Amplification of ammonia sensing performance through gate induced carrier modulation in Cur-rGO Silk-FET.

Uncontrolled human and industrial activities lead to the increase in demand for selective gas sensors for detection of poisonous gases in our environment. Conventional resistive gas sensors suffer from predetermined sensitivity and poor selectivity among gases. This paper demonstrates curcumin reduced graphene oxide-silk field effect transistor for selective and sensitive detection of ammonia in air. The sensing layer was characterized by X-ray diffraction, FESEM and HRTEM to confirm its structural and morphological features. Raman spectroscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy was carried out to analyze the functional moieties present in the sensing layer. Curcumin reduced graphene oxide introduces sufficient hydroxyl groups in the sensing layer to provide high degree of selectivity towards ammonia vapors. The performance of the sensor device was evaluated at positive, negative and zero gate voltage. Carrier modulation in the channel through gate electrostatics revealed that the minority carriers (electrons) in p-type reduced graphene oxide plays a pivotal role in enhancement of sensitivity of the sensor device. The sensor response was enhanced to 634% for 50 ppm ammonia at 0.6 V gate voltage compared to 23.2% and 39.3% at 0 V and - 3 V respectively. The sensor exhibited faster response and recovery at 0.6 V owing to higher mobility of electrons and quick charge transfer mechanism. The sensor exhibited satisfactory humidity resistant characteristics and high stability. Hence, curcumin reduced graphene oxide-silk field effect transistor device with proper gate bias elucidates excellent ammonia detection and may be a potential candidate for future room temperature, low power, portable gas detection system.

ZnO nanoparticles embedded silk fibroin-a piezoelectric composite for nanogenerator applications.

This paper demonstrates a flexible nanogenerator (NG) using Silk-Zinc Oxide (ZnO) composite by exploiting the inherent piezoelectric properties of silk and ZnO. A direct precipitation method was employed to synthesize Zinc Oxide nanoparticles (NPs). Silk-ZnO composite film was then prepared by spin-coating the homogenous silk-ZnO solution. The composition and morphology of silk-ZnO composite were analyzed using various standard characterization procedures. The biocompatibility study of the composite film was also performed through cell viability testing. The utility of as prepared composites was demonstrated through the fabrication of piezoelectric nanogenerator. This hybrid nanogenerator was capable to generate a maximum open circuit voltage of 25 V (peak to peak value) in the bending state for a specific ZnO concentration. The output response of the nanogenerator exhibited a good correlation with the bending angle of the device. A peak outputpower density of 6.67 mW cm-3was achieved from the nanogenerator. The fabricated prototype is efficient to light-up commercial red LEDs and to harvest energy from human body movement. The piezoelectric coefficient (d33) of silk-ZnO composite film was also experimentally figured out.