The degradation during recycling of polyamide 6 produced by anionic ring-opening polymerization of ε-caprolactam.

As the plastics industry continues to grow, the amount of plastic waste is also increasing. The European Union is controlling plastic waste through various regulations, focusing primarily on recyclability. A good alternative to traditional thermoset composites is thermoplastic polyamide 6 composites produced by Thermoplastic Resin Transfer Molding (T-RTM). Polyamide 6 has high strength and is produced by in-situ anionic ring-opening polymerization in T-RTM. Products made with this technology can replace traditional thermoset composites in many areas, which greatly increases recyclability. In this paper, the recyclability of the high molecular weight polyamide 6 matrix material of T-RTM composites is investigated. Products were mechanically recycled and then processed by injection molding. Thermal, mechanical and rheological properties of the samples were compared with the properties of the original product, as well as a general injection molding-grade PA6. Results show that the parts prepared with this innovative technology can be mechanically recycled and reprocessed by injection molding without a processing aid. After reprocessing, a significant reduction in properties is observed due to degradation, but the properties of the resulting product are in good agreement with those of a conventional commercially available injection molding grade PA6 material.

The Effect of the Parameters of T-RTM on the Properties of Polyamide 6 Prepared by in Situ Polymerization.

With the rapid development of the automotive industry, there is also a significant need to improve the raw materials used. Therefore, the demand is increasing for polymer composites with a focus on mass reduction and recyclability. Thermoplastic polymers are preferred because of their recyclability. As the automotive industry requires mass production, they require a thermoplastic raw material that can impregnate the reinforcement in a short cycle time. The most suitable monomer for this purpose is caprolactam. It can be most efficiently processed with T-RTM (thermoplastic resin transfer molding) technology, during which polyamide 6 is produced from the low-viscosity monomer by anionic ring-opening (in situ) polymerization in a tempered mold with a sufficiently short cycle time. Manufacturing parameters, such as polymerization time and mold temperature, highly influence the morphological and mechanical properties of the product. In this paper, the properties of polyamide 6 produced by T-RTM are analyzed as a function of the production parameters. We determine the crystallinity and the residual monomer content of the samples and their effect on mechanical properties.

Modeling the Thermal Conductivity Inhomogeneities of Injection-Molded Particle-Filled Composites, Caused by Segregation.

Many applications require new materials that have good thermal conductivity, are electrical insulators and can be processed easily and with relatively little energy. A new innovative solution for this problem is thermally conductive composites, which can replace metals in many cases. Many papers have focused on the prediction of their thermal conductivity. At the same time segregation has to be taken into account in the case of composites because it affects the distribution of thermally conductive particles, and thus local thermal conductivities. In this paper, we examined and modeled segregation during injection molding and its effect on thermal conductivity. We injection-molded samples from polypropylene with glass beads of different sizes and analyzed their filler content as a function of the flow path. We described the distribution of the filler with a mathematical model. Using this, we created a new, segregation-dependent model that describes the local thermal conductivity of polymer composites as a function of filler content with great accuracy.