1.
Chem Commun (Camb)
; 60(17): 2389-2392, 2024 Feb 22.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38321973
RESUMO
A bowl-shaped phosphangulene-protected cubic Cu58 nanocluster has been synthesized. The structure was determined by X-ray crystallography and further analyzed by multiple techniques. The phosphangulenes not only enable ligand substitutions with triphenylphosphines in a cluster-to-cluster transformation way, but also facilitate inter-cluster interactions with fullerenes. These interactions further influence the entirety's photocurrent response and ability to liberate hydrogen when stimulated by light.