Regioselective SmI2-Mediated Radical ipso-Substitution Cyclization for the Construction of Pyrrolophenanthridinone Skeletons: The Synthesis of Amaryllidaceae Alkaloids.

Here, we report a regioselective, samarium(II) diiodide mediated intramolecular radical ipso-substitution cyclization. Through the use of a methoxy group as a leaving group, it was possible to regulate the regioselectivity of the reaction by changing the temperature and additives. We applied the developed reaction to the synthesis of four Amaryllidaceae alkaloids and have shown that the present reaction successfully overcomes regioselectivity issues encountered with other cyclization methods.

Effects of the 2011 Tohoku earthquake and tsunami on the abundance and composition of anthropogenic marine debris on the continental slope off the Pacific coast of northeastern Japan.

The abundance and composition of anthropogenic marine debris from 2012 to 2014 was assessed according to three bottom trawl surveys conducted on the upper continental slope between 198 m and 501 m off the Pacific coast of northeastern Japan. The surveys quantitated marine debris as follows: 33.52-164.62 items km-2 (January to July 2012), 91.68-215.11 items km-2 (November 2012 to May 2013), and 160.13-178.19 items km-2 (November 2013 to May 2014). Plastic bags or household materials mainly dominated terrestrial sources of debris. Principal component analysis latitudinally divided the study area according to debris abundance caused by geographical and hydrodynamic features. The long-term effect of tsunami-associated debris on the seafloor environment was recognized, because terrestrial sources such as heavy household materials were most abundant throughout the study period, with the additional accumulation of fishing gear and plastic bags.

Meteoronakishinouyei, a new family, genus and species (Cnidaria, Cubozoa, Chirodropida) from Japanese Waters.

A new family, genus and species of cubozoan box jellyfish belonging to the order Chirodropida is reported from the eastern Japan. Meteoronakishinouyei gen. et sp. n. possesses the following unique morphological characters with respect to other known species in the Chirodropida: having one tentacle per scalpel-like unbranched pedalium and slightly raised unbranched gastric saccules. A comparative table of the primary diagnostic characters of genus and order in the Chirodropida is given. The order Chirodropida is redefined. The family Chiropsellidae is established. Discussion is provided on the implications for these findings on our current understanding of Cubozoan systematics.

Changes in abundance and composition of anthropogenic marine debris on the continental slope off the Pacific coast of northern Japan, after the March 2011 Tohoku earthquake.

Abundance and composition of anthropogenic marine debris were assessed on the basis of six bottom trawl surveys conducted on the continental slope off Iwate Prefecture, Pacific coast of northern Japan, in 2003, 2004 and 2011, and the temporal changes due to the Tohoku earthquake and tsunami in March 2011 evaluated. In 2003 and 2004, 54-94 items km(-2) of marine debris, dominated by sea-base sourced items mainly comprising fishing gear and related items from adjacent fishing grounds on the continental shelf, were quantified. In the post-earthquake period, the density increased drastically to 233-332 items km(-2), due to an increase in land-base sourced items generated by the tsunami. However, a major increase in abundance after the disaster, compared to the total amount of tsunami debris swept into the sea, was not found. Additional sources of land-based debris from the adjacent continental shelf are suggested in the present waters.