Impact of nutrient deficiency on biological sewage treatment - Perspectives towards urine source segregation.

Human urine contains 9 g/L of nitrogen (N) and 0.7 g/L of phosphorus (P). The recovery of N and P from urine helps close the nutrient loop and increase resource circularity in the sewage treatment sector. Urine contributes an average of 80 % N and 50 % P in sewage, whereby urine source segregation could reduce the burden of nutrient removal in sewage treatment plants (STPs) but result in N and P deficiency and unintended negative consequences. This review examines the potential impacts of N and P deficiency on the removal of organic carbon and nutrients, sludge characteristics and greenhouse gas emissions in activated sludge processes. The details of how these impacts affect the operation of STPs were also included. This review helps foresee operational challenges that established STPs may face when dealing with nutrient-deficient sewage in a future where source separation of urine is the norm. The findings indicate that the requirement of nitrification-denitrification and biological P removal processes could shrink at urine segregation above 80 % and 100 %, respectively. Organic carbon, N and biological P removal processes can be severely affected under full urine segregation. The decrease in solid retention time due to urine segregation increases treatment capacity up to 48 %. Sludge flocculation and settleability would deteriorate due to changes in extracellular polymeric substances and induce various forms of bulking. Beneficially, N deficiency reduces nitrous oxide emissions. These findings emphasise the importance of considering and preparing for impacts caused by urine source segregation-induced nutrient deficiency in sewage treatment processes.

Recent Advances in High-Rate Solar-Driven Interfacial Evaporation.

Recent advances in solar-driven interfacial evaporation (SDIE) have led to high evaporation rates that open promising avenues for practical utilization in freshwater production and industrial application for pollutant and nutrient concentration, and resource recovery. Breakthroughs in overcoming the theoretical limitation of 2D interfacial evaporation have allowed for developing systems with high evaporation rates. This study presents a comprehensive review of various evaporator designs that have achieved pure evaporation rates beyond 4 kg m-2 h-1, including structural and material designs allowing for rapid evaporation, passive 3D designs, and systems coupled with alternative energy sources of wind and joule heating. The operational mechanisms for each design are outlined together with discussion on the current benefits and areas for improvement. The overarching challenges encountered by SDIE concerning the feasibility of direct integration into contemporary practical settings are assessed, and issues relating to sustaining elevated evaporation rates under diverse environmental conditions are addressed.

Perfluorooctanoic acid-contaminated wastewater treatment by forward osmosis: Performance analysis.

Perfluorooctanoic acid (PFOA) is a persistent compound, raising considerable global apprehension due to its resistance to breakdown and detrimental impacts on human health and aquatic environments. Pressure-driven membrane technologies treating PFAS-contaminated water are expensive and prone to fouling. This study presented a parametric investigation of the effectiveness of cellulose triacetate membrane in the forward osmosis (FO) membrane for removing PFOA from an aqueous solution. The study examined the influence of membrane orientation modes, feed pH, draw solution composition and concentration, and PFOA concentration on the performance of FO. The experimental results demonstrated that PFOA rejection was 99 % with MgCl2 and slightly >98 % with NaCl draw solutions due to the mechanism of PFOA binding to the membrane surface through Mg2+ ions. This finding highlights the crucial role of the draw solution's composition in PFOA treatment. Laboratory results revealed that membrane rejection of PFOA was 99 % at neutral and acidic pH levels but decreased to 95 % in an alkaline solution at pH 9. The decrease in membrane rejection is attributed to the dissociation of the membrane's functional groups, consequently causing pore swelling. The results were confirmed by calculating the average pore radius of the CTA membrane, which increased from 27.94 nm at pH 5 to 30.70 nm at pH 9. Also, variations in the PFOA concentration from 5 to 100 mg/L did not significantly impact the membrane rejection, indicating the process's capability to handle a wide range of PFOA concentrations. When seawater was the draw solution, the FO membrane rejected 99 % of PFOA concentrations ranging from 5 mg/L to 100 mg/L. The CTA FO treating PFOA-contaminated wastewater from soil remediation achieved a 90 % recovery rate and water flux recovery of 96.5 % after cleaning with DI water at 40 °C, followed by osmotic backwash. The results suggest the potential of using abundant and cost-effective natural solutions in the FO process, all without evident membrane fouling.

Ion-imprinted membranes for lithium recovery: A review.

This review critically examines the effectiveness of ion-imprinted membranes (IIMs) in selectively recovering lithium (Li) from challenging sources such as seawater and brine. These membranes feature customized binding sites that specifically target Li ions, enabling selective separation from other ions, thanks to cavities shaped with crown ether or calixarene for improved selectivity. The review thoroughly investigates the application of IIMs in Li extraction, covering extensive sections on 12-crown-4 ether (a fundamental crown ether for Li), its modifications, calixarenes, and other materials for creating imprinting sites. It evaluates these systems against several criteria, including the source solution's complexity, Li+ concentration, operational pH, selectivity, and membrane's ability for regeneration and repeated use. This evaluation places IIMs as a leading-edge technology for Li extraction, surpassing traditional methods like ion-sieves, particularly in high Mg2+/Li+ ratio brines. It also highlights the developmental challenges of IIMs, focusing on optimizing adsorption, maintaining selectivity across varied ionic solutions, and enhancing permselectivity. The review reveals that while the bulk of research is still exploratory, only a limited portion has progressed to detailed lab verification, indicating that the application of IIMs in Li+ recovery is still at an embryonic stage, with no instances of pilot-scale trials reported. This thorough review elucidates the potential of IIMs in Li recovery, cataloging advancements, pinpointing challenges, and suggesting directions for forthcoming research endeavors. This informative synthesis serves as a valuable resource for both the scientific community and industry professionals navigating this evolving field.

Machine learning for layer-by-layer nanofiltration membrane performance prediction and polymer candidate exploration.

In this study, machine learning-based models were established for layer-by-layer (LBL) nanofiltration (NF) membrane performance prediction and polymer candidate exploration. Four different models, i.e., linear, random forest (RF), boosted tree (BT), and eXtreme Gradient Boosting (XGBoost), were formed, and membrane performance prediction was determined in terms of membrane permeability and selectivity. The XGBoost exhibited optimal prediction accuracy for membrane permeability (coefficient of determination (R2): 0.99) and membrane selectivity (R2: 0.80). The Shapley Additive exPlanation (SHAP) method was utilized to evaluate the effects of different LBL NF membrane fabrication conditions on membrane performances. The SHAP method was also used to identify the relationships between polymer structure and membrane performance. Polymers were represented by Morgan fingerprint, which is an effective description approach for developing modeling. Based on the SHAP value results, two reference Morgan fingerprints were constructed containing atomic groups with positive contributions to membrane permeability and selectivity. According to the reference Morgan fingerprint, 204 potential polymers were explored from the largest polymer database (PoLyInfo). By calculating the similarities between each potential polymer and both reference Morgan fingerprints, 23 polymer candidates were selected and could be further used for LBL NF membrane fabrication with the potential for providing good membrane performance. Overall, this work provided new ways both for LBL NF membrane performance prediction and high-performance polymer candidate exploration. The source code for the models and algorithms used in this study is publicly available to facilitate replication and further research. https://github.com/wangliwfsd/LLNMPP/.

Persistent free radicals on biochar for its catalytic capability: A review.

Biochar is an economical carbon material for water pollution control, which shows great promise to be applied in the up-scale wastewater remediation processes. Previous studies demonstrate that persistent free radicals (PFRs) on biochar are critical to its reactivity for wastewater remediation. A series of studies have revealed the important roles of PFRs when biochar was applied for organic pollutants degradation as well as the removal of Cr (VI) and As (III) from wastewater. Therefore, this review comprehensively concludes the significance of PFRs for the catalytic capabilities of biochar in advanced oxidation processes (AOPs)-driven organic pollutant removal, and applied in redox processes for Cr (VI) and As (III) remediation. In addition, the mechanisms for PFRs formation during biochar synthesis are discussed. The detection methods are reviewed for the quantification of PFRs on biochar. Future research directions were also proposed on underpinning the knowledge base to forward the applications of biochar in practical real wastewater treatment.

Electrically conductive membrane distillation via an alternating current operation for zero liquid discharge.

Membrane distillation (MD) shows promise for achieving high salinity treatment and zero liquid discharge (ZLD) compared to conventional water treatment processes due to its unique characteristics, including low energy consumption and high resulting water quality. However, performance degradation due to fouling and scaling under high recovery conditions remains a challenge, particularly considering the need to control both cations and anions for maximum scaling mitigation. Accordingly, in this study, alternating current (AC) operation for electrically conductive membrane distillation (ECMD) is newly proposed, based on its potential for controlling both cations and anions, in contrast to conventional direct current (DC) operation. Systematic experiments and theoretical analysis show that water recovery in ECMD can be increased by 27% through AC operation. The proposed modification and effective AC operation of ECMD increase the practicality of using MD in desalination for a high recovery rate, perhaps even for ZLD.

Recent Progress on Passive, Thermally Localized Solar-Driven Multistage Water Evaporation.

Thermally localized solar-driven water evaporation (SWE) in recent years has increasingly been developed due to the potential of cost-efficient freshwater production from small-scale portable devices. In particular, the multistage SWE has attracted much attention as the systems possess mostly a simple foundational structure and high solar-to-thermal conversion output rates, enough to produce freshwater from 1.5 L m-2h-1 (LMH) to 6 LMH. In this study, the currently designed multistage SWE devices were reviewed and examined based on their unique characteristics as well as their performances in freshwater production. The main distinguishing factors in these systems were the condenser staging design and the spectrally selective absorbers either in a form of high solar absorbing material, photovoltaic (PV) cells for water and electricity co-production, and coupling of absorber and solar concentrator. Other elements of the devices involved differences such as the direction of water flow, the number of layers constructed, and the materials used for each layer of the system. The key factors to consider for these systems include the heat and mass transport in the device, solar-to-vapor conversion efficiency, gain output ratio (representing how many times the latent heat has been reused), water production rate/number of stages, and kWh/number of stages. It was evident that most of the studied devices involved slightly different mechanisms and material compositions to draw out higher efficiency rates from the current limitations. The reviewed designs showed the ability to be adopted into small-scale solar desalination allowing for accessibility of sufficient freshwater in needing regions.

Novel LiAlO2 Material for Scalable and Facile Lithium Recovery Using Electrochemical Ion Pumping.

In this study, α-LiAlO2 was investigated for the first time as a Li-capturing positive electrode material to recover Li from aqueous Li resources. The material was synthesized using hydrothermal synthesis and air annealing, which is a low-cost and low-energy fabrication process. The physical characterization showed that the material formed an α-LiAlO2 phase, and electrochemical activation revealed the presence of AlO2* as a Li deficient form that can intercalate Li+. The AlO2*/activated carbon electrode pair showed selective capture of Li+ ions when the concentrations were between 100 mM and 25 mM. In mono salt solution comprising 25 mM LiCl, the adsorption capacity was 8.25 mg g-1, and the energy consumption was 27.98 Wh mol Li-1. The system can also handle complex solutions such as first-pass seawater reverse osmosis brine, which has a slightly higher concentration of Li than seawater at 0.34 ppm.

Janus Distillation Membrane via Mussel-Inspired Inkjet Printing Modification for Anti-Oil Fouling Membrane Distillation.

In this work, inkjet printing technology was used to print a thin layer of a hydrophilic solution containing polydopamine as a binder and polyethyleneimine as a strong hydrophilic agent on a commercial hydrophobic membrane to produce a Janus membrane for membrane distillation. The pristine and modified membranes were tested in a direct-contact membrane distillation system with mineral oil-containing feedwater. The results revealed that an integrated and homogenous hydrophilic layer was printed on the membrane with small intrusions in the pores. The membrane, which contained three layers of inkjet-printed hydrophilic layers, showed a high underwater oil contact angle and a low in-air water contact angle. One-layer inkjet printing was not robust enough, but the triple-layer coated modified membrane maintained its anti-oil fouling performance even for a feed solution containing 70 g/L NaCl and 0.01 v/v% mineral oil concentration with a flux of around 20 L/m2h. This study implies the high potential of the inkjet printing technique as a facile surface modification strategy to improve membrane performance.

Electrospun nanofiber composite membranes for geothermal brine treatment with lithium enrichment via membrane distillation.

In this study, a composite electrospun nanofiber membrane was fabricated and used to treat a geothermal brine source with lithium enrichment. An in-situ growth technique was applied to incorporate silica nanoparticles on the surface of nanofibers with (3-Aminopropyl) triethoxysilane as the nucleation site. The fabricated composite nanofiber membrane was heat pressed to enhance the integration of the membrane and its mechanical stability. The fabricated membranes were tested to evaluate their performance in feedwater containing different concentrations of NaCl in the range of 0-100 g/L, and the wetting resistivity of the membranes was examined. Finally, the optimal membrane was applied to treat the simulated geothermal brine. The experimental results revealed that the in-situ growth of nanoparticles and coating of flourosilane agent dramatically improved the separation performance of the membrane with high salt rejection, and adequate flux was achieved. The heat-pressed membrane obtained >99% salt rejection and flux of 14-19 L/m2h at varying feedwater salinity (0-100 g/L), and the concentration of the Li during the 24 h test reached >1100 ppm from the initial 360 ppm. Evaluation of the energy efficiency of the membranes showed that the heat-pressed membrane obtained the optimum energy efficiency in the high concentration of salts. Additionally, the economic analysis indicated that MD could achieve a levelized cost of 2.9 USD/m3 of lithium brine concentration as the heat source is within the feed. Overall, this technology would represent a viable alternative to the solar pond to concentrate Li brine, enabling a compact, efficient, and continuous operating system.

Effective emissions reduction of high-mileage fleets through a catalytic converter and oxygen sensor replacement program.

High-mileage vehicles such as taxis make disproportionately large contributions to urban air pollution due to their accelerated engine deterioration rates and high operation intensities despite their small proportions of the total fleet. Controlling emissions from these high-mileage fleets is thus important for improving urban air quality. This study evaluates the effectiveness of a pilot repair program in reducing emissions from taxis in Hong Kong which account for about 2 % of the total licensed vehicles. The emission factors of a large sample of 684 in-service taxis (including 121 for an emission survey program and 563 for a pilot repair program) were measured on transient chassis dynamometers. The results showed that 63 % of the sampled taxis failed the driving cycle test before the pilot repair program. Most of failed taxis were NO related and 91 % of failed taxis exceeded the emission limits of at least two regulated pollutants simultaneously. After the pilot repair program by replacing catalytic converters and oxygen sensors, the failure rate was significantly reduced to only 7 %. In addition, the fleet average NO, HC and CO emission factors were reduced by 85 %, 82 % and 56 %, respectively. In addition, on-road remote sensing measurements confirmed the real-world emission reductions from the taxis that participated in the pilot repair program. These findings led to the implementation of a large-scale replacement program for all taxis in Hong Kong during 2013-2014, which was estimated to have reduced the total HC, CO and NO emissions by about 420, 2570 and 1000 t per year, respectively (equivalent to 5-8 % emission reductions from the whole road transport sector). Therefore, reducing emissions from the small high-mileage fleets is a highly cost-effective measure to improve urban air quality.

Computational fluid dynamics simulation study of hypersaline water desalination via membrane distillation: Effect of membrane characteristics and operational parameters.

In this study, a comprehensive model was developed using Computational Fluid Dynamics (CFD), and the behaviour of a direct contact membrane distillation (DCMD) system was investigated at hypersaline feedwater conditions. The effects of various operating parameters including feed and permeate velocities, temperatures and salinities, as well as different membrane characteristics like thickness, porosity, and thermal conductivity were studied. The developed simulation model was also validated using experimental data. The results showed that the membrane conductivity and thickness had a significant impact on the DCMD performance, and the optimum operational condition was necessary to be determined. The results showed that increasing the feedwater salinity from 50 to 200 g/l decreased the membrane flux by up to 33%, while a four times decrease in thermal conductivity of the membrane could lead to an increase in the membrane flux from 11.2 to 32.4 l/m2·h (LMH). In addition, the optimal membrane thickness was found to increase with salinity, reaching >120 µm for treatment of 22 wt% NaCl feedwater solution. However, the flux declined from >32 LMH to <13 LMH upon the increase in feedwater salinity (up to 22 wt% NaCl solution). It is also shown that a thinner membrane performed better for desalination of low salinity feedwater, while the thicker one produces higher separation performance and thermal efficiency for hypersaline brine desalination.

Highly effective water hyacinth (Eichhornia crassipes) waste-based functionalized sustainable green adsorbents for antibiotic remediation from wastewater.

Azithromycin (AZIM) is considered as one of the most frequently prescribed antibiotics (ABs) in the world by medical professionals. This study explored, two novel, cheap and environmentally beneficial adsorbents i.e., alkali treated water hyacinth powder (AT-WHP) and graphene oxide-water hyacinth-polyvinyl alcohol (GO-WH-PVA) composite, fabricated from water hyacinth (Eichhornia crassipes) waste to remediate AZIM from wastewater. Biosorption experiments were performed by batch and packed-bed column studies and the adsorbents were characterized using various instrumental methods. The morpho-chemical profile of the adsorbents suggested noteworthy AZIM adsorption. AZIM adsorption data can be reasonably explained by pseudo second order (PSO) kinetic model with maximum regression coefficient (R2 > 0.99) and lowest Marquardt's present standard deviation (MPSD) and root mean squared error (RMSE) values. The isotherm models recommended Langmuir and Temkin to be the best-fitted, providing highest regression coefficient and lowest error values. Conferring to Langmuir model, the theoretical highest adsorption potentials (qmax) were accounted to be 244.498 and 338.115 mg/g for AT-WHP and GO-WH-PVA, correspondingly, very close to experimental values (qe, exp). AZIM adsorption processes were governed by the chemisorption mechanisms. The adsorbents had excellent regeneration potential and could be reused several times. In order to scale-up application of the adsorbents, performance of a 100 L packed-bed reactor was assessed and a breakthrough time of adsorption for GO-WH-PVA was 15 min in 5000 mg/L AZIM concentration. Thus, the absorbents synthesized in this study can be considered highly effective at removal of AZIM from wastewater.

Impact of source-separation of urine on treatment capacity, process design, and capital expenditure of a decentralised wastewater treatment plant.

In this study, the impact of urine diversion on the treatment capacity, treatment process, and capital costs of a decentralised wastewater treatment plant (WWTP) was simulated using BioWin. The data for simulation including for economic analysis were obtained from a real decentralised WWTP at Sydney. Simulation was conducted for two alternative process design scenarios of a WWTP: membrane bioreactor (MBR) without denitrification and anaerobic MBR in place of aerobic MBR and compared to existing process design. The simulation shows that with about 75% urine diversion (through source separation), the treatment capacity of the existing WWTP can be doubled although above 40% urine diversion, the impact appears less rapid. When the urine diversion exceeds 75%, it was found that the anoxic tank for biological denitrification becomes redundant and the current wastewater treatment process could be replaced with a simpler and much less aeration intensive membrane bioreactor (MBR) producing similar effluent quality with a 24% reduction in capital expenditure (footprint) cost. Anaerobic MBR can be a potential alternative to aerobic MBR although pre-treatment becomes essential before reverse osmosis treatment for water reuse applications. Sensitivity analysis has revealed that by operating the bioreactor at higher mixed liquor suspended solids concentrations (9 g/L instead of 5 g/L) could help increase the WWTP treatment capacity by about 3.5 times at 75% urine diversion. Hence, urine diversion (until nitrogen-limiting conditions occur above 75% urine diversion) can increase the treatment capacity of an existing WWTP and reduce the capital expenses due to reduced plant footprint.

Highly stable gold nanolayer membrane for efficient solar water evaporation under a harsh environment.

Interfacial solar water evaporation has attracted tremendous attention for sunlight harvesting for water purification. However, salt formation and stability of the photothermal materials (PTMs) remain a challenge that need addressing before bringing this technology to real-world applications. In this work, a nanoscale thin film of gold (Au) on a polytetrafluoroethylene (PTFE) membrane has been prepared using a magnetic sputtering technique. The fabricated membrane displays a robust mechanical strength and chemical stability arising from the adhesiveness of the thin film Au nanolayer on the PTFE membrane as well as the chemical inertness of the noble metal PTM. The Au nanolayer/PTFE membrane with cellulose sponge substrate resulted in an evaporation rate of 0.88 kg m-2 h-1 under 1 sun intensity. Remarkable salt ion rejection of 99.9% has been obtained, meeting the required standard for drinking water. Moreover, the membrane exhibited excellent stability and reusability in natural seawater and high salinity brine (150 g/L) and even in severe conditions (acidic, basic, and oxidized). No noticeable salt formation was observed on the evaporator surface after the tests. These findings reveal promising prospects for using a magnetron sputtering technique to fabricate a stable photothermal membrane for seawater and high salinity brine desalination.

Visible light activation of photocatalysts formed from the heterojunction of sludge-generated TiO2 and g-CN towards NO removal.

The feasibility of preparing TiO2/g-CN heterojunction from Ti-incorporated dried dye wastewater sludge is explored in this study. Two reaction routes of composite formation were evaluated. In the initial approach, one-step calcination of dried sludge and melamine mixture @600 °C was carried out. Detailed morphological and chemical characterizations showed that the one-step calcination route did not create TiO2/g-CN composites; instead, only N-doped anatase TiO2 composites were formed. Moreover, due to the non-uniform composition of organic content in the dried sludge, it was not easy to control the N doping level by varying melamine content (0-100%) in the precursor mix. However, successful formation of anatase TiO2 and g-CN was observed when a two-step calcination route was followed, i.e., via synthesis of anatase TiO2 from dried sludge, and later development of heterojunction by calcining (@550 °C) the TiO2 and melamine mixture. X-ray diffraction along with infrared and X-ray photoelectron spectroscopy verified the effective heterojunction. In addition, maximum atmospheric NO removal under UV and visible light were observed for the prepared composite when the melamine content in the precursor mixture was 70%. After 1 h of UV and visible light irradiation, the best TiO2/g-CN composite removed 25.71% and 13.50% of NO, respectively. Optical characterization suggested that the enhanced NO oxidation under UV/visible light was due to the bandgap narrowing and diminished photogenerated electron-hole recombination.

Electrode for selective bromide removal in membrane capacitive deionisation.

Due to the shortage of freshwater around the world, seawater is becoming an important water source. However, seawater contains a high concentration of bromide that can form harmful disinfection by-products during water disinfection. Therefore, the current seawater reverse osmosis (SWRO) has to adopt two-pass reverse osmosis (RO) configuration for effective bromide removal, increasing the overall desalination cost. In this study, a bromide selective composite electrode was developed for membrane capacitive deionisation (MCDI). The composite electrode was developed by coating a mixture of bromide selective resin and anion exchange polymer on the surface of the commercial activated carbon electrode, and its performance was compared to that of conventional carbon electrode. The results demonstrated that the composite electrode has ten times better bromide selectivity than the conventional carbon electrode. The study shows the potential application of MCDI for the selective removal of target ions from water sources and the potential for resource recovery through basic modification of commercial electrode.

Fertiliser recovery from source-separated urine via membrane bioreactor and heat localized solar evaporation.

Urine with its abundant macronutrients (N-P-K) is an ideal resource for the production of fertiliser. However, the odor and pathogens in the raw urine must be removed to meet the public acceptance of urine collection systems and to enable its safe reuse as a fertiliser. In this work, real urine was collected and treated through a pilot-scale gravity-driven membrane bioreactor (GDMBR) to remove the malodorous organics and to nitrify almost 50% of the ammonia into nitrate. The stablised urine was subsequently distilled via low-cost heat localized solar evaporation (HLSE) to produce a non-odorous solid fertiliser. The developed HLSE with a small footprint can attract bulk solution into a vertical insulated space and quickly heat it up to 68 °C within 1 h. The HLSE process had vapour flux at 1.3 kg m-2 h-1 as well as high solar to vapour conversion efficiency at 87%. Based on the EDX mapping and XRD analysis, the generated crystals are mainly NaNO3, NH4Cl, NaCl, NH4H2PO4 and K2HPO4, which are ideal nutrients for vegetation. In this study, the produced urine-derived fertilisers have a better performance on the growth of the leafy basil than the all-purpose commercial fertilisers. Generally, the GDMBR-HLSE is a promising cost-effective and green technology for nutrients recovery from urine.

Chemically Cross-Linked Graphene Oxide as a Selective Layer on Electrospun Polyvinyl Alcohol Nanofiber Membrane for Nanofiltration Application.

Graphene oxide (GO) nanosheets were utilized as a selective layer on a highly porous polyvinyl alcohol (PVA) nanofiber support via a pressure-assisted self-assembly technique to synthesize composite nanofiltration membranes. The GO layer was rendered stable by cross-linking the nanosheets (GO-to-GO) and by linking them onto the support surface (GO-to-PVA) using glutaraldehyde (GA). The amounts of GO and GA deposited on the PVA substrate were varied to determine the optimum nanofiltration membrane both in terms of water flux and salt rejection performances. The successful GA cross-linking of GO interlayers and GO-PVA via acetalization was confirmed by FTIR and XPS analyses, which corroborated with other characterization results from contact angle and zeta potential measurements. Morphologies of the most effective membrane (CGOPVA-50) featured a defect-free GA cross-linked GO layer with a thickness of ~67 nm. The best solute rejections of the CGOPVA-50 membrane were 91.01% for Na2SO4 (20 mM), 98.12% for Eosin Y (10 mg/L), 76.92% for Methylene blue (10 mg/L), and 49.62% for NaCl (20 mM). These findings may provide one of the promising approaches in synthesizing mechanically stable GO-based thin-film composite membranes that are effective for solute separation via nanofiltration.