RESUMO
Driven by the necessity to achieve a thorough comprehension of the bottom-up fabrication process of functional materials, this experimental study investigates the pairwise interactions or collisions between chemically active SiO2-Pt Janus colloids. These collisions are categorized based on the Janus colloids' orientations before and after they make physical contact. In addition to the hydrodynamic interactions, the Janus colloids are also known to affect each other's chemical field, resulting in chemophoretic interactions, which depend on the degree of surface anisotropy in reactivity of Janus colloid and the solute-surface interaction at play. Our study reveals that these interactions lead to a noticeable decrease in particle speed and changes in orientation that correlate with the contact duration and yield different collision types. Distinct configurations of contact during collisions were found, whose mechanisms and likelihood are found to be dependent primarily on the chemical interactions. Such estimates of collision and their characterization in dilute suspensions shall have a key impact in determining the arrangement and time scales of dynamical structures and assemblies of denser suspensions and potentially the functional materials of the future.
RESUMO
Self-propelled Janus colloids (JCs) have recently gained much attention due to their ability to move autonomously and mimic biological microswimmers. This ability makes them suitable for prospective drug/cargo-delivery applications in microscopic domains. Understanding their dynamics in surroundings doped with macromolecules such as polymers is crucial, as most of the target application media are complex in nature. In this study, we investigate the self-diffusiophoretic motion of hydrogen peroxide-fuelled SiO2-Pt JCs in the presence of dilute amounts of poly(ethylene oxide) (PEO). Despite the addition of PEO chains producing a Newtonian behavior with negligible increase in viscosity, the ballistic movement and rotational fluctuations of active JCs are observed to be significantly suppressed. With an increase in the polymer concentration, this leads to a transition from smooth to jittery to cage-hopping to the arrested motion of active JCs. We further propose that the anisotropic interaction of the polymers with the JC increases the "local drag" of the medium, resulting in the unusual impediment of the active motion.
