1.
Chem Commun (Camb)
; 60(38): 5074-5077, 2024 May 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38639070
RESUMO
This study investigates the gate-opening closed-to-open-pore structural transition of a porous coordination polymer induced by CO2 adsorption. Solid-state 13C NMR examination of adsorbed CO2 and framework dynamics reveals the surface adsorption state of the closed structure below the transition pressure and an intermediate structure during the transition process.