1.
J Org Chem
; 86(23): 17528-17532, 2021 12 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34793163
RESUMO
Two visible-light-mediated O-H insertion protocols involving oximes and aryldiazoacetates leading to different products depending on the solvent employed are reported. In DCM, direct O-H insertion takes place. In THF, there is the additional incorporation of the ring-opened form of this solvent into the structure of the product. These metal-free protocols are mild and tolerant to air and moisture. The preparation of an acaricide has been developed as an example of synthetic application.