Research on Thermal Stability and Flammability of Wood Scob-Based Loose-Fill Thermal Insulation Impregnated with Multicomponent Suspensions.

Loose-fill thermal composite insulation produced from surface-modified wood scobs has been explored as a potential fire-resistant material for building envelopes. This work involves fire resistance behavior comparisons between four coating systems consisting of liquid glass, liquid glass-tung oil, liquid glass-expandable graphite, and liquid glass-tung oil-expandable graphite. The techniques of thermogravimetric and differential thermogravimetric analyses, gross heat combustion via a calorimetric bomb, cone calorimetry, SEM imaging of char residues, and energy dispersive spectrometry for elemental analysis, as well as propensity to undergo continuous smoldering, were implemented. The coating technique resulted in greater thermal stability at a higher temperature range (500-650 °C) of the resulting loose-fill thermal composite insulation, reduced flame-damaged area heights after the exposure of samples at 45° for 15 s and 30 s, with a maximum of 49% decreased gross heat combustion, reduced heat release and total smoke release rates, improved char residue layer formation during combustion and changed smoldering behavior due to the formation of homogeneous and dense carbon layers. The results showed that the highest positive impact was obtained using the liquid glass and liquid glass-expandable graphite system because of the ability of the liquid glass to cover the wood scob particle surface and form a stable and strong expanding carbon layer.

Effect of Chemical Treatments on the Mechanical Properties of Jute/Polyester Composites.

Natural fiber composites have been extensively studied for structural applications, with recent exploration into their potential for various uses. This study investigates the impact of chemical treatments on the properties of Brazilian jute woven fabric/polyester resin composites. Sodium hydroxide, hydrogen peroxide, and peracetic acid were utilized to treat the jute fabrics, followed by resin transfer molding (RTM) to form the composites. Evaluation included water absorption, flexural strength, tensile strength, and short-beam strength. The alkaline treatment induced changes in the chemical composition of the fibers' surface. Chemical treatments resulted in increased flexural and short-beam strength of the composites, with no significant alterations in tensile properties. The hydrogen peroxide treatment exhibited lower water absorption, suggesting its potential as a viable option for enhancing the performance of these composites.

Effect of Liquid Glass-Modified Lignin Waste on the Flammability Properties of Biopolyurethane Foam Composites.

Water-blown biopolyurethane (bioPUR) foams are flammable and emit toxic gases during combustion. Herein, a novel approach suggested by the current study is to use different amounts of lignin waste (LigW), which increases the thermal stability and delays the flame spread and sodium silicate (LG), which has foaming ability at high temperatures and acts as a protective layer during a fire. However, there have been no studies carried out to investigate the synergy between these two materials. Therefore, two different ratios, namely 1/1 and 1/2 of LigW/LG, were used to prepare bioPUR foam composites. The obtained bioPUR foam composites with a 1/2 ratio of LigW/LG exhibited inhibition of flame propagation during the ignitability test by 7 s, increased thermal stability at higher temperatures by 40 °C, reduced total smoke production by 17%, reduced carbon monoxide release by 22%, and increased compressive strength by a maximum of 123% and 36% and tensile strength by a maximum of 49% and 30% at 100 °C and 200 °C, respectively, compared to bioPUR foam composites with unmodified LigW. Additionally, thanks to the sufficient compatibility between the polymeric matrix and LigW/LG particles, bioPUR foam composites were characterised by unchanged or even improved physical and mechanical properties, as well as increased glass transition temperature by 16% compared to bioPUR foam composites with unmodified LigW particles, making them suitable for application as a thermal insulating layer in building envelopes.

Performance Analysis of Loose-Fill Thermal Insulation from Wood Scobs Coated with Liquid Glass, Tung Oil, and Expandable Graphite Mixture.

The current study presents the results of monitoring the behavior of loose-fill thermal insulating material for buildings made of wood scobs (WS), which were coated with one, two, and three component-based coatings from liquid glass (LG), tung oil (TO), and expandable graphite (EG). The thermal conductivity of samples in the dry state and under normal laboratory conditions, short-term water absorption by partial immersion, surface wettability, and water vapor permeability were evaluated, and regression equations describing the variations in numerical values of specified properties under different amounts of each coating component were presented. It was shown that LG and TO act as hydrophobic layers that, in conjunction, reduce water absorption by a maximum of 274%, have a contact angle equal to 86°, and lower thermal conductivity by 55% in the dry state due to the specifics of the layer formed on the surface of WS. The addition of EG to LG coating resulted in insignificantly changed water absorption and thermal conductivity values, indicating the potential of this material to be used to improve the fire resistance of wood-based composites in the future. The results showed that the three-component layer of LG/TO/EG reduces water absorption by a maximum of 72%, increases thermal conductivity in the dry state by a minimum of 0.4%, and increases the contact angle to 81° at 100 wt.% LG. The changes in water vapor permeability of all compositions were determined to be insignificant.

Reuse of Textile Waste in the Production of Sound Absorption Boards.

Textile waste is formed in various stages, from the preparation of raw materials to the utilisation of textile products. One of the sources of textile waste is the production of woollen yarns. During the production of woollen yarns, waste is generated during the mixing, carding, roving, and spinning processes. This waste is disposed of in landfills or cogeneration plants. However, there are many examples of textile waste being recycled and new products being produced. This work deals with acoustic boards made from waste from the production of woollen yarns. This waste was generated in various yarn production processes up to the spinning stage. Due to the parameters, this waste was not suitable for further use in the production of yarns. During the work, the composition of waste from the production of woollen yarns was examined-namely, the amount of fibrous and nonfibrous materials, the composition of impurities, and the parameters of the fibres themselves. It was determined that about 74% of the waste is suitable for the production of acoustic boards. Four series of boards with different densities and different thicknesses were made with waste from the production of woollen yarns. The boards were made in a nonwoven line using carding technology to obtain semi-finished products from the individual layers of combed fibres and thermal treatment of the prepared semi-finished product. The sound absorption coefficients in the sound frequency range between 125 and 2000 Hz were determined for the manufactured boards, and the sound reduction coefficients were calculated. It was found that the acoustic characteristics of soft boards made from woollen yarn waste are very similar to those of classic boards or sound insulation products made from renewable resources. At a board density of 40 kg/m3, the value of the sound absorption coefficient varied from 0.4 to 0.9, and the noise reduction coefficient reached 0.65.

Sapropel as a Binding Material for Wood Processing Waste in the Development of Thermal Insulation Biocomposite.

When developing new innovative building materials, their performance characteristics as well as their environmental friendliness are important. It is difficult to produce a fully ecological material for building envelopes, because there is a lack of ecological binding materials on the market, good binding materials are very expensive, and cheaper ones have poorer adhesive properties and performance characteristics. In this work, natural organic sapropel was used as an ecological binder. Before use, an organic sapropel was additionally mechanically activated. Its activation efficiency was evaluated on the basis of consistency and tensile strength. Sapropel activation increased its consistency from 112 to 168 mm and its tensile strength from 466 to 958 kPa. Wood processing waste was used as a filler for the thermal insulation biocomposite. Additionally, the wood waste was chopped to regulate the density and main performance properties of the biocomposite. The density of the biocomposite was also regulated using different amounts of sapropel and the degree of compaction of the composite mixture. In this work, the influence of the amount of sapropel, the level of compression of the biocomposite mixture, and the size of the wood waste particles on the thermal conductivity and compressive stress of the biocomposite was analyzed. It was found that the compression level had the greatest influence on both the compressive stress and thermal conductivity, up to 12 times and 43.3%, respectively.

Impact of Different Ratios of Lignin Waste and Liquid Glass on the Performance Characteristics of Biopolyurethane Foams.

In the current study, biopolyurethane foam was modified with 2.5-10 wt.% lignin waste (LigW) and liquid glass (LG)-modified LigW particles at different LigW/LG ratios-1:1 and 1:2-and their impact on performance characteristics-i.e., rheology, foaming times, apparent density, thermal conductivity before and after aging, dimensional stability at ambient and elevated conditions, compressive and tensile strengths, short-term water absorption by partial immersion, and water vapor permeability-was determined and evaluated. Structural analysis was implemented and structural parameters were taken into consideration as well. During the study, it was determined that 2.5-10 wt.% particles at the LigW/LG ratio of 1:2 showed a superior impact on the physical and mechanical properties of bioPUR foams. The apparent density only insignificantly increased and was in a density range suitable for commercially available polyurethanes. For particles at 10 wt.% and LigW/LG ratio of 1:1, the thermal conductivity value improved by 3.2%, the compressive strength increased by 153%, while the tensile strength improved by 23.5%, indicating sufficient interfacial adhesion between the filler and polymer matrix. Moreover, the short-term water absorption by partial immersion remained almost unchanged, while the water vapour diffusion resistance factor improved from 43 to 48. Additionally, the incorporation of LigW/LG 1:1 and LigW/LG 1:2 particles made it possible to obtain dimensionally and structurally stable closed-cell bioPUR foams for possible application as thermal insulation in building envelopes.

Analysis of Active and Passive Deformation of Expanded Polystyrene Foam under Short-Term Compression.

In this paper, we undertake a detailed analysis of the active and passive deformation of expanded polystyrene (EPS), which is used as a thermal insulating layer in building partitions, under short-term compressive loading. The values of residual strain in 10-40 kg/m3 density EPS after monotonically increasing loading under active deformations of 20%, 30%, 40%, 50%, and 60% with the following complete removal are determined. These values are a physical sign of the elastic-plastic state of EPS. It has been shown that the final destruction of cells takes place in EPS when the active strain reaches 50%. Empirical equations are proposed to estimate the residual strain of EPS based on density with determination coefficients varying from 0.744 to 0.986 at a confidence level of 90%. Moreover, graphical interpretations with regression equations for residual strain dependence on density and compressive strength, as well as density and active strain, were proposed with determination coefficients equal to 0.779 and 0.717, respectively.

Impact of Sunflower Press Cake and Its Modification with Liquid Glass on Polyurethane Foam Composites: Thermal Stability, Ignitability, and Fire Resistance.

Polyurethane (PUR) foams are some of the most promising thermal insulating materials because of their high flammability, but further applications are limited. Therefore, the development of flame-retardant materials with sufficient strength characteristics, water resistance, and low thermal insulating properties is of great importance to the modern building industry. This study evaluates the possibility of a vacuum-based liquid glass (LG) infusion into bio-based fillers, in this case, sunflower press cake (SFP) particles, to improve the mechanical performance, water absorption, thermal insulation, ignitability, thermal stability, and flame retardancy of the resulting polyurethane (PUR) foam composites. The main findings show that LG slightly improves the thermal stability and highly contributes to the ignitability and flame retardancy of the resulting products. Most importantly, from 10 wt.% to 30 wt.%, the SFP/LG filler reduces the thermal conductivity and water absorption values by up to 20% and 50%, respectively, and increases the compressive strength by up to 110%. The results obtained indicate that the proposed SFP/LG filler-modified PUR foam composites are suitable for applications as thermal insulation materials in building structures.