Work Extraction from Unknown Quantum Sources.

Energy extraction is a central task in thermodynamics. In quantum physics, ergotropy measures the amount of work extractable under cyclic Hamiltonian control. As its full extraction requires perfect knowledge of the initial state, however, it does not characterize the work value of unknown or untrusted quantum sources. Fully characterizing such sources would require quantum tomography, which is prohibitively costly in experiments due to the exponential growth of required measurements and operational limitations. Here, we therefore derive a new notion of ergotropy applicable when nothing is known about the quantum states produced by the source, apart from what can be learned by performing only a single type of coarse-grained measurement. We find that in this case the extracted work is defined by the Boltzmann and observational entropy in cases where the measurement outcomes are, or are not, used in the work extraction, respectively. This notion of ergotropy represents a realistic measure of extractable work, which can be used as the relevant figure of merit to characterize a quantum battery.

Quantum Charging Advantage Cannot Be Extensive without Global Operations.

Quantum batteries are devices made from quantum states, which store and release energy in a fast and efficient manner, thus offering numerous possibilities in future technological applications. They offer a significant charging speedup when compared to classical batteries, due to the possibility of using entangling charging operations. We show that the maximal speedup that can be achieved is extensive in the number of cells, thus offering at most quadratic scaling in the charging power over the classically achievable linear scaling. To reach such a scaling, a global charging protocol, charging all the cells collectively, needs to be employed. This concludes the quest on the limits of charging power of quantum batteries and adds to other results in which quantum methods are known to provide at most quadratic scaling over their classical counterparts.

Classical dynamical coarse-grained entropy and comparison with the quantum version.

We develop the framework of classical observational entropy, which is a mathematically rigorous and precise framework for nonequilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen as a generalization of Boltzmann entropy to systems with indeterminate initial conditions, and it describes the knowledge achievable about the system by a macroscopic observer with limited measurement capabilities; it becomes Gibbs entropy in the limit of perfectly fine-grained measurements. This quantity, while previously mentioned in the literature, has been investigated in detail only in the quantum case. We describe this framework reasonably pedagogically, then show that in this framework, certain choices of coarse-graining lead to an entropy that is well-defined out of equilibrium, additive on independent systems, and that grows toward thermodynamic entropy as the system reaches equilibrium, even for systems that are genuinely isolated. Choosing certain macroscopic regions, this dynamical thermodynamic entropy measures how close these regions are to thermal equilibrium. We also show that in the given formalism, the correspondence between classical entropy (defined on classical phase space) and quantum entropy (defined on Hilbert space) becomes surprisingly direct and transparent, while manifesting differences stemming from noncommutativity of coarse-grainings and from nonexistence of a direct classical analog of quantum energy eigenstates.

Probabilistic bound on extreme fluctuations in isolated quantum systems.

We ask to what extent an isolated quantum system can eventually "contract" to be contained within a given Hilbert subspace. We do this by starting with an initial random state, considering the probability that all the particles will be measured in a fixed subspace, and maximizing this probability over all time. This is relevant, for example, in a cosmological context, which may have access to indefinite timescales. We find that when the subspace is much smaller than the entire space, this maximal probability goes to 1/2 for real initial wave functions, and to π^{2}/16 when the initial wave function has been drawn from a complex ensemble. For example, when starting in a real generic state, the chances of collapsing all particles into a small box will be less than but come arbitrarily close to 50%. This contraction corresponds to an entropy reduction by a factor of approximately 2, thus bounding large downward fluctuations in entropy from generic initial states.