Microplastics in Asian rivers: Geographical distribution, most detected types, and inconsistency in methodologies.

Microplastics pose a significant environmental threat, with potential implications for toxic chemical release, aquatic life endangerment, and human food chain contamination. In Asia, rapid economic growth coupled with inadequate waste management has escalated plastic pollution in rivers, positioning them as focal points for environmental concern. Despite Asia's rivers being considered the most polluted with plastics globally, scholarly attention to microplastics in the region's freshwater environments is a recent development. This study undertakes a systematic review of 228 scholarly articles to map microplastic hotspots in Asian freshwater systems and synthesize current research trends within the continent. Findings reveal a concentration of research in China and Japan, primarily investigating riverine and surface waters through net-based sampling methods. Polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET) emerge as the predominant microplastic types, frequently observed as fibers or fragments. However, the diversity of sampling methodologies and reporting metrics complicates data synthesis, underscoring the need for standardized analytical frameworks to facilitate comparative analysis. This paper delineates the distribution of microplastic hotspots and outlines the prevailing challenges and prospects in microplastic research within Asian freshwater contexts.

Suspended Particulate Matter Analysis of Pre and During Covid Lockdown Using Google Earth Engine Cloud Computing: A Case Study of Ukai Reservoir.

Presence of suspended particulate matter (SPM) in a waterbody or a river can be caused by multiple parameters such as other pollutants by the discharge of poorly maintained sewage, siltation, sedimentation, flood and even bacteria. In this study, remote sensing techniques were used to understand the effects of pandemic-induced lockdown on the SPM concentration in the lower Tapi reservoir or Ukai reservoir. The estimation was done using Landsat-8 OLI (Operational Land Imager) having radiometric resolution (12-bit) and a spatial resolution of 30 m. The Google Earth Engine (GEE) cloud computing platform was used in this study to generate the products. The GEE is a semi-automated workflow system using a robust approach designed for scientific analysis and visualization of geospatial datasets. An algorithm was deployed, and a time-series (2013-2020) analysis was done for the study area. It was found that the average mean value of SPM in Tapi River during 2020 is lowest than the last seven years at the same time.

Appraising the performance of oil palm fibre biochar for low concentration ammoniacal nitrogen recovery from aquaculture wastewater.

Oil palm fibre is a type of solid waste generated from palm oil processing plant. At present, there is no proper utilization of this abundant waste. Ammoniacal nitrogen (NH3-N) has received a lot of attention as a water pollutant due to its toxicity, which has an impact on both the environment and human health. In aquaculture wastewater (AQW), NH3-N is present in low concentrations (<10 ppm), and removing low concentrations of NH3-N is tedious. Thus, this study focuses on the potential of oil palm fibre biochar (OPFB) for sustainable low concentration NH3-N recovery from AQW and the recovered spent adsorbent to be used as a bio-fertilizer. The Physico-chemical properties of OPFB show a positive correlation with NH3-N recovery. A significant reduction of value-added metals in OPFB has confirmed the recovery of NH3-N through the ion exchange process. The adsorption isotherms and kinetics of NH3-N recovery had good correlation coefficients under the Freundlich and pseudo-second-order kinetic model confirming a multilayer heterogeneous and chemical adsorption respectively. Thermodynamic parameters indicated that the recovery process via adsorption was exothermic and had a Physio-chemical mechanism. At optimum conditions, OPFB could recover up to 66% of NH3-N actual AQW. The properties of spent OPFB showed potential reutilization as a soil amendment agent or biofertilizer which could be easily degraded.

Evaluation of oil palm fiber biochar and activated biochar for sulphur dioxide adsorption.

The emission of sulphur dioxide (SO2) gas from power plants and factories to the atmosphere has been an environmental challenge globally. Thus, there is a great interest to control the SO2 gas emission economically and effectively. This study aims to use and convert abundantly available oil palm fiber (OPF) biomass into an adsorbent to adsorb SO2 gas. The preparation of OPF biochar and activated biochar was optimised using the Response Surface Methodology (RSM) based on selected parameters (i.e., pyrolysis temperature, heating rate, holding time, activation temperature, activation time and CO2 flowrate). The best adsorbent was found to be the OPF activated biochar (OPFAB) compared to OPF biochar. OPFAB prepared at 753 °C for 73 min of activation time with 497 ml/min of CO2 flow yields the best adsorption capacity (33.09 mg/g) of SO2. Meanwhile, OPF pyrolysed at 450 °C of heating temperature, 12 °C/min of heating rate and 98 min of holding time yield adsorption capacity at 18.62 mg/g. Various characterisations were performed to investigate the properties and mechanism of the SO2 adsorption process. Thermal regeneration shows the possibilities for the spent adsorbent to be recycled. The findings imply OPFAB as a promising adsorbent for SO2 adsorption.

Ancillary palm oil fuel ash (POFA) in sequencing batch reactor for enhancing recalcitrant pollutants removal from domestic wastewater.

Domestic wastewater has been generated massively along with rapid growth of population and economic. Biological treatment using sequencing batch reactor (SBR) augmented with palm oil fuel ash (POFA) was investigated for the first time. The performance of POFA in enhancing biological treatment of wastewater has not been tested. The porosity property of POFA can improve SBR efficiency by promoting growth of mixed liquor suspended solids (MLSS) and formation of larger flocs for settling and facilitating attachment of microorganisms and pollutants onto POFA surfaces. The properties of POFA were tested to identify morphological properties, particle size, surface area, chemical compositions. Four SBRs, namely SBR1, SBR2, SBR3 and SBR4 were provided with aeration rate of 1, 2, 3 and 4 L/min, respectively. Each reactor was augmented with different dosages of POFA. Optimum aeration rate and POFA concentration were identified by the performance of SBRs in removing chemical oxygen demand (COD), ammoniacal nitrogen (NH3-N) and colour from domestic wastewater. The results showed the most efficient COD (97.8%), NH3-N (99.4%) and colour (98.8%) removals were achieved at optimum POFA concentration of 4 g/L in SBR and aeration rate of 1 L/min. The study also found that higher aeration rate would contribute to the smaller specific size of flocs and decrease the pollutant removal efficiency.

Selectivity of SO2 and H2S removal by ethanol-treated calcined eggshell at low temperature.

Eggshell is a food waste produced worldwide in substantial amount with very limited recycling activity. In this study, the potential of ethanol-treated calcined eggshell was tested as sorbent for SO2 and H2S. Three variables were selected in the preparation of sorbents via response surface methodology (RSM), i.e., concentration of ethanol in water (50%, 70%, 90%), reaction temperature (20 °C, 40 °C, 60 °C), and contact time (30, 60, 90 min). Central composite design (CCD) was used to develop a quadratic model to correlate the operating variables with the adsorption capacity. Analysis of variance (ANOVA) was performed to identify the significant factors of the experimental design. It was found that the reaction temperature during the sorbent preparation was the most significant factor. The optimum preparation conditions using RSM were found at 20 °C of reaction temperature with 76.37% of ethanol concentration for 67 min of reaction time. The maximum adsorption capacity for the optimized sorbent was found to be 27.75 mg/g and 9.55 mg/g for SO2 and H2S, respectively. The prepared sorbent was more selective towards SO2 compared with H2S. Moreover, the presence of 40% of relative humidity in the inlet gas further enhanced the adsorption capacity of both gases. The ethanol-treated calcined eggshell was further substantiated by FESEM, BET, FTIR, XRD, and XRF. Results showed potential usage of eggshell as a sorbent for SO2 and H2S gases.

Bimetallic Metal-Organic Framework-Derived Hybrid Nanostructures as High-Performance Catalysts for Methane Dry Reforming.

Syngas, consisting of equimolar CO and H2, is an important feedstock for large-scale production of a wide range of commodity chemicals including aldehyde, methanol, ammonia, and other oxygenated chemicals. Dry reforming of methane (DRM), proceeding by reacting greenhouse gases, CO2 and CH4, at high temperatures in the presence of a metal catalyst, is considered one of the most environmentally friendly routes for syngas production. Nevertheless, nonprecious metal-based catalysts, which can operate at relatively low temperatures for high product yields and selectivities, are required to drive the DRM process for industrial applications effectively. Here, we developed NiCo@C nanocomposites from a corresponding NiCo-based bimetallic metal-organic framework (MOF) to serve as high-performance catalysts for the DRM process, achieving high turnover frequencies (TOF) at low temperatures (>5.7 s-1 at 600 °C) and high product selectivities (H2/CO = 0.9 at 700 °C). The incorporation of Co in Ni catalysts improves the operation stability and light-off stability. The present development for MOF-derived nanocomposites opens a new horizon for design of DRM catalysts.

Optimization of activated palm oil sludge biochar preparation for sulphur dioxide adsorption.

Palm oil sludge (POS) is an organic waste generated from the palm oil industry. POS causes environmental pollution if it is improperly disposed. In this study, the potential of activated POS biochar, as an adsorbent for the removal of SO2 gas was tested. POS biochar was physically activated using CO2 gas. The effects of activation preparation variables i.e. activation temperature (300-700 °C), activation time (30-150 min) and CO2 flow rate (100-500 ml/min) were investigated using design expert version 8.0.7.1 software. Central Composite Design (CCD) was used to develop a quadratic model to correlate the operating variables with the activated biochar adsorption capacity. Analysis of variance (ANOVA) was performed to identify the significant factors on the experimental design response. The optimum preparation conditions of activated POS biochar were found to be at activation temperature of 442 °C, activation time of 63 min and CO2 flow rate of 397 ml/min. The maximum adsorption capacity at the optimum conditions was recorded as 16.65 mg/g. The adsorption capacity increased significantly after the activation process. Characteristics of the activated POS biochar proposed that SO2 was physically adsorbed. Furthermore, it was found that the adsorption capacity can be further enhanced by increasing the reaction temperature to 100 °C or with 15% of relative humidity in the inlet gas. The prepared adsorbents can be regenerated by thermal treatment.

Adsorptive behaviour of palm oil mill sludge biochar pyrolyzed at low temperature for copper and cadmium removal.

In this work, the influence of pyrolysis temperature on the physicochemical properties of palm oil mill sludge biochar (POSB) and its adsorption properties towards cadmium (Cd) and copper (Cu) was investigated. Characterization experiments suggested that POSBs' surface functional groups play the major role in the adsorption process. POSB pyrolyzed at 400 °C showed the best characteristics for Cu and Cd removal. Adsorption study indicated that contact time and shaking speed enhances the adsorption capacity of POSB. It was affirmed that pH adjustment is not necessary for POSB to adsorb Cu and Cd. Mechanism studies fitted well with Langmuir and Pseudo-Second Order model. Thermodynamic parameters indicated that the adsorption was spontaneous, endothermic and correspond to chemical adsorption. The highest uptakes of Cu and Cd were recorded at 48.8 mg/g and 46.2 mg/g respectively. This work verifies that the temperature used for palm oil mill sludge (POS) pyrolysis and adsorption condition played the most prominent role in Cu and Cd removal from aqueous solutions.

Optimization of palm oil mill sludge biochar preparation for sulfur dioxide removal.

In this study, palm oil mill sludge was used as a precursor to prepare biochar using conventional pyrolysis. Palm oil mill sludge biochar (POSB) was prepared at different preparation variables, i.e., heating temperature (300-800 °C), heating rate (10-20 °C/min) and holding time (60-120 min). The prepared biochars were tested for sulfur dioxide (SO2) adsorption in a fixed bed reactor using 300 ppm of SO2 gas at 300 ml/min (with N2 gas as balance). Response surface central composite experimental design was used to optimize the production of biochar versus SO2 removal. A quadratic model was developed in order to correlate the effect of variable parameters on the optimum adsorption capacity of SO2 gas. The experimental values and the predicted results of the model were found to show satisfactory agreement. The optimum conditions for biochar preparation to yield the best SO2 removal was found to be at 405 °C of heating temperature, 20 °C/min of heating rate and 88 min of holding time. At these conditions, the average yield of biochar and adsorption capacity for SO2 gas was reported as 54.25 g and 9.75 mg/g, respectively. The structure of biochar and their roles in SO2 adsorption were investigated by surface area, morphology images, infrared spectra, and proximate analysis, respectively. The characterization findings suggested that POSB adsorbs SO2 mainly by the functional groups.

A sequential treatment of intermediate tropical landfill leachate using a sequencing batch reactor (SBR) and coagulation.

The increase in landfill leachate generation is due to the increase of municipal solid waste (MSW) as global development continues. Landfill leachate has constantly been the most challenging issue in MSW management as it contains high amount of organic and inorganic compounds that might cause pollution to water resources. Biologically treated landfill leachate often fails to fulfill the regulatory discharge standards. Thus, to prevent environmental pollution, many landfill leachate treatment plants involve multiple stages treatment process. The Papan Landfill in Perak, Malaysia currently has no proper leachate treatment system. In the current study, sequential treatment via sequencing batch reactor (SBR) followed by coagulation was used to treat chemical oxygen demand (COD), ammoniacal nitrogen (NH3-N), total suspended solids (TSS), and colour from raw landfill leachate. SBR optimum aeration rate, L/min, optimal pH and dosage (g/L) of Alum for coagulation as a post-treatment were determined. The two-step sequential treatment by SBR followed by coagulation (Alum) achieved a removal efficiency of 84.89%, 94.25%, 91.82% and 85.81% for COD, NH3-N, TSS and colour, respectively. Moreover, the two-stage treatment process achieved 95.0% 95.0%, 95.3%, 100.0%, 87.2%, 62.9%, 50.0%, 41.3%, 41.2, 34.8, and 22.9 removals of Cadmium, Lead, Copper, Selenium, Barium, Iron, Silver, Nickel, Zinc, Arsenic, and Manganese, respectively.

Biomass-based palm shell activated carbon and palm shell carbon molecular sieve as gas separation adsorbents.

Lignocellulosic biomass has been widely recognised as a potential low-cost source for the production of high added value materials and proved to be a good precursor for the production of activated carbons. One of such valuable biomasses used for the production of activated carbons is palm shell. Palm shell (endocarp) is an abundant by-product produced from the palm oil industries throughout tropical countries. Palm shell activated carbon and palm shell carbon molecular sieve has been widely applied in various environmental pollution control technologies, mainly owing to its high adsorption performance, well-developed porosity and low cost, leading to potential applications in gas-phase separation using adsorption processes. This mini-review represents a comprehensive overview of the palm shell activated carbon and palm shell carbon molecular sieve preparation method, physicochemical properties and feasibility of palm shell activated carbon and palm shell carbon molecular sieve in gas separation processes. Some of the limitations are outlined and suggestions for future improvements are pointed out.

Optimization of coagulation-flocculation treatment on paper-recycling wastewater: Application of response surface methodology.

The application of coagulation-flocculation (CF) process for treating the paper-recycling wastewater in jar-test experiment was employed. The purpose of the study was aimed to examine the efficiency of alum and poly aluminum chloride (PACl) in combination with a cationic polyacrylamide (C-PAM) in removal of chemical oxygen demand (COD) and turbidity from paper-recycling wastewater. Optimization of CF process were performed by varying independent parameters (coagulants dosage, flocculants dosage, initial COD and pH) using a central composite design (CCD) under response surface methodology (RSM). Maximum set required 4.5 as pH, 40 mg/L coagulants dosage and 4.5 mg/L flocculants dosage at which gave 92% reduction of turbidity, 97% of COD removal and SVI 80 mL/g. The best coagulant and flocculants were alum and chemfloc 3876 at dose of 41 and 7.52 mg/L, respectively, correspondingly at pH of 6.85. These conditions gave 91.30% COD and 95.82% turbidity removals and 12 mL/g SVI.