Gel Point Determination in Resin Transfer Molding Process with Fiber Bragg Grating Inscribed in Side-Hole Elliptical Core Optical Fiber.

Material as well as process variations in the composites industry are reasons to develop methods for in-line monitoring, which would increase reproducibility of the manufacturing process and the final composite products. Fiber Bragg Gratings (FBGs) have shown to be useful for monitoring liquid-composite molding processes, e.g., in terms of online gel point detection. Existing works however, focus on in-plane strain measurements while out-of-plane residual strain prevails. In order to measure out-of-plane strain, FBG inscribed in highly birefringent fiber (HB FBG) can be used. The purpose of this research is the cure stage detection with (a) FBG inscribed in single mode and (b) FBG inscribed in highly-birefringent side-hole fiber in comparison to the reference gel point detected with an in-mold DC sensor. Results reveal that the curing process is better traceable with HB FBG than with regular FBG. Thus, the use of HB FBG can be a good method for the gel point estimation in the RTM process.

Usage of Near-Infrared Spectroscopy for Inline Monitoring the Degree of Curing in RTM Processes.

Near-infrared spectroscopy (NIR) was implemented in the resin transfer molding (RTM) process to inline monitor the degree of curing of a bio-based epoxy resin, which consists of epoxidized linseed oil (resin) and citric acid (hardener), respectively. A NIR micro-spectrometer was used for the development of robust calibration models using partial least squares (PLS) regression. Since the micro-spectrometer offers a smaller wavelength range compared with conventional NIR devices, and typical absorbance peaks are not directly involved in the captured data range, the results show new insights for the utilization of this technology. Different pre-treatments of the spectroscopic data have been tested, starting with different reference spectra, i.e., uncured resin and polytetrafluorethylene (PTFE), and followed by chemometrical algorithms. As a reference method for the degree of curing, direct current (DC) supported by differential scanning calorimetry (DSC) was used. The results show the potential of these cost-efficient and compact NIR micro-spectrometers for the intended inline monitoring purpose to gain relevant information feedback during the process.

In-Plane Strain Measurement in Composite Structures with Fiber Bragg Grating Written in Side-Hole Elliptical Core Optical Fiber.

In this paper, the application of a fiber Bragg grating written in a highly birefringent side-hole elliptical core optical fiber for two-axial strain measurement is presented. Hybrid optical fiber structures achieved by combining large side-holes and elliptical core result in a very high birefringence of 1 × 10-3 and thus high initial Bragg peak spectral separation of 1.16 nm, as well as a very high transverse force sensitivity, of up to 650 pm/(N/mm) or even -1150 pm/(N/mm), depending on the fiber orientation with respect to the applied force. Due to the ~22 %m/m GeO2 concentration in the core the fiber being highly photosensitive, which significantly simplifies FBG fabrication by UV illumination without the need for prior hydrogen loading, which worsens thermal stability. Finally, the developed FBGs written in the highly birefringent side-hole elliptical core optical fiber were embedded in the square composite plates and applied for strain measurements. Tests of two-directional four-point bending have shown usability of such FBG for two-axial in-plane strain measurement with a single FBG in iso-thermal conditions.

Non-Destructive Thermography Analysis of Impact Damage on Large-Scale CFRP Automotive Parts.

Laminated composites are increasingly used in aeronautics and the wind energy industry, as well as in the automotive industry. In these applications, the construction and processing need to fulfill the highest requirements regarding weight and mechanical properties. Environmental issues, like fuel consumption and CO2-footprint, set new challenges in producing lightweight parts that meet the highly monitored standards for these branches. In the automotive industry, one main aspect of construction is the impact behavior of structural parts. To verify the quality of parts made from composite materials with little effort, cost and time, non-destructive test methods are increasingly used. A highly recommended non-destructive testing method is thermography analysis. In this work, a prototype for a car's base plate was produced by using vacuum infusion. For research work, testing specimens were produced with the same multi-layer build up as the prototypes. These specimens were charged with defined loads in impact tests to simulate the effect of stone chips. Afterwards, the impacted specimens were investigated with thermography analysis. The research results in that work will help to understand the possible fields of application and the usage of thermography analysis as the first quick and economic failure detection method for automotive parts.