On the reproducibility of electron-beam lithographic fabrication of photonic nanostructures.

Photonic nanostructures such as gratings and ring resonators have become ubiquitous building blocks in Photonics. For example, they are used in filters, they resonantly enhance signals and act as grating couplers. Much research effort is invested in using such structures to create novel functionalities, which often employs electron-beam lithography. An intrinsic issue in this field is the ability to accurately achieve a specific operating wavelength, especially for resonant systems, because nanometer-scale variations in feature size may easily detune the device. Here, we examine some of the key fabrication steps and show how to improve the reproducibility of fabricating wavelength scale photonic nanostructures. We use guided mode resonance grating sensors as our exemplar and find that the exposure condition and the development process significantly affect the consistency of the resonance wavelength, amplitude, and sensitivity of the sensor. By having careful control over these factors, we can achieve consistent performance for all the sensors studied, with less than 10% variation in their resonance behaviors. These investigations provide useful guidelines for fabricating nanostructures more reliably and to achieve a higher success rate in exploratory experiments.

Noise Tolerant Photonic Bowtie Grating Environmental Sensor.

Resonant photonic refractive index sensors have made major advances based on their high sensitivity and contact-less readout capability, which is advantageous in many areas of science and technology. A major issue for the technological implementation of such sensors is their response to external influences, such as vibrations and temperature variations; the more sensitive a sensor, the more susceptible it also becomes to external influences. Here, we introduce a novel bowtie-shaped sensor that is highly responsive to refractive index variations while compensating for temperature changes and mechanical (linear and angular) vibrations. We exemplify its capability by demonstrating the detection of salinity to a precision of 0.1%, corresponding to 2.3 × 10-4 refractive index units in the presence of temperature fluctuations and mechanical vibrations. As a second exemplar, we detected bacteria growth in a pilot industrial environment. Our results demonstrate that it is possible to translate high sensitivity resonant photonic refractive index sensors into real-world environments.

Phase noise matching in resonant metasurfaces for intrinsic sensing stability.

Interferometry offers a precise means of interrogating resonances in dielectric and plasmonic metasurfaces, surpassing spectrometer-imposed resolution limits. However, interferometry implementations often face complexity or instability issues due to heightened sensitivity. Here, we address the necessity for noise compensation and tolerance by harnessing the inherent capabilities of photonic resonances. Our proposed solution, termed "resonant phase noise matching," employs optical referencing to align the phases of equally sensitive, orthogonal components of the same mode. This effectively mitigates drift and noise, facilitating the detection of subtle phase changes induced by a target analyte through spatially selective surface functionalization. Validation of this strategy using Fano resonances in a 2D photonic crystal slab showcases noteworthy phase stability (σ<10-4π). With demonstrated label-free detection of low-molecular-weight proteins at clinically relevant concentrations, resonant phase noise matching presents itself as a potentially valuable strategy for advancing scalable, high-performance sensing technology beyond traditional laboratory settings.

Nanophotonic and hydrogel-based diagnostic system for the monitoring of chronic wounds.

Chronic wounds present a major healthcare burden, yet most wounds are only assessed superficially, and treatment is rarely based on the analysis of wound biomarkers. This lack of analysis is based on the fact that sampling of wound biomarkers is typically invasive, leading to a disruption of the wound bed while biomarker detection and quantification is performed in a remote laboratory, away from the point of care. Here, we introduce the diagnostic element of a novel theranostic system that can non-invasively sample biomarkers without disrupting the wound and that can perform biomarker quantification at the point of care, on a short timescale. The system is based on a thermally switchable hydrogel scaffold that enhances wound healing through regeneration of the wound tissue and allows the extraction of wound biomarkers non-destructively. We demonstrate the detection of two major biomarkers of wound health, i.e., IL-6 and TNF-α, in human matrix absorbed into the hydrogel dressing. Quantification of the biomarkers directly in the hydrogel is achieved using a chirped guided mode resonant biosensor and we demonstrate biomarker detection within the clinically relevant range of pg/mL to µg/mL concentrations. We also demonstrate the detection of IL-6 and TNF-α at concentration 1 ng/mL in hydrogel dressing absorbed with clinical wound exudate samples. The high sensitivity and the wide dynamic range we demonstrate are both essential for the clinical relevance of our system. Our test makes a major contribution towards the development of a wound theranostic for guided treatment and management of chronic wounds.

Stable hybrid plasmonic directional coupler based on an embedded silver nanostructure waveguide.

In this paper, a stable hybrid plasmonic optical directional coupler based on an embedded silver nanostructure that can offer a power transfer up to 95% is presented. This optimum power transfer is obtained at an outer edge-to-edge separation of 0.58 µm between the two waveguides. The obtained propagation loss is as low as 0.0863 dB/µm. The electric field distributions of the symmetric and antisymmetric modes of the coupler are compared, and the transmission characteristics are studied in detail using the finite element method. The performances of the directional coupler have been further characterized in terms of excess loss, coupling degree, and directionality. The shortest coupling length at which the maximum power coupling occurs is obtained as 2.488 µm. The proposed compact directional coupler features good field confinement and low propagation loss, which opens the door for many device applications in photonic-integrated circuits and optoelectronic industries.

High azimuthal angle tolerant dual-channel wavelength filter from visible to NIR using conically mounted guided mode resonance structures.

We present a concept to design narrow linewidth dual-channel wavelength filters using the principle of wavelength tuning under conical mounting of guided mode resonance structure. The general procedure for the design of such filters from visible to NIR wavelength range is presented and validated experimentally. We show that already fabricated guided mode resonance structures that do not show dual wavelength filtering at these wavelengths in classical mounting can exhibit dual wavelength filtering in conical mounting. Using this principle, we design high azimuthal angle tolerant guided mode resonance dual wavelength filters at C-band communication wavelengths (1310 and 1550 nm) that are insensitive to azimuthal angle over a range of up to 20 deg, achieved in expense of a tolerance in the angle of incidence that is less than 3 deg.

Dynamic pulse propagation modelling for predictive femtosecond-laser-microbonding of transparent materials.

A dynamic pulse propagation modeling for femtosecond laser bonding of Borofloat glass is presented. The temperature evolution and internal modifications are predicted by incorporating the nonlinear electron dynamics along with temperature dependent thermal properties. The modelling predicts the spatial and temporal distribution of absorption coefficient and plasma density that gives quantitative estimations of the heat affected zone and weld geometry. The impact of focusing condition on heat affected zone and weld geometry is investigated, which for the first time to our knowledge allows to numerically determine the desired relative position between the geometrical focus of a femtosecond-laser-pulse and the interface of the two substrates to be welded. The prediction of the modelling on the offset distance is applied to weld Borofloat glass plates having optical contact and can be applied to other dielectric solids.

Enhanced absorption in a graphene embedded 1D guided-mode-resonance structure without back-reflector and interferometrically written gratings.

A theoretical model based on the coupled mode theory is presented to calculate the absorption in a graphene embedded 1D guided-mode-resonance (GMR) structure that does not require a back reflector. The optimized graphene-GMR structure can absorb up to 70% of the incident light which far exceeds the already reported results without using any back-metal reflector or Bragg mirror. The theoretical analysis is valid for binary gratings and pyramidal gratings which are patterned using an interference lithography system. We experimentally validate our theoretical results and analyze the influence of the geometrical parameters to achieve critical coupling for the enhanced absorption.

Ultrafast volume holography for stretchable photonic structures.

Stretchability and flexibility are two key requirements for manipulating the propagation of light in compact and high-performance lab-on-a-chip systems. These requirements are best met by embedding stretchable and flexible tuning elements such as volume phase gratings (VPGs) in polydimethylsiloxane (PDMS), making them attractive alternatives to conventional rigid optical elements. However, fabrication of these PDMS VPGs is a challenge, requiring extensive modifications to PDMS or complex multi-step processes that require long processing times. In this context, we propose the concept of "ultrafast volume holography" for the fabrication of stretchable photonic structures such as tunable VPGs directly in unmodified PDMS. Our concept translates insights in heat regulation via fs repetition rate control into volumetric patterning, forming periodic refractive index modulation of 1.95 × 10-4 in the PDMS without post-processing. VPGs formed are further demonstrated as active beam steering units and tunable spectroscopic optical elements.

High sensitivity guided-mode-resonance optical sensor employing phase detection.

We report an ultra-sensitive refractive index (RI) sensor employing phase detection in a guided mode resonance (GMR) structure. By incorporating the GMR structure in to a Mach-Zehnder Interferometer, we measured the phase of GMR signal by calculating the amount of fringe shift. Since the phase of GMR signal varies rapidly around the resonance wavelength, the interference fringe pattern it forms with the reference signal becomes very sensitive to the surrounding RI change. The sensitivity comes out to be 0.608π phase shift per 10-4 RI change in water medium which is more than 100 times higher than the other reported GMR based phase detection method. In our setup, we can achieve a minimum phase shift of (1.94 × 10-3) π that corresponds to a RI change of 3.43 × 10-7, outperforming any of reported optical sensors and making it useful to detect RI changes in gaseous medium as well. We have developed a theoretical model to numerically estimate the phase shift of the GMR signal that predicts the experimental results very well. Our phase detection method comes out to be much more sensitive than the conventional GMR sensors based on wavelength or angle resolved scanning methods.

ZnO nanowire-enabled light funneling effect for antireflection and light convergence applications.

We present a new light trapping technique to reduce reflection loss, as well as for light, focusing at submicron scales for solar cell and image sensing applications. We have fabricated hexagonal arrays of ZnO funnel-like structures on Si substrate by the patterned growth of ZnO nanowires in a hydrothermal growth process. The funnels are optimized so that the effective refractive index along the vertical direction decreases gradually from the Si surface to the top of funnel to reduce Fresnel reflection at a device-air interface. Finite difference time domain simulation is used for optimization of the minimum reflectivity and to analyze optical properties such as angle dependency, polarization dependency, and funneling effect. The structures function similar to a GRIN lens in light trapping and convergence. An optimized structure reduces the average reflectivity close to 3% in the wavelength range of 300-1200 nm with the possibility of confining incident light to a few hundreds of nanometers.

High sensitivity refractive index sensor based on simple diffraction from phase grating.

We present a technique for refractive index sensing using a phase grating structure. A grating under normal incidence can be designed such that the first-order diffracted light travels at a diffraction angle of 90° with respect to the zeroth order. The diffracted light, which is along the direction of periodicity, can further be diffracted from the grating and interfere with the zeroth-order light. Under this condition, the π phase difference that arises between the two interfering beams results in a transmission dip. We can tune this dip wavelength for senor applications, based on the grating equation. This Letter presents both simulation and experimental data that show good agreement with each other.

Surface second harmonic generation from silicon pillar arrays with strong geometrical dependence.

We present experimental demonstration and analysis of enhanced surface second harmonic generation (SHG) from hexagonal arrays of silicon pillars. Three sets of Si pillar samples with truncated cone-shaped pillar arrays having periods of 500, 1000, and 2000 nm, and corresponding average diameters of 200, 585 and 1550 nm, respectively, are fabricated by colloidal lithography and plasma dry etching. We have observed strong dependence of SHG intensity on the pillar geometry. Pillar arrays with a 1000 nm period and a 585 nm average diameter give more than a one order of magnitude higher SHG signal compared to the other two samples. We theoretically verified the dependence of SHG intensity on pillar geometry by finite difference time domain simulations in terms of the surface normal E-field component. The enhanced surface SHG light can be useful for nonlinear silicon photonics, surface/interface characterization, and optical biosensing.

Optical diode using nonlinear polystyrene ring resonators in two-dimensional photonic crystal structure.

An optical diode that uses nonlinear ring resonators in 2D photonic crystal is numerically simulated by using the finite-difference time-domain (FDTD) method. Nonlinear polystyrene is used as the Kerr medium forming ring resonators. The operating wavelength of the optical diode is considered to be the coupling wavelength at which light couples efficiently from waveguide to ring resonator, which is also equal to the average of the resonant wavelengths of the two resonators considered in the proposed structure. For both forward and backward propagation, the characteristics of the proposed optical diode are similar to those of an electronic diode. FDTD simulation is done using the MEEP package, which exhibits the desired results.