1.
Org Lett
; 1(5): 689-91, 1999 Sep 09.
Artigo
em Inglês
| MEDLINE
| ID: mdl-16118864
RESUMO
[reaction: see text] A new allylstannane reagent on non-cross-linked polystyrene was developed for the first time. This support differs markedly from standard cross-linked polymers because it is completely soluble in organic solvents; moreover, the reactions can be conveniently monitored directly by standard 1H NMR methods. The allylstannane underwent a free radical reaction with an alkyl halide to form a new allyl appendage. Tin byproducts can be easily recovered from cold methanol as white crystalline solids.