Nano Groove and Prism-Structured Triboelectric Nanogenerators.

Enhancing the output power of triboelectric nanogenerators (TENGs) requires the creation of micro or nano-features on polymeric triboelectric surfaces to increase the TENGs' effective contact area and, therefore, output power. We deploy a novel bench-top fabrication method called dynamic Scanning Probe Lithography (d-SPL) to fabricate massive arrays of uniform 1 cm long and 2.5 µm wide nano-features comprising a 600 nm deep groove (NG) and a 600 nm high triangular prism (NTP). The method creates both features simultaneously in the polymeric surface, thereby doubling the structured surface area. Six thousand pairs of NGs and NTPs were patterned on a 6×5 cm2 PMMA substrate. It was then used as a mold to structure the surface of a 200 µm thick Polydimethylsiloxane (PDMS) layer. We show that the output power of the nano-structured TENG is significantly more than that of a TENG using flat PDMS films, at 12.2 mW compared to 2.2 mW, under the same operating conditions (a base acceleration amplitude of 0.8 g).

Built-In Packaging for Two-Terminal Devices.

Conventional packaging and interconnection methods for two-terminal devices, e.g., diodes often involve expensive and bulky equipment, introduce parasitic effects and have reliability issues. In this study, we propose a built-in packaging method and evaluate its performance compared to probing and wire bonding methods. The built-in packaging approach offers a larger overlap area, improved contact resistance, and direct connection to testing equipment. The experimental results demonstrate a 12% increase in current, an 11% reduction in resistance, and improved performance of the diode. The proposed method is promising for enhancing sensing applications, wireless power transmission, energy harvesting, and solar rectennas. Overall, the built-in packaging method offers a simpler, cheaper, more compact and more reliable packaging solution, paving the way for more efficient and advanced technologies in these domains.

Built-In Packaging for Single Terminal Devices.

An alternative packaging method, termed built-in packaging, is proposed for single terminal devices, and demonstrated with an actuator application. Built-in packaging removes the requirements of wire bonding, chip carrier, PCB, probe station, interconnection elements, and even wires to drive single terminal devices. Reducing these needs simplifies operation and eliminates possible noise sources. A micro resonator device is fabricated and built-in packaged for demonstration with electrostatic actuation and optical measurement. Identical actuation performances are achieved with the most conventional packaging method, wire bonding. The proposed method offers a compact and cheap packaging for industrial and academic applications.

Performance-Improved Highly Integrated Uniaxial Tristate Hybrid Nanogenerator for Sustainable Mechanical Energy Harvesting.

Despite advances in the development of individual nanogenerators, the level of output energy generation must be increased to meet the demands of commercial electronic systems and to broaden their scope of application. To harvest low-frequency ambient mechanical energy more efficiently, we proposed a highly integrated hybridized piezoelectric-triboelectric-electromagnetic (tristate) nanogenerator in a uniaxial structure. In its highly integrated approach, a piezoelectric nanogenerator (PENG) based on CsPbBr3 (cesium lead bromide) nanoparticles (NPs) and poly(dimethylsiloxane) (PDMS) nanocomposite was fabricated on a triboelectrically negative nanostructured polyimide (PI) substrate. A cylindrical aluminum electrode grooved with permanent magnets was directed to move along a spring-less metallic guide bounded by these nanocomposites, thus essentially forming two single-electrode mode triboelectric nanogenerators (TENGs). By its optimized material design and novel integration approach of the PENGs, TENGs, and electromagnetic generators (EMGs), this uniaxial tristate hybrid nanogenerator (UTHNG) can synergistically produce an instantaneous electrical power of 49 mW at low-frequency ambient vibration (5 Hz). The UTHNG has excellent charging characteristics, ramping up the output voltage of a 22 µF capacitor to 2.7 V in only 12 s, which is much faster than individual nanogenerators. This work will be a superior solution for harvesting low-frequency ambient energies by improving the performance of hybrid nanogenerators, potentially curtailing the technology gap for self-powered micro/nanosystems for the Internet of Things.

Porosity Modulated High-Performance Piezoelectric Nanogenerator Based on Organic/Inorganic Nanomaterials for Self-Powered Structural Health Monitoring.

In the modern era, structural health monitoring (SHM) is critically important and indispensable in the aerospace industry as an effective measure to enhance the safety and consistency of aircraft structures by deploying a reliable sensor network. The deployment of built-in sensor networks enables uninterrupted structural integrity monitoring of an aircraft, providing crucial information on operation condition, deformation, and potential damage to the structure. Sustainable and durable piezoelectric nanogenerators (PENGs) with good flexibility, high performance, and superior reliability are promising candidates for powering wireless sensor networks, particularly for aerospace SHM applications. This research demonstrates a self-powered wireless sensing system based on a porous polyvinylidene fluoride (PVDF)-based PENG, which is prominently anticipated for developing auto-operated sensor networks. Our reported porous PVDF film is made from a flexible piezoelectric polymer (PVDF) and inorganic zinc oxide (ZnO) nanoparticles. The fabricated porous PVDF-based PENG demonstrates ∼11 times and ∼8 times enhancement of output current and voltage, respectively, compared to a pure PVDF-based PENG. The porous PVDF-based PENG can produce a peak-to-peak short-circuit current of 22 µA, a peak-to-peak open-circuit voltage of 84.5 V, a peak output power of 0.46 mW (P=Voc2×Isc2), and a peak output power density of 41.02 µW/cm2 (P/A). By harnessing energy from minute vibrations, the fabricated porous PVDF-based PENG device (area of A = 11.33 cm2) can generate sufficient electrical energy to power up a customized wireless sensing and communication unit and transfer sensor data every ∼4 min. The PENG can generate sufficient electrical energy from an automobile car vibration, which reflects the scenario of potential real-life SHM systems. We anticipate that this high-performance porous PVDF-based PENG can act as a reliable power source for the sensor networks in aircraft, which minimizes potential safety risks.

Long-Term Stability of Ferroelectret Energy Harvesters.

Cellular polypropylene (PP) has been recently used in energy harvesting applications. In this work, we investigate its viability and long-term stability under various operating conditions. Specifically, the effect of constant stress and stress cycling on output power and long-term stability of ferroelectret energy harvesters is analyzed. Our findings show that after 112 days constant stress significantly increases the piezoelectric charge constant d 33 and output power from 0.51 µW for a stress-free harvester to 2.71 µW. It also increases the harvester center frequency from 450 to 700 Hz and decreases its optimal resistance from 7 to 5.5 M Ω .