2,3-Diarylmaleate salts as a versatile class of diarylethenes with a full spectrum of photoactivity in water.

There is incessant interest in the transfer of common chemical processes from organic solvents to water, which is vital for the development of bioinspired and green chemical technologies. Diarylethenes feature a rich photochemistry, including both irreversible and reversible reactions that are in demand in organic synthesis, materials chemistry, and photopharmacology. Herein, we introduce the first versatile class of diarylethenes, namely, potassium 2,3-diarylmaleates (DAMs), that show excellent solubility in water. DAMs obtained from highly available precursors feature a full spectrum of photoactivity in water and undergo irreversible reactions (oxidative cyclization or rearrangement) or reversible photocyclization (switching), depending on their structure. This finding paves a way towards wider application of diarylethenes in photopharmacology and bioinspired technologies that require aqueous media for photochemical reactions.

Terahertz-field-induced optical luminescence from graphene for imaging and near-field visualization of a terahertz field.

Graphene-based terahertz (THz)-field-induced optical luminescence (GB-TFIOL) is proposed in this Letter as a novel, to the best of our knowledge, THz imaging technique. We experimentally show that two-dimensional distribution of the optical luminescence from a monolayer graphene traces the beam profile of the pump THz radiation. The atomic thickness of a graphene detector, as well as a strong nonlinear dependence of optical luminescence on THz field, make the GB-TFIOL technique a useful tool for near-field mapping. A proof-of-principle experiment of the visualization of local THz-field enhancement near a metal tip with a 2 µm radius curvature was performed.

Polynomial, Neural Network, and Spline Wavelet Models for Continuous Wavelet Transform of Signals.

In this paper a modified wavelet synthesis algorithm for continuous wavelet transform is proposed, allowing one to obtain a guaranteed approximation of the maternal wavelet to the sample of the analyzed signal (overlap match) and, at the same time, a formalized representation of the wavelet. What distinguishes this method from similar ones? During the procedure of wavelets' synthesis for continuous wavelet transform it is proposed to use splines and artificial neural networks. The paper also suggests a comparative analysis of polynomial, neural network, and wavelet spline models. It also deals with feasibility of using these models in the synthesis of wavelets during such studies like fine structure of signals, as well as in analysis of large parts of signals whose shape is variable. A number of studies have shown that during the wavelets' synthesis, the use of artificial neural networks (based on radial basis functions) and cubic splines enables the possibility of obtaining guaranteed accuracy in approaching the maternal wavelet to the signal's sample (with no approximation error). It also allows for its formalized representation, which is especially important during software implementation of the algorithm for calculating the continuous conversions at digital signal processors and microcontrollers. This paper demonstrates the possibility of using synthesized wavelet, obtained based on polynomial, neural network, and spline models, during the performance of an inverse continuous wavelet transform.

Detection of SARS-CoV-2 RNA by a Multiplex Reverse-Transcription Loop-Mediated Isothermal Amplification Coupled with Melting Curves Analysis.

Loop-mediated isothermal amplification (LAMP) is a method of nucleic acid amplification that is more stable and resistant to DNA amplification inhibitors than conventional PCR. LAMP multiplexing with reverse transcription allows for the single-tube amplification of several RNA fragments, including an internal control sample, which provides the option of controlling all analytical steps. We developed a method of SARS-CoV-2 viral RNA detection based on multiplex reverse-transcription LAMP, with single-tube qualitative analysis of SARS-CoV-2 RNA and MS2 phage used as a control RNA. The multiplexing is based on the differences in characteristic melting peaks generated during the amplification process. The developed technique detects at least 20 copies of SARS-CoV-2 RNA per reaction on a background of 12,000 MS2 RNA copies. The total time of analysis does not exceed 40 min. The method validation, performed on 125 clinical samples of patients' nasal swabs, showed a 97.6% concordance rate with the results of real-time (RT)-PCR assays. The developed multiplexed LAMP can be employed as an alternative to PCR in diagnostic practice to save personnel and equipment time.

Organic amendments potentially stabilize metals in smelter contaminated Arctic soils: An incubation study.

The long-term emission impacts of the nickel processing industry in the Kola Peninsula, the largest source of sulfur dioxide and heavy metals emissions in Northern Europe, have created vast technogenic barrens near the mineral industry complexes. The pace of rehabilitation using the improved remediation technologies to enhance sustainable environmental management and regional economic development is of crucial social and economic importance. In a 120-day incubation experiment, we evaluated the prospects for the restoration of two soils at different degradation stages via carbon pool regulation comparing to mineral ameliorants - NPK fertilizer, and liming agent. Organic additives used included a humic preparation based on an alkaline brown coal extract, wood-derived biochar, and peat-derived gel, supplied by mycorrhizae fungi. The results demonstrate that the selected organic amendments are suitable for restoration of acidic metal contaminated soils. Specifically, the treatments provided a measurable increase in soil carbon content, a marked decrease in acidity, a decrease in extractable metal contents, together with an enhanced nutrient uptake and vegetative growth. A stabilization effect increased from biochar to peat-gel, liming agent and humic preparation, with an accompanying increase in soil pH. Although biochar showed a reduced ability to metal stabilization, the associated treatments were the most productive. The most effective amendments in multi-metallic contaminated soils need to be able to stabilize bioavailability of metals, adjust pH to the optimum for plant growth, and regulate nutrient consumption.

Outstanding Radiation Tolerance of Supported Graphene: Towards 2D Sensors for the Space Millimeter Radioastronomy.

We experimentally and theoretically investigated the effects of ionizing radiation on a stack of graphene sheets separated by polymethyl methacrylate (PMMA) slabs. The exceptional absorption ability of such a heterostructure in the THz range makes it promising for use in a graphene-based THz bolometer to be deployed in space. A hydrogen/carbon ion beam was used to simulate the action of protons and secondary ions on the device. We showed that the graphene sheets remain intact after irradiation with an intense 290 keV ion beam at the density of 1.5 × 1012 cm-2. However, the THz absorption ability of the graphene/PMMA multilayer can be substantially suppressed due to heating damage of the topmost PMMA slabs produced by carbon ions. By contrast, protons do not have this negative effect due to their much longer mean free pass in PMMA. Since the particles' flux at the geostationary orbit is significantly lower than that used in our experiments, we conclude that it cannot cause tangible damage of the graphene/PMMA based THz absorber. Our numerical simulations reveal that, at the geostationary orbit, the damaging of the graphene/PMMA multilayer due to the ions bombardment is sufficiently lower to affect the performance of the graphene/PMMA multilayer, the main working element of the THz bolometer, which remains unchanged for more than ten years.

Terahertz induced optical birefringence in polar and nonpolar liquids.

The terahertz induced optical birefringence in liquids with polar (acetone, chloroform) and nonpolar (benzene, carbon tetrachloride) molecules has been investigated. Fast and slow responses were extracted from the experimental data and compared with previous studies of the femtosecond optical Kerr effect. Terahertz Kerr constants were found and compared with known DC and optical constants. Analysis of the results obtained showed that, in contrast to the optical excitation, the interaction of a permanent dipole moment of molecules with a THz field makes a significant contribution to the transient birefringence and Kerr constants. This conclusion fully agrees with the direct comparison of the femtosecond optical and THz Kerr effects reported by Sajadi et al. [Nat. Commun. 8, 14963 (2017)].

Charge separation and carrier dynamics in donor-acceptor heterojunction photovoltaic systems.

Electron transfer and subsequent charge separation across donor-acceptor heterojunctions remain the most important areas of study in the field of third-generation photovoltaics. In this context, it is particularly important to unravel the dynamics of individual ultrafast processes (such as photoinduced electron transfer, carrier trapping and association, and energy transfer and relaxation), which prevail in materials and at their interfaces. In the frame of the National Center of Competence in Research "Molecular Ultrafast Science and Technology," a research instrument of the Swiss National Science Foundation, several groups active in the field of ultrafast science in Switzerland have applied a number of complementary experimental techniques and computational simulation tools to scrutinize these critical photophysical phenomena. Structural, electronic, and transport properties of the materials and the detailed mechanisms of photoinduced charge separation in dye-sensitized solar cells, conjugated polymer- and small molecule-based organic photovoltaics, and high-efficiency lead halide perovskite solar energy converters have been scrutinized. Results yielded more than thirty research articles, an overview of which is provided here.

Organometal halide perovskite solar cell materials rationalized: ultrafast charge generation, high and microsecond-long balanced mobilities, and slow recombination.

Organometal halide perovskite-based solar cells have recently been reported to be highly efficient, giving an overall power conversion efficiency of up to 15%. However, much of the fundamental photophysical properties underlying this performance has remained unknown. Here, we apply photoluminescence, transient absorption, time-resolved terahertz and microwave conductivity measurements to determine the time scales of generation and recombination of charge carriers as well as their transport properties in solution-processed CH3NH3PbI3 perovskite materials. We found that electron-hole pairs are generated almost instantaneously after photoexcitation and dissociate in 2 ps forming highly mobile charges (25 cm(2) V(-1) s(-1)) in the neat perovskite and in perovskite/alumina blends; almost balanced electron and hole mobilities remain very high up to the microsecond time scale. When the perovskite is introduced into a TiO2 mesoporous structure, electron injection from perovskite to the metal oxide is efficient in less than a picosecond, but the lower intrinsic electron mobility of TiO2 leads to unbalanced charge transport. Microwave conductivity measurements showed that the decay of mobile charges is very slow in CH3NH3PbI3, lasting up to tens of microseconds. These results unravel the remarkable intrinsic properties of CH3NH3PbI3 perovskite material if used as light absorber and charge transport layer. Moreover, finding a metal oxide with higher electron mobility may further increase the performance of this class of solar cells.

Structural defects and positronium formation in 40 keV B(+)-implanted polymethylmethacrylate.

Slow positron beam and optical absorption measurements are carried out to study structural defects and positronium formation in 40 keV B(+)-implanted polymethylmethacrylate (B:PMMA) with ion doses from 6.25 × 10(14) to 5.0 × 10(16) ions/cm(2). Detailed depth-selective information on defects in implanted samples was obtained by measuring of Doppler broadening of positron annihilation γ rays as a function of incident positron energy and these experimental results were compared with SRIM (stopping and range of ions in matter) simulation results. Two general processes, appearance of free radicals at lower ion doses (<10(16) ions/cm(2)) and carbonization at higher ion doses (>10(16) ions/cm(2)), are considered from the Doppler S-E and W-E dependences in the framework of the concept of defects formation during radiation damage of polymer structure. Probabilities of ortho-positronium (o-Ps) formation are analyzed using S-W plot and slow positron annihilation lifetime measurements. Dose dependence of o-Ps lifetime τ3 and intensity I3 at the incident positron energy of 2.15 keV correlates well with the dose dependence of S-parameter and seems to account for the existence of the expected two processes, i.e., scission of polymer chains and appearance of free radicals preceding the aggregation of the clusters resulting in the formation of network of conjugated bonds at lower ion doses and carbonization at higher ion doses. The increase of optical absorption observed with increasing ion implantation dose also suggests a formation of carbonaceous phase in the ion-irradiated PMMA.

Effect of an electric field on air filament decay at the trail of an intense femtosecond laser pulse.

Air plasma density decay in a filament produced by an intense femtosecond laser pulse in an external electric field was investigated experimentally and theoretically. It was demonstrated by means of the terahertz scattering technique that the rate of plasma decay decreases with increasing electric field. At the electric field of 7 kV/cm the lifetime of plasma with the density above 10(16) cm(-3) was prolonged from 0.5 ns to 1 ns. Numerical simulation of electron density decay and electron temperature evolution was performed, taking into consideration dissociative and three-body electron-ion recombination as well as formation of complex positive ions. The simulation showed that under the electric field the electron temperature evolves nonmonotonically and passes through a minimum due to varying contribution of electron-ion collisions to electron heating in the field. The rate of three-body electron recombination with O(2)(+) ions of 2×10(-19)(300/T(e))(9/2) cm(6)/s was found from the experimental measurements at electron temperatures in the 0.25-0.4 eV range and electron densities in the 10(15)-10(17) cm(-3) range.

The ion implantation-induced properties of one-dimensional nanomaterials.

Nowadays, ion implantation is an extensively used technique for material modification. Using this method, we can tailor the properties of target materials, including morphological, mechanical, electronic, and optical properties. All of these modifications impel nanomaterials to be a more useful application to fabricate more high-performance nanomaterial-based devices. Ion implantation is an accurate and controlled doping method for one-dimensional nanomaterials. In this article, we review recent research on ion implantation-induced effects in one-dimensional nanostructure, such as nanowires, nanotubes, and nanobelts. In addition, the optical property of single cadmium sulfide nanobelt implanted by N+ ions has been researched.

Efficiency enhancements in Ag nanoparticles-SiO2-TiO2 sandwiched structure via plasmonic effect-enhanced light capturing.

TiO2-SiO2-Ag composites are fabricated by depositing TiO2 films on silica substrates embedded with Ag nanoparticles. Enhancement of light absorption of the nanostructural composites is observed. The light absorption enhancement of the synthesized structure in comparison to TiO2 originated from the near-field enhancement caused by the plasmonic effect of Ag nanoparticles, which can be demonstrated by the optical absorption spectra, Raman scattering investigation, and the increase of the photocatalytic activity. The embedded Ag nanoparticles are formed by ion implantation, which effectively prevents Ag to be oxidized through direct contact with TiO2. The suggested incorporation of plasmonic nanostructures shows a great potential application in a highly efficient photocatalyst and ultra-thin solar cell.

Plasma filament investigation by transverse optical interferometry and terahertz scattering.

Transverse plasma distribution with 10(17) cm(-3) maximum electron density and 150 µm transverse size in a plasma filament formed in air by an intense femtosecond laser pulse was measured by means of optical interferometry. Two orders of magnitude decay of the electron density within 2 ns was obtained by combined use of the interferometry and newly proposed terahertz scattering techniques. Excellent agreement was obtained between the measured plasma density evolution and theoretical calculation.

Novel efficient design of Y-splitter for surface plasmon polariton applications.

Surface plasmon polaritons have become a research area of great importance. We present theoretical investigations on the realization of components and Y-splitters for surface plasmon polaritons guided by dielectric-loaded waveguides. The effect of the limited resolution of the fabrication process on the characteristics of fabricated Y-splitters is analyzed. A more efficient and robust configuration of the Y-splitter for surface plasmon polaritons is proposed.

Analysis of the angular acceptance of surface plasmon Bragg mirrors.

We analyze an important aspect of the behavior of surface plasmon polariton (SPP) Bragg mirrors: the dependence of the angular acceptance for reflection on the incidence angle. By means of leakage radiation microscopy, both in direct and Fourier space, we observe that the angular acceptance diminishes for increasing incidence angles. This effect, which can considerably affect the design of devices based on these elements, is shown to be the consequence of the decrease of the bandgap width with increasing incidence angle.

Quantitative analysis of surface plasmon interaction with silver nanoparticles.

The present insight into plasmon effects on the nanoscale seems sufficiently advanced to allow the development of surface-plasmon-polariton- (SPP-) based optical devices. Therefore quantitative information describing SPP phenomena is required. We investigate a SPP beam splitter constituted by silver nanoparticles on a silver thin film, fabricated by electron-beam lithography. We acquire quantitative information on the beam splitter performance by monitoring SPP leakage radiation, yielding SPP reflection, transmission, and scattering efficiencies.

Nonlinear optical absorption of ZnO doped with copper nanoparticles in the picosecond and nanosecond pulse laser field.

The nonlinear absorption of nanocomposite layers based on ZnO implanted with Cu+ ions with an energy of 160 keV in implantation doses of 10(16) and 10(17) ions/cm2 was investigated. The values of the nonlinear absorption coefficient were measured by the Z-scan method at a wavelength of 532 nm by use of nanosecond and picosecond laser pulses. Possible optical applications of these materials are discussed.

Dielectric optical elements for surface plasmons.

Basic optical elements for surface plasmons are fabricated and their functionality (focusing, refraction, and total internal reflection) is demonstrated experimentally. The optical elements consist of dielectric structures of defined geometry on top of a gold film. The working principle of these structures is discussed on the basis of calculated surface plasmon dispersion relations.