High-Performance Ternary Perovskite-Organic Solar Cells.

Perovskite solar cells in which 2D perovskites are incorporated within a 3D perovskite network exhibit improved stability with respect to purely 3D systems, but lower record power conversion efficiencies (PCEs). Here, a breakthrough is reported in achieving enhanced PCEs, increased stability, and suppressed photocurrent hysteresis by incorporating n-type, low-optical-gap conjugated organic molecules into 2D:3D mixed perovskite composites. The resulting ternary perovskite-organic composites display extended absorption in the near-infrared region, improved film morphology, enlarged crystallinity, balanced charge transport, efficient photoinduced charge transfer, and suppressed counter-ion movement. As a result, the ternary perovskite-organic solar cells exhibit PCEs over 23%, which are among the best PCEs for perovskite solar cells with p-i-n device structure. Moreover, the ternary perovskite-organic solar cells possess dramatically enhanced stability and diminished photocurrent hysteresis. All these results demonstrate that the strategy of exploiting ternary perovskite-organic composite thin films provides a facile way to realize high-performance perovskite solar cells.

Effect of Composition on the Spin Relaxation of Lead Halide Perovskites.

Lead halide perovskites have been promising candidates in spintronics applications; however, the mechanism of spin relaxation is still unclear. Here, we compare the temperature-dependent spin dynamics of four perovskite films (XPbY3) with different compositions (X = CH3NH3, Cs; Y = I, Br). The room-temperature net spin lifetime is found to increase as the molar mass decreases, indicating the dominant role of spin orbital coupling in their spin relaxation. As the temperature is reduced from room temperature to 77 K, the spin relaxations in CH3NH3PbI3 and CsPbI3 are significantly slowed down while those of CH3NH3PbBr3 and CsPbBr3 are only slightly changed. Based on the analysis of phonon scattering of perovskites, it is suggested that two different mechanisms, Elliot-Yafet in which spin flips upon momentum scattering and D'yakonov-Perel in which spin relaxes between momentum scattering, are responsible for the spin relaxation in XPbI3 and XPbBr3 (X = CH3NH3, Cs), respectively.