RESUMO
In the face of a global pandemic, such as that caused by the SARS-CoV-2 virus, the prevention of new infections is essential to stop the spread and ultimately return to normality. In addition to wearing masks and maintaining safe distances, regular ventilation in enclosed spaces where several people are gathered has proven to be an effective protective measure as advised by the World Health Organization. Additionally, as has been shown in a recent study of other airborne viruses, there is a strong correlation between the CO2level and aerosol content in a confined space under the assumption humans are the only CO2source. This can be exploited by means of a low-cost infrared CO2sensor to indirectly monitor the aerosol content and to provide targeted ventilation if predefined thresholds are exceeded. The distributed CO2monitoring network presented in this paper extends that idea and provides an inexpensive, comprehensive and modular monitoring network based on readily available components and 3D printing. By using a long-range communication link (LoRa) to centrally collect the real-time CO2concentration in a multitude of rooms, this network is particularly suitable for larger building complexes such as kindergartens, schools and universities without requiring partial or even full WLAN coverage.
RESUMO
A merocyanine dye equipped with a Hamilton-receptor unit has been synthesized that enables strong noncovalent binding of other merocyanine dyes bearing barbituric acid acceptor groups by six hydrogen bonds. NMR and UV/vis titration experiments in toluene, chloroform, dichloromethane, dioxane, and THF provide evidence for the formation of 1:1 complexes even in the dipolar solvents. An enhanced binding strength is observed for the more dipolar merocyanine dyes in the head-to-tail assembly structure with binding constants up to >10 (8) M (-1) in toluene. In the present bimolecular complexes two merocyanine chromophores are assembled in a head-to-tail fashion that affords increased dipole moments as demanded for efficient electric field induced poling processes in nonlinear optical and photorefractive polymeric hosts. The solvent dependency of the binding constants for various barbituric acid dye-Hamilton receptor complexes as well as a perylene imide-melamine complex reveals linear free energy relationships (LFER) that allow for an estimation of binding constants larger than 10 (12) M (-1) for Hamilton receptor organized head-to-tail merocyanine bimolecular complexes in aliphatic solvents. It is suggested that such LFER are valuable tools for the estimation of binding constants in solvents where experimental binding constants cannot be determined because of solubility or spectroscopic problems.
