RESUMO
The synthesis of a random copolymer through free radical copolymerization of a properly vinyl monofunctionalized regioregular poly(3-octylthiophene) (rrP3OT) macromonomer and N,N'-dimethylacrylamide (DMAM) is presented. The optical properties of the copolymer in water and in several organic solvents of varying polarity, as well as in THF/water and THF/methanol mixtures, were explored using UV-vis and photoluminescence spectroscopy. It is demonstrated that the rrP3OT chains adopt a coil conformation in solvents such as tetrahydrofuran (THF) and chloroform with the appearance of the absorption and emission maxima at 439 and 565 nm, respectively. On the contrary, the rrP3OT chains are organized on a single chain packing form (intrachain interactions) in polar solvents such as ethanol and methanol, as it is verified with the observation of the characteristic three vibronic features of the absorption spectra of the copolymer with maxima at 513, 550, and 603 nm and emission maxima at 560 nm. However, when water is used as solvent, the rrP3OT chains self-assemble into a stacklike structure due to the increased interchain interactions, as confirmed by the different aggregation process of the rrP3OT chains in the THF/water mixture, the broader absorption spectrum in water compared to those recorded in ethanol and methanol, and the 80 nm red-shifted emission maximum, centered at 640 nm.
RESUMO
Facile routes for the synthesis of hybrid materials consisting of regioregular poly(3-octylthiophene)s covalently attached to single-wall carbon nanotubes are presented for the first time. These materials are easily processable using common organic solvents, and at the same time combine the properties of regioregular poly(3-alkylthiophene)s with those of single-wall carbon nanotubes. Moreover, studies of the properties of these materials have provided strong evidence for an electron transfer from the regioregular poly(3-octylthiophene) to the single-wall carbon nanotube.
