1.
Chem Commun (Camb)
; 50(76): 11129-31, 2014 Oct 04.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25105178
RESUMO
Thiol-yne click chemistry is used to covalently link a ferrocenyl derivative to the pore walls of a fully organic porous polymer coating (SURGEL). By cyclic voltammetry, it is demonstrated that the ferrocene bound to the SURGEL via a flexible alkyl linker can be reversibly reduced and oxidised. Surprisingly, when adding ferrocene as an electrolyte, a Nernstian diffusion limited process is observed. We explain this observation in terms of a high permeability of the SURGELs for ferrocene after the post synthetic modification.