 = 0.990) with the maximum adsorption capacity of about 112 µg/g. Increasing the dosage of nanocomposite and initial solute concentration led to increasing the adsorption capacity of As(V) ions, while decreasing the solution temperature resulted in the enhanced adsorption process. According to the results of thermodynamic study, the adsorption of As(V) ions onto the nanocomposite was spontaneous and exothermic in nature.


Assuntos
Arsênio/química , Quitosana/química , Nanocompostos , Poluentes Químicos da Água/química , Adsorção , Descontaminação , Concentração de Íons de Hidrogênio , Cinética , Espectroscopia de Infravermelho com Transformada de Fourier
15.
J Environ Manage ; 187: 111-121, 2017 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-27888712

RESUMO

This study was performed to assess the efficiency of silica nanopowder (SNP)/milk vetch-derived charcoal (MVDC) nanocomposite coupled with the ultrasonic irradiation named sono-adsorption process for treating water-contained Basic Red 46 (BR46) dye. Field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and Fourier transform infrared spectroscopy (FT-IR) were performed for the characterization of as-prepared adsorbent. The sono-assisted adsorption process was optimized using response surface optimization on the basis of central composite design by the application of quadratic model. Accordingly, the color removal can be retained more than 93% by an initial BR46 concentration of 8 mg/L, sonication time of 31 min, adsorbent dosage of 1.2 g/L and initial pH of 9. The pseudo-second order kinetic model described the sono-assisted adsorption of BR46 reasonably well (R2 > 0.99). The intra-particular diffusion kinetic model pointed out that the sono-assisted adsorption of BR46 onto SNP/MVDC nanocomposite was diffusion controlled as well as that ultrasonication enhanced the diffusion rate.


Assuntos
Astrágalo/química , Compostos Azo/isolamento & purificação , Corantes/isolamento & purificação , Nanocompostos/química , Poluentes Químicos da Água/isolamento & purificação , Adsorção , Compostos Azo/química , Carvão Vegetal/química , Corantes/química , Difusão , Concentração de Íons de Hidrogênio , Cinética , Modelos Teóricos , Dióxido de Silício/química , Espectroscopia de Infravermelho com Transformada de Fourier , Indústria Têxtil , Ultrassom/métodos , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/química , Difração de Raios X
16.
J Environ Manage ; 179: 47-57, 2016 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-27173890

RESUMO

The scope of this study was the use of bentonite as the carrier of ZnO nanoparticles for enhancing the sonocatalytic decolorization of Basic Red 46 (BR46) in the aqueous phase. The results demonstrated the higher sonocatalytic activity of bentonite-supported ZnO nanoparticles (BSZNs) in comparison with the suspended ZnO nanoparticles (SZNs). The particle size of BSZNs (5-40 nm) was lower than that of SZNs (20-120 nm). Due to the immobilization of ZnO nanoparticles, a specific surface area of 80.6 m(2)/g was obtained for the BSZNs, which was higher than the specific surface area of the raw bentonite (42.2 m(2)/g). Optimization of the process via response surface methodology (RSM) based on central composite design (CCD) showed the maximum sonocatalytic decolorization efficiency (%) of 89.92% in which the initial dye concentration, the ZnO/bentonite ratio, the sonocatalyst dosage, and the initial pH were 6 mg/L, 0.3, 2.5 g/L and 9, respectively. The byproducts generated during the sonocatalysis of BR46 over BSZNs were identified using gas chromatography-mass spectrometry (GC-MS) analysis. From an application viewpoint, the sonocatalysis of real textile wastewater resulted in a COD removal efficiency (%) of about 44% within a reaction time of 150 min.


Assuntos
Bentonita/química , Nanopartículas/química , Indústria Têxtil , Eliminação de Resíduos Líquidos/métodos , Óxido de Zinco/química , Compostos Azo/química , Catálise , Ultrassom/métodos , Águas Residuárias/química
17.
Ultrason Sonochem ; 32: 181-190, 2016 09.
Artigo em Inglês | MEDLINE | ID: mdl-27150759

RESUMO

The improvement of sonocatalytic treatment of real textile wastewater in the presence of MgO nanoparticles was the main goal of the present study. According to our preliminary results, the application of pulse mode of sonication, together with the addition of periodate ions, produced the greatest sonocatalytic activity and consequently, the highest chemical oxygen demand (COD) removal efficiency (73.95%) among all the assessed options. In the following, pulsed sonocatalysis of real textile wastewater in the presence of periodate ions was evaluated response surface methodologically on the basis of central composite design. Accordingly, a high correlation coefficient of 0.95 was attained for the applied statistical strategy to optimize the process. As results, a pulsed sonication time of 141min, MgO dosage of 2.4g/L, solution temperature of 314K and periodate concentration of 0.11M gave the maximum COD removal of about 85%. Under aforementioned operational conditions, the removal of total organic carbon (TOC) was obtained to be 63.34% with the reaction rate constant of 7.1×10(-3)min(-1) based on the pseudo-first order kinetic model (R(2)=0.99). Overall, periodate-assisted pulsed sonocatalysis over MgO nanoparticles can be applied as an efficient alternative process for treating and mineralizing real textile wastewater with good reusability potential.


Assuntos
Nanopartículas , Ácido Periódico , Águas Residuárias , Indústria Têxtil , Têxteis , Eliminação de Resíduos Líquidos
18.
Ultrason Sonochem ; 30: 123-31, 2016 May.
Artigo em Inglês | MEDLINE | ID: mdl-26615797

RESUMO

The present study focused on the synthesis of nanostructured MgO via sonochemical method and its application as sonocatalyst for the decolorization of Basic Red 46 (BR46) dye under ultrasonic irradiation. The sonocatalyst was characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) equipped with energy dispersive X-ray microanalysis (EDX). In the following, the sonocatalytic removal of the dye under different operational conditions was evaluated kinetically on the basis of pseudo first-order kinetic model. The reaction rate of sonocatalyzed decolorization using MgO nanostructures (12.7 × 10(-3) min(-1)) was more efficient than that of ultrasound alone (2.0 × 10(-3) min(-1)). The increased sonocatalyst dosage showed better sonocatalytic activity but the application of excessive dosage should be avoided. The presence of periodate ions substantially increased the decolorization rate from 14.76 × 10(-3) to 33.4 × 10(-3) min(-1). Although the application of aeration favored the decolorization rate (17.8 × 10(-3) min(-1)), the addition of hydrogen peroxide resulted in a considerable decrease in the decolorization rate (9.5 × 10(-3) min(-1)) due to its scavenging effects at specific concentrations. Unlike alcoholic compounds, the addition of phenol had an insignificant scavenging effect on the sonocatalysis. A mineralization rate of 7.4 × 10(-3) min(-1) was obtained within 120 min. The intermediate byproducts were also detected using GC-MS analysis.

19.
Environ Sci Pollut Res Int ; 22(21): 16875-80, 2015 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-26104905

RESUMO

In this study, Cu-doped ZnO nanoparticles were investigated as an efficient synthesized catalyst for photodegradation of humic substances in aqueous solution under natural sunlight irradiation. Cu-doped ZnO nanocatalyst was prepared through mild hydrothermal method and was characterized using FT-IR, powder XRD and SEM techniques. The effect of operating parameters such as doping ratio, initial pH, catalyst dosage, initial concentrations of humic substances and sunlight illuminance were studied on humic substances degradation efficiency. The results of characterization analyses of samples confirmed the proper synthesis of Cu-doped ZnO nanocatalyst. The experimental results indicated the highest degradation efficiency of HS (99.2%) observed using 1.5% Cu-doped ZnO nanoparticles at reaction time of 120 min. Photocatalytic degradation efficiency of HS in a neutral and acidic pH was much higher than that at alkaline pH. Photocatalytic degradation of HS was enhanced with increasing the catalyst dosage and sunlight illuminance, while increasing the initial HS concentration led to decrease in the degradation efficiency of HS. Conclusively, Cu-doped ZnO nanoparticles can be used as a promising and efficient catalyst for degradation of HS under natural sunlight irradiation.


Assuntos
Cobre/química , Substâncias Húmicas/análise , Nanopartículas/química , Luz Solar , Poluentes Químicos da Água/análise , Óxido de Zinco/química , Catálise , Água Potável/normas , Substâncias Húmicas/efeitos da radiação , Concentração de Íons de Hidrogênio , Microscopia Eletrônica de Varredura , Modelos Teóricos , Fotólise , Soluções , Espectroscopia de Infravermelho com Transformada de Fourier , Poluentes Químicos da Água/efeitos da radiação , Purificação da Água/métodos , Qualidade da Água
20.
Environ Technol ; 36(5-8): 1057-62, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-25295616

RESUMO

The aim of this work was to enhance the efficiency of a bioelectrochemical denitrification process using a biocathode of carbon felt (CF)/multiwall carbon nanotube (MWCNT) composite. The efficiency of the bioelectrochemical denitrification was assessed as the function of various operational parameters, such as ORP, pH, current density, retention time and nitrate concentrations. Scanning electron microscope (SEM) images of the biocathode surfaces revealed a homogeneous distribution of the MWCNT on the CF matrix. Optimum ORP, pH, current density and retention time were -100 mV, 7.0, 15 mA/cm2 and 6 h, respectively. The highest nitrate removal efficiency at the optimum condition was 92.7% for CF/MWCNT. The reduction time for achieving the nitrate standard using CF/MWCNT was 4 h. It is proposed that the prepared nanocomposite will have the best biocathode properties in the bioelectrochemistry denitrification experiments.


Assuntos
Desnitrificação , Técnicas Eletroquímicas , Nanotubos de Carbono , Concentração de Íons de Hidrogênio , Nitratos
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