Effects of natural organic matter on calcium and phosphorus co-precipitation.

Phosphorus (P), calcium (Ca) and natural organic matter (NOM) naturally occur in all aquatic ecosystems. However, excessive P loads can cause eutrophic or hyper-eutrophic conditions in these waters. As a result, P regulation is important for these impaired aquatic systems, and Ca-P co-precipitation is a vital mechanism of natural P removal in many alkaline systems, such as the Florida Everglades. The interaction of P, Ca, and NOM is also an important factor in lime softening and corrosion control, both critical processes of drinking water treatment. Determining the role of NOM in Ca-P co-precipitation is important for identifying mechanisms that may limit P removal in both natural and engineered systems. The main goal of this research is to assess the role of NOM in inhibiting Ca and P co-precipitation by: (1) measuring how Ca, NOM, and P concentrations affect NOM's potential inhibition of co-precipitation; (2) determining the effect of pH; and (3) evaluating the precipitated solids. Results showed that Ca-P co-precipitation occurs at pH 9.5 in the presence of high natural organic matter (NOM) (≈30 mg L(-1)). The supersaturation of calcite overcomes the inhibitory effect of NOM seen at lower pH values. Higher initial P concentrations lead to both higher P precipitation rates and densities of P on the calcite surface. The maximum surface density of co-precipitated P on the precipitated calcite surface increases with increasing NOM levels, suggesting that NOM does prevent the co-precipitation of Ca and P.

Evaluating UV/H2O2, UV/percarbonate, and UV/perborate for natural organic matter reduction from alternative water sources.

Natural organic matter (NOM) continues to increase in drinking water sources due to many factors, including changes in land use and global climate. Water treatment facilities will need to evaluate the best treatment options to account for these higher NOM levels. The UV/H2O2 advanced oxidation process (AOP) is one treatment option that has shown success at reducing high levels of NOM. As a result, this study evaluated the UV/H2O2 for the reduction of NOM in a high NOM water matrix, the Florida Everglades. In addition to liquid H2O2, sodium percarbonate and sodium perborate were used as oxidants to evaluate their performance as alternatives to liquid H2O2. Results showed that all three oxidants were able to reduce aromatic carbon (UV254) by 46-66% and dissolved organic carbon (DOC) by 11-19% at UV fluences of 2.6-2.7 J cm(-2) and an H2O2 dose of 100 mg L(-1). When the UV fluences were increased to 21.8-26.1 J cm(-2) at an H2O2 dose of 100 mg L(-1), UV254 reduction increased to 79-97% and DOC to 42-82% for all three oxidants. All three oxidants performed statistically similar for UV254 reduction. However, for DOC reduction, H2O2 performed statically better than both percarbonate and perborate, and perborate performed statistically better than percarbonate. While the UV/H2O2 AOP is effective for NOM reduction in high NOM waters, advances in electrical efficiency are needed to make it economically feasible.