A novel nanocomposite for photocatalytic rhodamine B dye removal from wastewater using visible light.

Providing safe access to water and addressing the impact of waterborne diseases, which claim over two million lives annually, is a major contribution to water purification. The study introduces a novel nanocomposite, Ch/Fe3O4/α-MoO3, which exhibits outstanding photocatalytic efficacy under visible light. An in-depth investigation of the nanocomposite's synthesis, characterization, and photodegradation mechanisms reveals its outstanding capabilities. Photocatalytic activity is influenced by the catalytic dose, pH, dye concentration, and reaction time, according to the study. A response surface method is used to determine the optimal conditions for Rhodamine B degradation, which results in 96.3% removal efficiency at pH 8.5, dye concentration 25 mg/L, nanocomposite dose at 22 mg/L, and reaction time 50 min. As a result of its high surface area, biocompatibility, availability, and magnetization with iron compounds, Chitosan is an excellent substrate for enhancing the photocatalytic properties of MoO3 nanoparticles. A nanocomposite with an energy band of 3.18 eV exhibits improved visible light absorption. This study confirms the nanocomposite's recyclability and stability, affirming its practicality. Besides dye removal, it offers hope for the global quest for clean water sources by addressing a broader range of waterborne contaminants. By combining molybdenum and magnetite, nanocomposite materials facilitate the degradation of pollutant and bacteria, contributing positively to society's quest for clean and safe water. It emphasizes the role nanotechnology plays in preserving human health and well-being in combating waterborne diseases.

The role of alkane chain in primary amine capped CdSe and CdS quantum dots from first-principles.

In this study, we performab initiocalculations, using density functional theory, to provide more insights about the role of alkane chain in primary amine capped (CdSe)33and (CdS)33quantum dots (QDs). We passivate the QDs surfaces with seven primary amines of different carbon chain lengths starting from NH3to hexylamine. The primary amine ligands induce a blue shift in the band gap of the ligated QDs, in agreement with experimental studies, but the alkane chain itself show negligible changes in the band gap. By increasing the chain length the binding energy between ligands and the QDs increases but its rate decreases due to the increase of steric hindrance between the ligands. The role of van der Waals forces in such behavior is found to be notable which is done by performing geometry optimization through adding and neglecting the dispersion correction effects for each system. The results of this study can provide helpful information for ligand selectivity in controlling the size and properties of the QDs using primary amines.

Application of oxidation-reduction potential (ORP) as a controlling parameter during the synthesis of Fe3O4@PVA nanocomposites from industrial waste (raffinate).

The objective of this study was to develop a process for the synthesis of magnetite nanocomposites from raffinate of hydrometallurgical plants containing iron ions. Towards this goal, a three-step process was developed. After the reduction of Fe(III) to Fe(II) in the first stage, Al3+ in the raffinate was precipitated as Al(OH)3 and finally magnetite NPs were synthesized by chemical co-precipitation method via controlling the oxidation-reduction potentials (ORPs). The produced nanomaterials were analyzed using XRD, TEM, VSM, TGA, and FTIR. The TG, XPS, and FTIR results affirmed the existence of PVA while TEM images illustrated the spherical nanoparticles with an average size of about 19 ± 4 nm. Evaluation of VSM data indicated the highly ferromagnetic behavior for Fe3O4 and Fe3O4@PVA products at the room temperature with a saturation magnetization of 46.98 and 35.78 emu/g, respectively.